Influence of adsorption on the measurement of diffusion coefficients by Taylor dispersion

The effect of adsorption on the measurement of diffusion coefficients by the Taylor dispersion technique is investigated by modifying the governing equation to account for reversible, nonequilibrium adsorption. The resulting two-dimensional equations are solved by an explicit finite-difference technique. Experimental data for the acridine carbon dioxide system indicated that acridine adsorbs on the walls on the tubing and these data were investigated with this model. The influence of carious parameters including the number of sites and the rates of adsorption desorption was investigated by conducting a parametric sensitivity analysis on the model. It was found that adsorption of the solute on the wall of the tubing could produce an error as high as 35% on the measured diffusion coefficient compared to the actual diffusion coellicient. Examination of the influence of each of the parameters will enable Inure investigators to reduce the effect of adsorption in the measurement of diffusion coefficients by Taylor dispersion.     

Results of the ASTM field test of tristimulus weighting functions

In 1993, the American Society for Testing and Materials carried out a field test of newly calculated tristimulus weighting factors. These weighting factors had been calculated by a method proposed by Venable. the test also included a method of correction for bandpass dependence put forth by Stearns. the purpose of the trial was to assess the possible reduction in bandpass dependence introduced by each of these sets of weights. A large number of sets of spectral data were gathered from the cooperators in the field test. Results of integration by the various sets of tristimulus weighting factors were calculated. A total of 15 120 color differences were calculated and statistics were derived to test the probable error resulting from each method of correction. Errors attributable to bandpass dependence were on the order of a few tenths to as much as one CIELAB unit when uncorrected weight sets were used. These errors could be reduced to a few hundreths of a CIELAB unit, and in some cases to a few thousandths of a unit, by employing one correcting strategy or the other. an overall mix of strategies was ultimately chosen to minimize the bandpass dependence over the entire range of weight sets. Utilizing this mixed strategy, the median error introduced into 10-nm integration by bandpass dependence was only 0.004 CIELAB units. © 1995 John Wiley & Sons, Inc.     

Ruins and Revival: Paris in the Aftermath of the Second World War

Although many devastated European cities have been studied, the bombing and reconstruction of key industrial sites and certain suburban residential zones in greater Paris have received little scholarly attention. Using archival sources, this article explores both destruction and reconstruction, and traces how homeless families shared apartments or endured years of 'temporary' accommodation in huts and other shelters. Post-war economic planning in France privileged the restoration of industrial and commercial sites; rebuilding of housing by the state, by housing co-operatives and by individual property owners received less support and progressed far more slowly. Today, the visual legacy of reconstruction is easily confused with that of completely new post-war apartments; however its origin, if not its architecture, is distinctively different and merits recognition in its own right.     

Insight into the chemical reaction of CH2OH with NO: Formation of N-hydroxy formamide as an isocyanic acid precursor

This study has explored the potential energy surface on the chemical reaction of CH₂OH with NO by using ab initio calculation. We have found the new reaction pathway producing N-hydroxy formamide, which can further decompose to generate isocyanic acid as a reducing agent of hydrocarbons selective catalytic reduction.     

CAN IS AVOID MARGINALIZATION ?

Two major areas of concern for IS managers are the use of outsourcing and the often-expressed view that little competitive advantage has been gained from information processing. These developments have begun to mirror events in other professions from a bygone age. By looking outside the IS field for some perspective, we may avert a similar outcome and better define the role of IS in the organization.