锝化学研究 Ⅸ.脑显像剂Tc~(Ⅴ)ON_2S_2类配合物结构稳定性和价态的研究

采用改进的ＣＮＤＯ／２法模拟了ＢＡＴ类脑显像剂Ｔｃ（Ⅴ）Ｏ配合物价态的转换过程，发现Ｎ２Ｓ２类配体与Ｔｃ（Ⅴ）Ｏ核配位时，可能存在配位平衡离子Ｘ。在溶液中由于Ｘ离子的优先解络，瞬间存在＋１价对称性９９Ｔｃｍ配合物，并且，它又自动向相对稳定的０价不对称性９９Ｔｃｍ配合物转换，在动态转换过程中，将导致仅有一个配位Ｎ原子保留一个质子，这与实验结果一致。采用键级削弱百分数概念，表征配位过程的二个配位Ｎ原子上保留程度，解释了Ｔｃ（Ⅴ）Ｏ核、Ｔｃ（Ⅴ）≡Ｎ核Ｎ２Ｓ２类配合物两个Ｎ－Ｈ键上质子保留程度不同的原因，为今后设计不同价态锝配合物结构提供理论依据。     

Variations of physical properties in pellets containing alumina/carbon powder mixtures during reduction and nitridation

Surface area and porosity of pellets containing alumina/carbon powder mixtures during reduction and nitridation were determined. The experimental results indicated that surface area and porosity of solid samples were decreased by increasing the reaction temperature, grain size, forming pressure and the amount of catalyst. Increasing the molar ratio of C/Al₂O₃ and gas flow rate could decrease the surface area and increase the porosity of the solid sample.     

粗苯放散气体回收系统的开工调试经验

介绍了焦化厂粗苯放散气体回收系统开工调试的经验。     

Free vibration of laminated plates using a finite strip method based on a higher-order plate theory

The finite strip method based on the higher-order plate theory is developed for determining the natural frequencies of laminated plates. This method can accurately predict the through thickness effect of transverse shear deformation. Furthermore, only a few degress of freedom are required in the finite strip method. Some numerical results for various span-to-thickness ratios, material properties and stack sequences are presented for illustrative purposes. The present model provides a better way to obtain more accurate natural frequency results.     

A new process of fabricating inverted-staggered tri-layer thin-filmtransistors

A new method of fabricating a-Si:H TFT with etching-stop structure has been proposed. Only one plasma-enhanced chemical vapor deposition is required in this new method and a PH₃/H₂ plasma treatment during the deposition has been used to form the TFT contact and thus saved another plasma deposition. With this method, a TFT of 500 Å active layer has been fabricated successfully. The drain current and saturation mobility of this device is 2.4×10^-7 A and 0.1 cm²/V sec, respectively, which is comparable to the conventional fabricating method. The plasma treatment will also form an additional leakage path on the TFT top surface and increase the TFT subthreshold slope. However, a current of less than 1 pA at V_G=-2.4 V can still be obtained. The possible mechanism of the contact formation by the plasma treatment is also discussed     

Robust controller with disturbance rejection for hydraulic servosystems

A controller is presented that improves the performance and reduces the sensitivity of hydraulic servo systems in the presence of parameter variations, nonlinear effects, and other disturbances. The control system has enhanced closed-loop stability and can recover from steady-state and transient error quickly and completely. It consists of a servo controller, an auxiliary controller, and a robust controller. Simulation and experimental results demonstrate the validity of the controller     

Laser glazing of an Fe-C-Sn alloy

Morphology and geometry of melted zones, cooling rates, microstructure and microhardness in the laser-glazed Fe-4%C-10%Sn alloy have been investigated. The computer simulation on the basis of the moving gaussian source model was used successfully to predict the maximum width and depth of the melted zone and the cooling rate. The microstructure from the surface to the bottom of the laser-melted zone is a non-crystalline phase, dendritic grains and a microcrystalline zone successively. Values of the averaged-spacing of the non-crystalline phase are 0.205⁶ and 0.121⁹nm, respectively; twinned martensites, having an axial ratioc/a of 1.128, existed in dendritic grains, and carbides of Fe₃ C at the interdendritic regions; the microcrystalline zone was composed of -Fe and a new bet (a=0.415 nm,c=0.955 nm) phase. The different microstructure in the melted zone can be explained by the results of the heat flow calculation. A fine eutectic structure (-Fe + Fe₃C) was observed in heat-affected zones. Microhardness of the eutectic structure can be predicted by the empirical relation of fracture stress to the interlamellar spacing of pearlite.     

A study on bioglass ceramics in the Na2O-CaO-SiO2-P2O5 system

A new bioglass ceramic with composition of Na₂O 12%, CaO 28%, P₂O₅ 10% and SiO₂ 50% with a high bending strength (120–140 MPa) and compressive strength (600–750 MPa) was studied. The crystallized phases of-Ca₂P₂P₇ and Na₂Ca₃Si₆O₁₆ were determined by X-ray diffraction. Optical microscopy of the material revealed that a very uniform crystal size of about 30 m was obtained with high nucleation frequency. The nucleation and crystallization processes were also investigated. The rat shoulder test showed that the material formed a tight chemical bond with biological texture and had good biocompatibility.