Boosting Redox Kinetics of Sulfur Electrochemistry by Manipulating Interfacial Charge Redistribution and Multiple Spatial Confinement in Mott–Schottky Electrocatalysts

The serious shuttle effect and sluggish reaction kinetics intrinsically handicap the practical application of Li-S batteries. Herein, a unique 3D hierarchically porous Mott–Schottky electrocatalyst composed of W₂C quantum dots (QD) spatially confined in nitrogen-doped graphene microspheres (NGM) is proposed for regulating the kinetics of sulfur electrochemistry. Experimental and theoretical results disclose a spontaneous charge rearrangement and induce built-in electric field across the W₂C QD/NGM heterojunction interface, contributing to reduced energy barrier for both polysulfides reduction and Li₂S oxidation during entitle discharge/charge processes. Furthermore, the ultrasmall W₂C QD with high electrocatalytic activity and superior conductivity can promote the conversion of S species, while the hierarchically porous microspheres assembled from wrinkled graphene nanosheets not only can efficiently inhibit the polysulfides shuttling via multiple spatial confinement, but also provide abundant inner space for stable reservation of active S, highly conductive networks, and maintain the structural integrity of cathode during consecutive cycling. Consequently, Li-S batteries employed with the designed W₂C QD/NGM-based cathode exhibit outstanding electrochemical properties even at a high sulfur loading. The superior performance combined with the simplicity of the synthesis process represents a promising strategy for the rational design of advanced electrocatalyst for energy applications.     

利用EALCD的数字全息干涉术

基于电寻址液晶(EALCD)读写图像实时、衍射效率高的特性,设计了以EALCD和CCD为关键器件的数字全息干涉系统.系统满足空间带宽积,时间、空间相干度和偏振度的要求,提高了干涉条纹的对比度,降低了散斑噪声等影响,实现了数字全息干涉术的高精度测试.利用双曝光全息干涉术原理,应用Matlab编程取代传统相移术中的压电位移...     

一种模糊自适应BP算法的研究

本文在人工神经网络中引入模糊集理论，提出一种模糊自适应ＢＰ算法。通过奇偶校验和ＥＥＧ异常波形检测两上实例，验证了新算法在学习速度与性能上都优于传统的ＢＰ和虎法。     

雷达目标检测概率简化算法及应用分析

介绍了典型雷达目标的RCS起伏模型,阐述了由雷达目标起伏造成的信噪比损失,分析了雷达发现概率、虚警概率和信噪比之间的关系,绘制了仿真曲线。对非起伏目标和起伏目标之间在相同检测概率下的所需信噪比的不同,给出了一种等效算法,并针对非起伏目标的检测概率复杂度大的问题,给出了一种简化模型,并对简化后的误差进行了分析,最后对模型在雷达检飞试验中的应用进行了简要分析。     

Thermal Shrinkage Behavior of Metal–Organic Frameworks

Thermal treatment of metal–organic frameworks (MOFs) as a post‐treatment approach has grown in popularity and resulted in various MOF‐derived materials. However, the widely used extreme thermolytic conditions (usually above 500 °C) lead to degradation in the well‐defined MOFs intrinsic properties. This work demonstrates that MIL‐101 calcined at medium‐temperature range (200–280 °C) partially breaks the coordination bonds that can introduce more accessible active sites, exhibiting a 10‐fold increase in oxidation activity while retaining its intrinsic structure and porosity. Another fascinating feature of MIL‐101 calcined in this temperature range is their temperature‐dependent shrinkage behavior, which is also found in many other types of MOFs. Based on different shrinkage ratios of various MOFs, yolk–shell MOFs@MOFs structures can be constructed through nonsacrificial template method. Overall, the structural and morphological evolution process of MOFs treated in the medium‐temperature range can open new horizons to develop efficient MOFs catalysts and design complex structures.     

适用于高阶QAM解调的载波恢复算法及其实现验证

高阶正交幅度调制（QAM）系统中,随着QAM信号阶数的提高,频偏和相偏对系统解调性能的影响越敏感,其对同步性能的要求也越来越高。因此,必须在接收端对系统中的频偏和相偏进行更精确的补偿,使得接收端与发送端的载波信号达到同频同相,来提高解调系统的性能。本文首先简单介绍了两种常用两种面向判决的载波相位恢复算法,并利用MATLAB／Simulink为该算法搭建了系统仿真模型进行分析,然后给出了具体的实现方法并对其性能进行了分析。仿真结果表明,面向判决的载波恢复算法实现简单,稳态时抖动较小,非常适用于高阶QAM解调系统。     

电弧保护装置的设计

本文分析了故障电弧导致火灾的可能性与严重性,简述了目前国内外相关保护装置的发展与现状。详细介绍了故障电弧保护装置的设计流程与技术关键点。     

Regulating Water Adhesion on Superhydrophobic TiO2 Nanotube Arrays

Bioinspired surfaces with special wettability have attracted a significant attention in recent years because of their potential applications for no loss liquid transfer, anti‐icing, and self‐cleaning. Herein, the realization of two extreme superhydrophobic states on 1H, 1H, 2H, 2H–perfluorooctyltriethoxysilane‐modified TiO₂ nanotube arrays (NTAs) is described by changing the structural characteristics of nanotubes while keeping the surface chemical composition constant. The water adhesive force is regulated in a wide range from ≈4.4 to ≈89.6 μN by the nanotubular diameter, length, density, and surface roughness. The cooperation effect between the negative pressures induced by the volume change of sealed air‐pockets and the van der Waals' attraction at solid–liquid interface contributes to the water adhesion. The superhydrophobic TiO₂ NTAs with a high adhesive force is used as a “mechanical hand” to transfer water microdroplets without any loss, and the one with extremely low adhesive force is utilized as a self‐cleaning and anti‐icing surface.     

Investigation of charge loss characteristics of HfO2 annealed in N2 or 02 ambient

The retention characteristics of electrons and holes in hafnium oxide with post-deposition annealing in a N2 or 02 ambient were investigated by Kelvin probe force microscopy. The KFM results show that compared with the N2 PDA process, the O2 PDA process can lead to a significant retention improvement. Vertical charge leakage and lateral charge spreading both played an important role in the charge loss mechanisms. The retention improvement is attributed to the deeper trap energy. For electrons, the trap energy of the HOS structure annealed in a N2 or 02 ambient were determined to be about 0.44 and 0.49 eV, respectively. For holes, these are about 0.34 and 0.36 eV, respectively. Finally, the electrical characteristics of the memory devices are demonstrated from the experiment, which agreed with our characterization results. The qualitative and quantitative determination of the charge retention properties, the possible charge decay mechanism and trap energy reported in this work can be very useful for the characterization of hafnium charge storage devices.     

氮气或氧气气氛退火的氧化铪材料电荷泄漏情况研究

本文中, 使用开尔文探针显微镜,研究了不同退火气氛(氧气或氮气)情况下氧化铪材料的电子和空穴的电荷保持特性。与氮气退火器件相比,氧气退火可以使保持性能变好。横向扩散和纵向泄露在电荷泄露机制中都起了重要的作用。 并且,保持性能的改善与陷阱能级深度有关。氮气和氧气退火情况下,氧化铪存储结构的的电子分别为0.44 eV, 0.49 eV,空穴能级分别为0.34 eV, 0.36 eV。 最后得到,不同退火气氛存储器件的电学性能也与KFM结果一致。对于氧化铪作为存储层的存储器件而言,对存储特性的定性和定量分析,陷阱能级,还有泄漏机制研究是十分有意义的。