Effect of temperature on polymer migration II: Concentration equation

Polymer migration is a generally well-known phenomenon in a flow field, and it has been verified that the sources of such phenomena are nonhomogeneity of the flow, concentration effects and hydrodynamic interactions between the polymer molecules. In addition, temperature effects were found to be another source of polymer migration. The Langevin equation for a polymer molecule was first derived from single chain dynamics using a kinetic theory for the bead-spring elastic harmonic dumbbell model, as described in part I (reference [1]). In this paper the diffusion equation and concentration profile of the polymer molecules induced by a temperature gradient are obtained from the Fokker-Planck equation. A new differential operator is also introduced to calculate the concentration profile. From the concentration equation obtained in the general flow geometry, we find that in dilute polymer solution there are significant effects on the polymer migration not only due to the nonhomogeneity of the flow field but also due to temperature gradients.     

Transferring information from one experiment to another

This paper presents a rational method (based on Bayes' Theorem) for transferring information on parameter values from one experiment to another, in situations where the mathematical models for the two experiments share some parameters in common. The uncertainty in the estimates of the parameters, which reflects the experimental error in the initial experiment, is properly transferred as well. The use of the method is demonstrated by applying it to a fairly complicated system, typical in chemical reaction engineering, in which the kinetic parameters in a model for the hydrogenolysis of butane reaction were estimated using data obtained from a bench-scale, integral packed-bed reactor. These parameter estimates were then transferred to a model for a fluidized bed reactor in which the same chemical reaction occurred. Using the fluidized bed data they were updated and two additional parameters in the fluidized bed model were also estimated. This procedure allows a more realistic estimate of the uncertainty in all parameter values in the model for the fluidized bed reactor.     

Soap‐free emulsion copolymerization of perfluoroalkyl acrylates in the presence of a reactive surfactant

Soap‐free emulsion copolymerization of perfluoroalkyl acrylate (FA)/methyl methacrylate (MMA)/n‐butyl acrylate (n‐BA) was carried out in the presence of sodium 2‐acrylamide‐2‐methyl propanesulfonate (AMPSNa) as a reactive surfactant and potassium persulfate (KPS) as an initiator. An analysis of the effects of concentration of AMPSNa, KPS, FA as well as polymerization temperature on the kinetic features (rate of polymerization) and colloidal characteristics (mean particle diameter, particle disperse index, particle numbers, and surface charge density) was followed. NMR, FTIR, AFM, and fluorine‐selective electrode analysis were used to characterize the composition and morphology of the FA copolymers. Both AFM analysis and contact angle measurements strongly implied that the fluorinated segments migrated to the outmost surface and created films with lower surface energy. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2438–2444, 2007     

Effects of estrogen-induced hyperlipidemia on the erythrocyte membrane in chicks

The effects of estrogen-induced hyperlipidemia on plasma lipid peroxidation, fatty acid composition and osmotic fragility of erythrocytes in chickens were studied. Young male chickens implanted with estrogen for three wk developed a marked hyperlipidemia. Plasma levels of triglyceride, cholesterol and phospholipid were elevated 68-, four- and 24-fold, respectively, over controls. There was also a two-fold increase in plasma lipid peroxidation measured by the thiobarbituric acid test. Vitamin E supplement (1,000 IU/kg diet) reduced the plasma lipid peroxidation to the control level, but had no effect on the plasma lipid content. Estrogen-induced hyperlipidemia resulted in changes in the fatty acid composition of membrane lipids of erythrocytes. The major changes were an increase in oleic acid from 10.0% to 14.2% and a decrease in linoleic acid from 31.3% to 26.0%. The erytrocytes with an altered membrane fatty acid composition were found to have an increased osmotic fragility. It was apparent that there was a direct correlation between the oleic acid content and the osmotic fragility of erythrocytes.     

Effect of adsorptive gaseous reactant on non-isothermal behavior for gas-solid reactions

The effect of adsorptive species on non-isothermal gas-solid reactions is studied on the basis of Langmuir-Hinshelwood kinetics. The concept of an effectiveness factor provides good information to ascertain the effect of adsorptive species and the transition of the rate controlling regime, in connection with the parameters, generally used in the analysis of non-isothermal behavior. For highly exothermic reactions, the effectiveness factor-Thiele modulus curves with multiple solutions are presented with respect to the modified adsorption equilibrium constant. The variations of the rate-controlling regime by the effect of adsorptive species are also discussed.     

Enhanced utilization bound of Rate-Monotonic scheduling in Controller Area Networks

When priorities to message streams are assigned using Rate Monotonic (RM) for a Controller Area Network (CAN), the utilization bound is known to be about 25% for CAN 2.0A and 29% for CAN 2.0B. In this letter, we present a higher utilization bound than the existing ones with a reasonable constraint. The new utilization bounds are approximately 34% for CAN 2.0A and 41% for CAN 2.0B if no single message stream's utilization exceeds 46% or 27% of the total utilization for CAN 2.0A or CAN 2.0B, respectively.     

Semi-annual cycle of sea-surface temperature in the East/Japan Sea and cooling process

Semi-annual cycles of the sea-surface temperature (SST) in the East/Japan Sea (EJS) and their forcings were examined by analysing National Oceanic and Atmospheric Administration/Advanced Very-High-Resolution Radiometer data, scatterometer wind vectors, and heat flux data. The semi-annual cycle contributed to the total variance of the SST by 8% and amounted to 25% of the amplitudes of the annual SST cycle, particularly in the Tatarskiy Strait and along the continental shelf off Russia. The lowest phase, corresponding to the minimum SST, occurred during early November and 6 months earlier in May or June depending on the position. The forcings of the semi-annual cycle were not semi-annual but substantially annual with a lag of 6 months, which gave rise to SST cooling in spring and autumn. Our analyses illustrated that SST cooling in autumn was caused by direct, local atmospheric wind forcings, whereas the cooling with large amplitudes of the semi-annual cycle in spring was caused by the non-local, remotely forced cold water advection of the Liman Current associated with sea-ice melting in the Tatarskiy Strait. The phase lag of 1–2 months between the complete melting of the sea ice in the Tatarskiy Strait and the surface cooling along the Russian continental shelf was related to the advection of cold water from sea ice in the form of the Liman Cold Current. The semi-annual cycle also resulted from asymmetry of the time series of the SST due to a long cold winter and a short warm summer. To understand how SST curves are distorted and asymmetric, we suggested two mathematical parameters of kurtosis and skewness. In addition, we suggest that the ratio of the semi-annual amplitude to the annual amplitude of SST harmonics can be used as a typical indicator of the asymmetry in year-to-year SST variations.     

The use of non–physical standards in colour communication and matching

As a result of developments in spectrophotometry, together with improved accuracy in computer colour matching and laboratory dyeing, non–physical standards (reflectance data) can now be used for the successful communication, matching and quality control of colour. In colour palette generation, ‘matching by numbers’ has become a reality.     

Phase behavior of blends of aliphatic polyesters with a vinylidene chloride/vinyl chloride copolymer

A series of aliphatic polyesters having CH₂/COO ratios from 2 to 14 in their repeat units were blended with a copolymer of vinylidene chloride containing 13.5% by weight of vinyl chloride. Blends of polyesters having CH₂/COO < 4 did not form completely miscible amorphous phases, whereas polyesters having CH₂/COO ≥ 4 did form completely homogeneous amorphous phases for all temperatures below the decomposition point except for the polyester with CH₂/COO = 14 which showed reversible phase separation on heating, i.e., lower critical solution temperature behavior. Interaction parameters were estimated by melting point depression and by analog calorimetry. The behavior reported here is qualitatively similar to that reported earlier for blends of aliphatic polyesters with poly(vinyl chloride), polyepichlorohydrin, polycarbonate, styrene–allyl alcohol copolymers, and the hydroxy ether of bisphenol A.     

Adsorption and desorption characteristics of 2-methyl-4-chlorophenoxyacetic acid onto activated carbon

Adsorption and desorption characteristics of the 2-methyl-4-chlorophenoxyacetic acid (MCPA) from aqueous solution onto the activated carbon (GAC, F-400) were studied. Adsorption equilibrium capacities of the MCPA increased with decreasing pH and temperature of the solution. Adsorption equilibrium of the MCPA could be represented by the Sips equation. The internal diffusion coefficients were determined by comparing the experimental concentration decay curves with those predicted from surface diffusion model and pore diffusion model. The adsorption model based on the linear driving force approximation (LDFA) was used for simulating the adsorption behavior of the MCPA in a fixed bed. Over ninety five percent desorption of the MCPA could be obtained using distilled water.