Surface modification of carbon nanofibers via deposition of an ultrathin coating of plasma‐polymerized poly(acrylic acid) and its effect on the properties of polyamide 6/CNF nanocomposites

Carbon nanofibers (CNFs) were coated with an ultrathin layer of poly(acrylic acid) (PAA) via plasma polymerization. The effect of the plasma reactor parameters on the extent of the CNF modification was studied. SEM micrographs showed that surface roughness increased with the plasma treatment. The thickness of the ultrathin PAA layer deposited on the CNF was determined by STEM to be ca. 8 nm. Untreated and treated CNF were melt‐mixed with polyamide 6 (PA6) in a Brabender mixing chamber to obtain PA6/CNF nanocomposites. The effect of the plasma treatment on the dispersion and compatibility was examined and found to improve markedly. Fractured tensile specimens showed that the CNF seemed to be completely embedded in the polymer matrix, indicating high compatibility between the PA6 and the PAA‐coated CNF. Tensile stress and tensile modulus of PA6 nanocomposites with treated CNF were found to increase by 30 and 48%, respectively, when compared with those with untreated CNF. However, the increase in tensile stress and modulus with respect to pure PA6 was 52 and 88%, respectively. Finally, XRD showed that the CNF induce the formation of the α (alpha)‐crystalline phase in PA6. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Accurate Effective Potentials of Real Substances from Acoustic Virial Coefficients

Accurate second acoustic virial coefficients have been employed to determine parameters of an effective intermolecular potential for nine pure substances: argon, nitrogen, carbon dioxide, carbon tetrafluoride, and the first five alkanes (methane, ethane, propane, butane, and pentane). The values used for the second acoustic virial coefficients were taken from data reported in the literature. To obtain the form and parameters of the effective potential, we employed an inversion method recently introduced for volumetric second virial coefficients of nonconformal potentials. The potential parameters determined in this way are useful in predicting various gas properties. The model reproduces the experimental second virial data within their uncertainty, including volumetric second virial coefficients that were not used in the potential determination.     

Earthquakes and children: The role of psychologists with families and communities.

The 2008 Sichuan Province earthquake and 2005 Pakistan earthquake are examples of natural disasters that took an unimaginable toll on children. In such disaster management contexts, family members as well as health care and school personnel are the first-line responders and are natural sources of continued social support as children recover. Although psychologists have increasingly sophisticated understandings of post-disaster reactions and strategies for helping children and adolescents cope with trauma, models for responding to mass catastrophes are limited, particularly in geographically remote communities and in regions in which mental health services are stigmatizing. With children’s well-being subsequent to earthquakes inextricably linked to family and community, psychologists can make important contributions in 3 spheres: (a) coordinating and activating collaborations within children’s existing social contexts to develop post-earthquake interventions; (b) designing prevention and preparedness programs focused on the emotional needs of children in earthquake-prone communities; and (c) conducting research on interventions and recovery with particular attention to developmental stage, sociocultural-economic contexts, and the similarities versus differences across various types of disasters. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Search engines as a security threat

Because they implement vulnerable security policies, search engines are excellent tools for helping hackers to attack machines anonymously, search for easy targets or gather confidential data. Securing all channels against hackers trying to penetrate a vulnerable system isn't possible, but there is no reason for search engines to be wide-open channels that continue to help hackers find and penetrate weak systems. Because it is so easy to use a search engine to cloak an attack, search-engine-based hacker abuse has become a real threat that poses serious risks. However, not all blame should fall on those who operate the search engines. Search engines aren't responsible for the huge numbers of poorly configured and insecure machines all over the Internet even if the search engines do aid in identifying them, but the search engines must take some blame if they continue to provide easy ways to locate weak and penetrable machines     

Optimization of operational planning for wind/hydro hybrid water supply systems

Water supply systems (WSS) frequently present high-energy consumption values, which correspond to the major expenses of these systems. Energy costs are a function of its real consumption and of the variability of the daily energy tariff.This paper presents a model of optimization for the energy efficiency in a water supply system. The system is equipped with a pump station and presents excess of available energy in the gravity branch. First, a water turbine is introduced in the system in order to use this excess of hydraulic available energy. Then, an optimization method to define the pump operation planning along the 24 h of simulation, as well as the analysis of the economic benefits resulting from the profit of wind energy to supply the water pumping, while satisfying the system constraints and population demands, is implemented, in order to minimize the global operational costs.The model, developed in MATLAB, uses linear programming and provides the planning strategy to take in each time step, which will influence the following hours. The simulation period considered is one day, sub-divided in hourly time steps. The rules obtained as output of the optimization procedures are subsequently introduced in a hydraulic simulator (e.g. EPANET), in order to verify the system behaviour along the simulation period. The results are compared with the normal operating mode (i.e. without optimization algorithm) and show that energy cost's savings are achieved dependently of the initial reservoir levels or volume. The insertion of the water turbine also generates significant economical benefits for the water supply system.     

Simultaneous degradation of atrazine and simazine by a binary culture of Stenotrophomonas maltophilia and Arthrobacter sp. in a two‐stage biofilm reactor

BACKGROUND: The impact of mixtures of chloro‐triazinic herbicides, such as atrazine and simazine, on aquatic ecosystems is of environmental concern. To study their biodegradation under various operational conditions, a binary community comprising Stenotrophomonas maltophilia and Arthrobacter sp. attached to the porous support of a packed bed reactor, was evaluated. RESULTS: The genetic analysis of the two atrazine‐degrading strains revealed that genes atzA, atzB, atzC are present in both bacteria, but only S. maltophilia possess atzD. Thus, by cultivating Arthrobacter sp. on these herbicides, cyanuric acid accumulation was observed. When the binary community was cultivated in the biofilm reactor, at all the loading rates probed, both herbicides were entirely removed. However, complete biodegradation of cyanuric acid was not achieved. CONCLUSIONS: Even with a two‐stage reactor, cyanuric acid was only partially removed. This fact could be attributed to the absence, in the second stage, of an easily degradable energy source, required by S. maltophilia for the uptake and cometabolic degradation of the recalcitrant heterocyclic ring. Responding to differences in nutritional conditions prevailing at each reactor stage, local differences in species' predominance were clearly detected by microbiological and molecular biology methods. Copyright © 2010 Society of Chemical Industry     

Structural symmetry breaking of silicon‐containing poly(amide‐imide) oligomers and its relation to electrical conductivity and Raman‐active vibrations

Optically active poly(amide‐imide) oligomers were synthesized by direct polycondensation between an aromatic diamine and a dicarboxylic acid both containing a diphenylsilylene unit. The reaction was carried out using triphenyl phosphite/pyridine in the presence of CaCl₂ and N‐methyl‐2‐pyrrolidone as solvent. Oligomers were obtained in good yields and showed high solubility in common aprotic polar solvents. The precursors, monomers and poly(amide‐imide) oligomers were characterized using elemental analysis and Fourier transform infrared and NMR (¹H, ¹³C, ²⁹Si) spectroscopy. Additionally, the main vibrations of the functional groups (C?O, C?C or N? H) in the oligomers with respect to temperature were characterized using Raman spectroscopy. The glass transition temperature was determined by studying the Raman spectra and corroborated using differential scanning calorimetry. The thermal stability was studied using thermogravimetric analysis. The molecular mass of the compounds was obtained from matrix‐assisted laser desorption ionization time‐of‐flight mass spectrometry and their optical properties were analyzed using UV‐visible diode array spectrophotometry. The electronic properties of the oligomers as well as the delocalization of charge carriers within their structures were analyzed using conductance‐voltage curves, which showed that these materials are excellent candidates for integrated optoelectronic applications. Copyright © 2011 Society of Chemical Industry     

Estimation of water diffusivity parameters on grape dynamic drying

A computer program was developed, aiming at estimating water diffusivity parameters in a dynamic drying process with grapes, assessing the predictability of corresponding non-isothermal drying curves. It numerically solves Fick’s second law for a sphere, by explicit finite differences, in a shrinking system, with anisotropic properties and changing boundary conditions.     

Control of Microbial Adhesion as a Strategy for Food and Bioprocess Technology

Bacteria and other microorganisms have a natural tendency to adhere to surfaces as a survival mechanism. This can occur in many environments, including the living host, industrial systems, and natural waters. The general outcome of bacterial colonization of a surface is biofilm formation, which consists of microorganisms immobilized in a variety of polymeric compounds generally referred to as extracellular polymeric substances. Bacterial adhesion to a solid surface is a crucial step in the biofilm process. This step is dependent upon van der Waals, electrostatic, and acid–base interactions. These interactions are influenced by physicochemical properties of the substratum and the bacterial surface, such as hydrophobicity, surface charge, and electron donor–electron acceptor properties. In addition, the roughness of the substratum and the microbiological characteristics of the cell surface, such as cellular appendages and production of exopolysaccharides, can affect the adherence process. To date, many strategies have been developed to decrease the adherence of bacteria to surfaces. Surface modification with the addition of the suitable compounds makes surfaces less attractive for microorganisms and therefore prevents bacterial adherence and biofilm formation.     

Click‐ligation of coumarin to polyether polyols for polyurethane foams

A simple strategy for the synthesis and functionalization of polyurethanes is described. Anionic ring‐opening polymerization was combined with ‘click’ chemistry to synthesize polyols with fluorescent properties. This route allows the incorporation of a wide range of functionalities in the polyols with an easy, clean and highly selective process compatible with several types of functional groups. The proposed strategy opens the way to the production, in a cost‐effective way, of ‘smart’ polyurethanes with non‐conventional properties like fire retardancy, antimite properties, antibacterial properties, etc. Alkynyl groups were introduced into the polyol chains by the controlled addition of glycidyl propargyl ether as co‐monomer during a conventional anionic ring‐opening copolymerization with propylene oxide. Subsequently 4‐azidomethyl‐7‐methoxycoumarin molecules were introduced onto the alkynyl‐polyether polyols by copper‐catalysed cycloaddition reactions to produce end‐functionalized polyols. The chemical structure of the novel polyols was characterized using infrared spectroscopy, nuclear magnetic resonance spectroscopy, gel permeation chromatography with triple detection and matrix‐assisted laser desorption/ionization time‐of‐flight mass spectroscopy. These characterization techniques confirmed the presence of a considerable amount of functional groups in the structure of the polyols. Finally, various fluorescent rigid foams, based on the functionalized polyols, were synthesized. Copyright © 2012 Society of Chemical Industry