色谱顶空法测活度系数及对三元极性体系液液平衡预测

用气相色谱顶空分析法测定 18组部分互溶三元极性体系在完全互溶区的 3个组分活度系数 ,由此拟合出 U NIQU AC过量自由焓模型参数 ,再用 U NIQUAC方程预测液液平衡。这一方法曾很好地用在水-正烷烃 -醇体系。将此法拓展到含醇、酮、酯 ,醚、卤烷烃和水等多种极性组分的三元体系液液平衡的预测 ,其结果与文献的液液平衡数据比较 ,平均均方根误差 1.4 1% ,表明本法对含极性组分的体系仍然可行     

Melt‐processable rubber: Chlorinated waste tire rubber‐filled polyvinyl chloride

Chlorinated ground rubber tire (Cl‐GRT) particles were used as filler in a plasticized polyvinylchloride (PVC) to develop a melt‐processable rubber composition. Physical properties of the Cl‐GRT‐filled PVC compound showed improvement compared to the nonchlorinated counterpart. Interaction between Cl‐GRT and PVC was examined on the basis of results of stress relaxation, dynamic mechanical thermal analysis, and solvent swelling studies. The Cl‐GRT could be loaded upto 40 parts per hundred parts of PVC, and the composition still retains the elastomeric characteristics. The Cl‐GRT‐filled composite was found to be reprocessable like the unfilled PVC compound. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 622–631, 2002; DOI 10.1002/app.10352     

Factors influencing magnetic polymer microspheres prepared by dispersion polymerization

Magnetic iron oxide (Fe₃O₄) was prepared by a coprecipitation method. Core–shell composite magnetic polymer microspheres with carboxyl groups were synthesized by the dispersion polymerization of styrene and acrylic acid in the presence of magnetic oxide, and dibenzoyl peroxide was used as an initiator. The synthesized magnetic polymer microspheres were characterized with X‐ray diffraction, transmission electron microscopy, scanning electron microscopy, Fourier transform infrared spectroscopy, and so forth. The results indicated that the product was single‐phase Fe₃O₄, and its average size was about 10 nm. The configuration of the microspheres, which contained carboxyl groups, was spherical, and the average size was about 2 μm. The results of vibrating sample magnetometry tests showed that the magnetic powders produced by different surfactants had different saturation magnetizations. When poly(ethylene glycol) with a weight‐average molecular weight of 4000 was used as a surfactant, the saturation magnetization of the samples reached 69.2 emu/g. The factors that affected the shape, magnetism, size, and distribution of the microspheres were also studied. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

企业网站设计内容第一的原则

企业网站设计内容第一的原则,其根本在于企业网站能否吸引和留住客户或潜在客户,它包含三层意思：网站内容的面向对象要准确清晰;针对目标访客的网站内容要紧扣其兴趣中心,从为其带来价值的角度出发,令其感到有收获;促使目标访客对网站内容建立起充分的信任感、解答其疑问。从网站内容方面保证了企业网站对目标访客的吸引力和访问粘度,从而为企业网站实现其既定目标打下了良好的基础。     

制镁还原罐的研制

从含镁的矿石中提炼金属镁的方法已不仅仅是电解法 ,还有目前广泛采用的真空还原法 (皮江法 ) ,但其所用的还原罐寿命短、价格高一直是困扰着国内、国外生产的难题。用研制出新的材料和改革后的铸造工艺生产出的还原罐 ,较好地解决了上述问题 ;并达到国内、国外先进水平。     

Note: Simultaneous electrical and optical detection of expanding dense partially ionized vapour clouds

The scheme and construction of an electro-optical probe able to collect charge and detect optical emission from expanding dense partially ionized vapour clouds are reported. The instrument can be applied to phenomena such as dust impact ionization and solid target laser ablation. First, results of measurements of expanding plasma cloud formed upon ablating W target are presented. Use of the instrument in different experimental facilities, including tokamak, is discussed.     

A modified expectation maximization algorithm for penalized likelihood estimation in emission tomography

The maximum likelihood (ML) expectation maximization (EM) approach in emission tomography has been very popular in medical imaging for several years. In spite of this, no satisfactory convergent modifications have been proposed for the regularized approach. Here, a modification of the EM algorithm is presented. The new method is a natural extension of the EM for maximizing likelihood with concave priors. Convergence proofs are given.     

The so-called congenital trigger digit: further experience

The authors reviewed 53 patients with 70 congenital trigger digits. Three of these were seen at an early age. Most "congenital" trigger digits present later than the neonatal period. A clear difference exists between trigger thumbs and trigger fingers. In our series, thumbs were more frequently affected, 30% were bilateral and none resolved spontaneously. The long fingers were less frequently affected, and two of them (28%) recovered without operation. All other children had an operative release of the A1 pulley of the flexor tendon sheath, with excellent results.     

Spectral Measurement of the Film-Substrate Index Difference in Proton-Exchanged LiNbO(3) Waveguides

We report the spectral characterization of proton-exchanged lithium niobate (PE:LiNbO(3)) waveguides in terms of the variation of the refractive-index difference between the waveguiding layer and the substrate. The dispersion of the extraordinary refractive-index increase (deltan(e)) is measured from 405 to 1319 nm with several light sources. Two types of proton-exchanged waveguide, prepared under different conditions, are studied. These measurements should be of use in the optimization of PE:LiNbO(3) waveguides for nonlinear optical applications, particularly in second-harmonic generation in the blue-green wavelength region.     

Solid state bonding of Al2O3 with Cu, Ni and Fe: characteristics and properties

A solid state bonding technique under hot pressing was used for joining alumina with thin metal sheets of Ni, Cu and Fe. The microstructure and microchemistry of the ceramic–metal interface and of the fracture interface were examined using scanning electron microscopy (SEM) energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD), in order to identify the adhesion mechanisms and the nature of strength limiting flaws. Interaction between the selected metals and alumina can be physical or physico-chemical in nature: very low amounts of interfacial compounds were formed, depending on the processing conditions and on the presence of oxygen in the system. Fracture and toughness tests indicated that high ceramic–metal interface strengths (up to 177 MPa) were achieved under the adopted processing conditions and that strength and toughness were directly related. Moreover, an increase in hardening in the metal interlayer at a distance of 2–3 m from the interface was observed in the samples with high strength values. The mechanical behaviour was related to several factors that strongly depend on the bonding conditions: plastic deformation of the metal, metal creep, metal intrusion and diffusion into alumina, and chemical reactions at the interface. © 1998 Chapman & Hall