Electric field–temperature phase diagram of sodium bismuth titanate-based relaxor ferroelectrics

The electric field–temperature phase diagrams of three bismuth sodium titanate-based relaxor ferroelectrics are reported, namely 0.94(Na_1/2Bi_1/2TiO₃)–0.06(BaTiO₃), 0.80(Na_1/2Bi_1/2TiO₃)–0.20(K_1/2Bi_1/2TiO₃) and 0.75(Na_1/2Bi_1/2TiO₃)–0.25(SrTiO₃). Relaxor behavior is demonstrated by temperature-dependent dielectric permittivity measurements in the unpoled and poled states, as well as by the field-induced phase transition into a ferroelectric phase from the relaxor phase. From temperature-dependent thermometry measurements, we identified the threshold electric field to induce the ferroelectric phase and obtained the released latent heat of the phase transition. We determined the nonergodic and ergodic relaxor phase temperature range based on the absence or presence of reversibility of the relaxor to ferroelectric transition. For all three compositions, the electric field–temperature phase diagram was constructed and a critical point was identified. The constructed electric field–temperature phase diagrams are useful to find optimum operational ranges of ferroelectrics and relaxors for electromechanical and electrocaloric applications.     

Genetic algorithm to design logical topologies in reconfigurable WDM networks

A new method to design logical topologies based on genetic algorithms is presented. Not only does the algorithm determine which nodes should be connected by means of lightpaths with the aim of minimizing congestion, but it also solves the routing and wavelength assignment problem. In this way, the algorithm guarantees that the logical topology obtained can be embedded in the optical network subject to the available set of resources. The algorithm is effective in terms of both congestion and fairness. For instance, when compared with other work, the congestion is significantly reduced (from 20% to 75% depending on the matrix of traffic considered), and the fairness, when evaluated in terms of the Jain index, is generally higher than 0.94. Moreover, the algorithm brings advantages when employed in dynamic scenarios where the logical topology is frequently reconfigured, as it is fast and, in contrast to other algorithms previously proposed, the calculation process can be stopped at any time (if required) in order to give the best virtual topology found up to the moment.

Operations research in the high-level synthesis of integrated circuits

The acceptance of high-level synthesis tools and methodologies by the design engineers depends on their efficiency in producing circuits with small silicon areas and high operating speeds. This paper shows how this efficiency can be achieved through the use of several operations research techniques applied to the many optimization problems that must be solved. These include: shortest path algorithms, integer programming techniques applied to silicon area minimization, force directed scheduling to optimize the number of operators and cost/speed trade-offs of logical gates. This paper presents several examples providing an operations research solution to each of them.     

Methamphetamine Blocks Adenosine A2A Receptor Activation via Sigma 1 and Cannabinoid CB1 Receptors

Methamphetamine is, worldwide, one of the most consumed drugs of abuse. One important side effect is neurodegeneration leading to a decrease in life expectancy. The aim of this paper was to check whether the drug affects one of the receptors involved in neurodegeneration/neuroprotection events, namely the adenosine A_2A receptor (A_2AR). First, we noticed that methamphetamine does not affect A_2A functionality if the receptor is expressed in a heterologous system. However, A_2AR becomes sensitive to the drug upon complexes formation with the cannabinoid CB₁ receptor (CB₁R) and the sigma 1 receptor (σ₁R). Signaling via both adenosine A_2AR and cannabinoid CB₁R was affected by methamphetamine in cells co-expressing the two receptors. In striatal primary cultures, the A_2AR–CB₁R heteromer complex was detected and methamphetamine not only altered its expression but completely blocked the A_2AR- and the CB₁R-mediated activation of the mitogen activated protein kinase (MAPK) pathway. In conclusion, methamphetamine, with the participation of σ₁R, alters the expression and function of two interacting receptors, A_2AR, which is a therapeutic target for neuroprotection, and CB₁R, which is the most abundant G protein-coupled receptor (GPCR) in the brain.     

Sex Attractant Pheromone from the Rice Stalk Stink Bug, Tibraca limbativentris Stal

The male-produced sex pheromone from the Brazilian rice stalk stink bug Tibraca limbativentris is reported. Olfactometer bioassays with sexually mature males and females showed that males attracted females, which suggests that males release a sex pheromone. Males were not attracted to either sex, nor were females attractive to conspecific females. Attraction of the females to males was highest at night. The headspace volatiles collected from male and female bugs were analyzed by gas chromatography (GC) and GC–mass spectrometry. Two male-specific compounds were identified as isomers of 1′S-zingiberenol, whereas a series of defensive compounds were identified in extracts from both sexes. Zingiberenol has three chiral centers, and the nonselective syntheses used produced two groups of isomers, zingiberenol I containing four isomers, namely (1RS,4RS,1′R)-4-(1′,5′-dimethylhex-4′-enyl)-1-methylcyclohex-2-en-1-ol, and zingiberenol II containing the other four isomers, namely (1RS,4RS,1′S)-4-(1′,5′-dimethylhex-4′-enyl)-1-methylcyclohex-2-en-1-ol. Both groups of stereoisomers were more attractive than hexane controls. The absolute configuration of the insect-produced pheromonal components remains to be elucidated, but the 1′S stereochemistry was established for at least one of the isomers.     

Acid Value,Polar Compounds and Polymers as Determinants of the Efficient Conversion of Waste Frying Oils to Biodiesel

The cost of starting materials for the production of biodiesel is typically 75 % of the final retail price. Oils previously used for frying, waste frying oils (WFO), are a very suitable resource. Repetitive use of oil for frying foods involves high temperature, moisture and aeration for extended periods. The most important deterioration processes triggered by these conditions are hydrolysis and oxidation. In this study, 24 WFO samples of different origins were analyzed and classified as potential starting materials for biodiesel production using three quality parameters representing the main factors that affect the conversion of WFO. These parameters were: acid value, content of polar compounds and content of polymers, which varied in the ranges from 0.2 to 7.6, 14.9 to 43.2 and 0.9 to 15.2 %, respectively. Ester content obtained using conventional transesterification (TE) for WFO conversion decreased with increased levels of WFO deterioration determined by any of the three parameters noted above. TE products obtained had ester content between 81.4 and 95.7 %. Total ester content of a WFO sample with relatively low %AV could be increased to 96.5 % using a two-stage base catalysis TE. Finally, conversion of WFO samples resulted in ester contents of 89.0 and 91.3 %, respectively, when transesterified by conventional TE. After blending up to 10 % with refined oil, the ester content achieved was near 96.5 %. Thus, the blending represents an alternative for obtaining a product with suitable ester content.     

A tribute to professor Roger Sargent: Intellectual leader of process systems engineering

This article and this issue of the AIChE Journal, is a tribute to Professor Roger Sargent who, as pioneer and intellectual leader of process systems engineering, has had a profound impact on the discipline of chemical engineering. Spanning more than five decades, his work has provided a strong mathematical foundation to process systems engineering through the development of sophisticated mathematical and computational tools for the simulation, design, control, operation and optimization of chemical processes. In this article we first give a brief overview of his career that included several leadership positions and the establishment of the Centre for Process Systems Engineering (CPSE) at Imperial College London. We next review his research contributions in the areas of process modeling, differential algebraic systems, process dynamics and control, nonlinear optimization and optimal control, design under uncertainty, and process scheduling. We highlight the tremendous impact that he has had through his students, students' students, and his entire academic family tree, which at present contains over 2000 names, probably one of the largest among the academic leaders of chemical engineering. Finally, we provide a brief overview of him as a modest and charming individual with a wonderful sense of humor. He is without doubt a true intellectual giant who has helped to expand the scope of chemical engineering by providing a strong systems component to it, and by establishing strong multidisciplinary links with other fields. © 2016 American Institute of Chemical Engineers AIChE J, 62: 2951–2958, 2016     

Effect of processing on water absorption and softening kinetics in chickpea (Cicer arietinumL) seeds

The processing effect on the physical properties of chickpea seeds (kabuli type cv Athenas) is reported. Soaking of chickpea seeds in different solutions (distilled water, 0·5% NaHCO₃ and 0·5% CaCl₂) is characterised by a rapid water absorption followed by a decrease in the hydration rate to saturation point. An improvement in chickpea softening rate and water absorption during cooking, with previous 12 h soaking in 0·5% NaHCO₃, was observed. The presence of Ca²⁺ ions delayed the softening process in chickpea seeds. Physicochemical changes associated to the soaking and cooking process necessary for reducing cooking time are discussed. The texturometer method was estimated as a suitable objective method for the evaluation of the cooking degree in chickpea seeds. © 1998 Society of Chemical Industry     

Joint optimization of delay and congestion in wavelength-routed optical networks using genetic algorithms

A new multipurpose genetic algorithm, based on Pareto optimality, is proposed to design logical topologies for wavelength-routed optical networks with the aim of minimizing both the congestion and the end-to-end delay. Simulation results show its efficiency when compared with other previously proposed algorithms, achieving in most cases optimal or near-optimal solutions, and in less time than other methods. Moreover, since the algorithm relies on Pareto optimality, not only does it obtain a single logical topology but a set of them, so that the network designer can easily select the most appropriate one according to the current network requirements.     

Flexural behavior of stratified reinforced concrete: construction,testing, analysis,and design

Stratified concrete poses a promising alternative for construction. Its fresh and hardened properties have been studied at the material level; however, structural behavior in steel reinforced specimens has not been studied. This paper focuses on the flexural behavior of eight stratified reinforced concrete (SRC) specimens representing slices from a slab or non-bearing wall. Specimens with two stratified concrete designs and three steel ratios were tested and compared to estimates from a fiber element numerical model and rectangular stress-block design methods from ACI 318 and Eurocode 2. The results suggest that SRC has similar damage modes as ordinary reinforced concrete (ORC). The fiber element model accurately estimated the measured behavior, while ACI 318 and Eurocode 2 differed from the experimental results by <25%. These prediction accuracies are similar to those for ORC. Therefore, the flexural design of SRC can be done using both fiber element and rectangular stress-block approaches.