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21.
Male rats maintained at 24 C and then shifted to 5 C for 5 days increased food intake and decreased in growth rate and food
conversion. No modification was observed in Δ6 desaturase activity, while Δ9 desaturase activity decreased after this period
of time. These results were confirmed by liver microsomal and mitochondrial fatty acid composition. The phospholipid composition
of liver microsomes was unaltered, whereas in mitochondria, phosphatidylcholine and sphingomyelin decreased and phosphatidylethanolamine
increased due to the cold environment. The influence of food intake and weight changes on fatty acid metabolism was studied
using (i) rats maintained at 5 C with restricted food intake to match the food intake of those kept at 24 C with food ad libitum
and (ii) rats maintained at 24 C whose food intake was also restricted so that their growth rate would be the same as that
of rats maintained at 5 C with food ad libitum, respectively. These results indicate that the negative metabolic balance state
of these cold conditions is not an active factor modifier of Δ6 desaturase activity, whereas it decreases Δ9 desaturase activity,
reflecting the lipogenic characteristics of the latter enzyme. 相似文献
22.
A priori design of catalysts is not yet possible. Such task would demand unavailable scientific knowledge of the correlations among synthesis parameters and resulting solid state and surface structures, on the one hand, and among those atomic-level structural details and their catalytic functions, on the other hand. To avoid testing every possible combination, therefore, the applied chemist or chemical engineer must identify empirical correlations underlying the existing experimental data base.
The ability of artificial neural networks to identify complex correlations and to predict the result of experiments has recently generated considerable interest in various areas of science and engineering. In this paper, neural networks are used to identify composition-performance relationships in automobile exhaust catalysts.
This work employs an artificial neural network technique to do a sensitivity analysis of the conversions of pollutant gases as a function of the catalyst composition and the operating conditions. This approach converges on the optimum catalyst composition and operating condition in order to produce specified conversions of carbon monoxide, hydrocarbons and nitrogen oxides, to carbon dioxide, water and di-nitrogen respectively. 相似文献
The ability of artificial neural networks to identify complex correlations and to predict the result of experiments has recently generated considerable interest in various areas of science and engineering. In this paper, neural networks are used to identify composition-performance relationships in automobile exhaust catalysts.
This work employs an artificial neural network technique to do a sensitivity analysis of the conversions of pollutant gases as a function of the catalyst composition and the operating conditions. This approach converges on the optimum catalyst composition and operating condition in order to produce specified conversions of carbon monoxide, hydrocarbons and nitrogen oxides, to carbon dioxide, water and di-nitrogen respectively. 相似文献
23.
A.?de?Lucas J.?Rincón I.?GraciaEmail author 《Journal of the American Oil Chemists' Society》2003,80(2):181-188
Supercritical CO2 extraction is a viable alternative process for the extraction of high-quality oil from olive husk (also known as olive pomace),
a residue obtained in the production of olive oil. We analyzed the effect of pressure (100–300 bar), temperature (40–60°C),
solvent flow (1–1.5 L/min), and particle size (0.30–0.55 mm) on four important quality parameters of the oil extracted with
CO2: tocopherol concentration, extinction coefficients at 232 and 270 nm, and saponification value. Response surface methodology
was used to obtain mathematical expressions related to the operating variables and parameters studied. Results from these
experiments were also used to design a three-step sequential CO2 extraction procedure to obtain a higher-quality extract. The optimal operational sequence consisted of a first extraction
step at 75 bar for 1 h using 1% (vol/vol) ethanol modifier, followed by a second extraction stage at 350 bar for 2.5 h without
ethanol and a third step, also at 350 bar, for 2.5 h but using ethanol. These extraction conditions obtained an intermediate
fraction of oil with 64% yield and all normal parameters according to European Commission food legislation. This fraction
is suitable without any further refining. On the contrary, the oils obtained by hexane extraction and by conventional supercritical
CO2 extraction at optimal conditions are suitable for human consumption after further refining. This last finding may result
in improved economics of the sequential CO2 extraction process compared to the conventional extraction method with hexane. 相似文献
24.
Raul C. Maranhão Thais B. Cesar Suzana R. Pedroso-Mariani Mario H. Hirata Carlos H. Mesquita 《Lipids》1993,28(8):691-696
A protein-free microemulsion (LDE) with a lipid composition resembling that of low-density lipoprotein (LDL) was used in metabolic
studies in rats to compare LDE with the native lipoprotein. LDE labeled with radioactive lipids was injected into the bloodstream
of male Wistar rats, and plasma kinetics of the labeled lipids were followed on plasma samples collected at regular intervals
for 12 h after injection. The 24-h LDE uptake by different tissues was also measured in tissue samples excised after the animals
had been sacrificed. We found that LDE plasma kinetics were similar to those described for native LDL [fractional clearance
rate (FCR) of cholesteryl ester, 0.42±0.11 h−1]. The major site for LDE uptake was the liver, and the tissue distribution of the LDE injected radioactivity was as one would
expect for LDL. To test whether LDE was taken up by the specific LDL receptors, the LDE emulsion was injected into rats treated
with 17α-ethinylestradiol, which is known to increase the activity of these receptors; as expected, removal of LDE from the
bloodstream increased (FCR=0.90±0.35 h−1). On the other hand, saturation of the receptors that remove remnants by prior infusion of massive amounts of lymph chylomicrons
did not change LDE plasma kinetics. These results indicate that LDE is cleared from plasma by B,E receptors and not by the
E receptors that remove remnants. Incorporation of free cholesterol into LDE increased LDE plasma clearance. Incubation studies
also showed that LDE incorporates a variety of apolipoproteins, including apo E, a ligand for recognition of lipoproteins
by specific receptors. Our data suggest that LDE can be a useful tool to test LDL metabolism and B,E receptor function. 相似文献
25.
Antonio G. González Ignacio A. Jiménez Mercedes P. Núñez Angel G. Ravelo Isabel L. Bazzocchi Orlando M. Muñoz Marcelino A. Aguilar 《Journal of chemical ecology》1994,20(4):823-830
Three new dihydro--agarofuran sesquiterpenes from two species ofMaytenus were isolated and their structures were elucidated by means of1H and13C NMR studies. The differences and similarities noted in the chemical content of the dihydro--agarofuran sesquiterpenes from the fourMaytenus species from Chile are in line with the taxonomic characterization of these species; their geographical distribution is also given. 相似文献
26.
Nisha Sheth Carl Greenley Raul Bermejo John C. Mauro Carlo G. Pantano Seong H. Kim 《Journal of the American Ceramic Society》2021,104(9):4550-4558
Water or acid soaking surface treatments have been shown to increase the mechanical strength of soda-lime silicate (SLS) glasses. This increase in strength has traditionally been attributed to effects related to residual stress or changes in fracture resistance. In this work, we report experimental data that cannot be explained based on the existing knowledge of glass surface mechanics. In dry environments, annealed and acid-leached SLS surfaces have comparable crack initiation stress and fracture stress as measured by Hertzian indentation and biaxial bending tests, respectively. Yet, in the presence of humidity, acid-leached surfaces have higher failure stress than the annealed surfaces. This apparent enhancement in the crack resistance of the acid-leached surface of SLS glass in humid environments supports the hypothesis that acid-leached surface chemistry can lower the transport kinetics of molecular water to critical flaws. 相似文献
27.
28.
29.
Ricardo Villar-Ribera Francisco Hernández-AbadJosé Ignacio Rojas-Sola David Hernández-Díaz 《Mechanism and Machine Theory》2011,46(6):820-830
The transmission of information has gone through various stages of evolution throughout its history. A stage before that of the electric telegraph was the so-called aerial/optical telegraph. It was developed towards the end of the 18th century and was in service until the middle of the 19th century. Chappe's system was widely used in France, and was the first to be in consistent use. However, a new and technologically superior system was developed soon afterwards which superseded it. Its inventor was Agustín de Betancourt, considered by some authors one of the founders of the Theory of Machines and Mechanisms, who, together with the distinguished clockmaker Breguet, presented it to the French Authorities in the turbulent decade of the 1790s.This article presents a historical review of this telegraph and analyzes its technical characteristics. It presents analytically, numerically and graphically some of the statements made about the telegraph, and corrects other subsequent observations. Lastly, a detailed reconstruction of the telegraph is made using different advanced CAD techniques, which provide an accurate static and dynamic view of each of its parts. 相似文献
30.
Biomechanics of human head has been widely studied since several decades. At a mechanical level, the use of engineering allowed investigating injury mechanisms developing numerical models of adult head. For children, the problem is more difficult and evaluating child injury mechanisms using data obtained from scaling adult injury criteria does not account for differences in morphology and structure between adults and children. During growth, child head undergoes different modifications in morphology and structure. The present paper compares the anthropometry and numerical simulations of a child head model based on medical CT scans to a child head model developed by scaling an adult head model using the method proposed by Mertz [H.J. Mertz, A procedure for normalizing impact response data, SAE paper 840884, 1984]. These analysis point out significant differences showing that scaling down an adult head to obtain a child head does not appear relevant. Biofidelic and specific child geometry is needed to investigate child injury mechanisms. 相似文献