Deposition of AlN films by reactive sputtering: Effect of radiofrequency substrate bias

Piezoelectric AlN thin films were deposited on Silicon substrates by triode reactive sputtering. The variation of residual stress versus bias voltage on the substrate was investigated. A compressive stress was always observed with a maximum value for a negative substrate bias of 50 V. For higher negative bias voltage values, the compressive stress decreases. X-ray diffraction measurements showed two kinds of growth orientation. First, without bias voltage, films are well crystallized and (002) oriented. Second, with bias voltage, the (002) orientation disappears and a small peak appears (situated in the 2θ = 32°-33° range) which can be attributed to (100) orientation. Finally, the influence of compressive stress and ion bombardment on the change of orientation is discussed.     

Robust non-fragile LQ controllers: The static state feedback case

This paper describes the synthesis of non-fragile or resilient regulators for linear systems. A general framework for fragility is described using state-space methodologies, and the LQ/H₂ static state-feedback problem is examined in detail. We discuss the multiplicative structured uncertainties case, and propose remedies of the fragility problem using an optimization programming framework via matrix inequalities. A special case that leads to a convex optimization framework via linear matrix inequalities (LMIs) will be considered. The benchmark problem is taken as an example to show how special controller gain variations can affect the performance of the closed-loop system.     

Performance of Primary Users in Spectrum Sharing Cognitive Radio Environment

This paper investigates the performance of the primary user in a multiuser cognitive radio environment. Using spectrum sharing method, multiple cognitive users compete to share a channel dedicated to the primary user in order to transmit their data to a common receiver unit. Only one cognitive user is scheduled to share the channel, and to do so, its transmit power should not increase the primary user’s outage probability above a certain limit. The average bit error rate and the average channel capacity of the primary user are derived in this setup for different cognitive scheduling schemes. The performance measures of the primary user are found to depend on the cognitive user’s scheduling criterion and on the parameters of the communication environment.     

Synthesis and characterization of uniformly coated particles (cobalt compounds on copper compounds)

Spherical particles (～3 μm) of copper(II) oxalate were produced in the form of precipitated solids by gently mixing aqueous solutions of oxalic acid and copper nitrate with predetermined concentrations at room temperature. These particles were isolated from the mother liquor and then coated with cobalt basic carbonate. The coating trials involved heating of the aqueous dispersions, containing known amounts of the dispersed copper oxalate particles (cores), urea, and cobalt nitrate, at 70–85 °C for various periods of time with constant stirring. The heating process decomposed urea, increased pH, liberated carbonate ions, which resulted in the precipitation of the dissolved cobalt ions in the form of shells of cobalt basic carbonate around each core particle. The coating process was sensitive to the applied experimental parameters, since uniformly coated particles were obtained under a narrow range of coating mixture composition. In the absence of the cores, the same reactants solutions produced coating precursor particles (cobalt basic carbonate), when subjected to similar heating conditions. Physical and chemical analyses indicated that the coating material of the coated particles and the coating precursor particles had the same chemical compositions. The as-prepared core, coating precursor, and coated particles were converted into oxide forms by heating their dry powders at elevated temperatures under controlled heating conditions. The heat treatment produced obvious changes in the surface morphology of these particles due to loss of material. Moreover, the heat-treated particles preserved shape integrity to a maximum extent, showing their thermal stability. Selected batches of the as-prepared and heat-treated products were characterized by various physical methods.     

Electrical properties of oilshale rocks

The characterization of electric properties of oilshale deposit is reported. The scanning electron microscopy and the results of the dielectric constants show that the deposit is a heterogeneous composite material containing some conducting and insulating microstructural units. The components of the equivalent input impedance measured at microwave frequencies (8 to 12 GHz) and the impedance at low frequencies (0.5 Hz to 30 kHz) showed frequency dependence. The real and imaginary components of the permittivity determined from the impedance data obtained at low frequencies showed an exponential decrease with frequency. The observed frequency dependence of the rock permittivity is ascribed generally to a Maxwell-Wagner type of mechanism. Also it was observed that the conductivity is almost independent of the frequency below 1 kHz and increases with frequency above this range. The values obtained for the conductivity at low frequencies indicate that the rock has an intermediate electrical conduction due to some mineralized metallic complexes and carbon content.     

The effect of moisture on buckle delamination of thin inorganic layers on a polymer substrate

Moisture-induced buckle delamination of thin inorganic layers on a polymer substrate was studied. Moisture has been found to have a significant effect on the failure mode. Experimentally, an increase in the buckle width, height and the total buckle delamination length with time and humidity was observed. Moreover, a transition from straight to telephone-cord buckle pattern was taken place in a humid environment. Applying only a uniaxial compressive strain on the thin layers did not result in the transition from straight to telephone-cord. For a compliant substrate the transition from straight to telephone-cord buckle occurred at significantly higher ratio of residual strain over critical buckling strain than for a rigid substrate. A simple model for buckling was applied. Using the energy release rate, the interfacial toughness was investigated as a function of relative humidity.     

Electrochemical and Theoretical Investigation for the Protection of Aluminum Corrosion in Hydrochloric Acid using Some Azole Derivatives

Protection of Metals and Physical Chemistry of Surfaces - Three compounds of azole derivatives were investigated as inhibitors for the dissolution of aluminum (Al) in 0.5 M HCl solution using...