Experimental characterization of Ti6Al4V T joints welded through linear friction welding technique: microstructure and NDE

Linear friction welding (LFW) is an innovative solid-state welding technique that allows to manufacture joints with high mechanical properties. This technology has various applications in the aerospace field; in particular it is used to weld massive structural components made of Ti6Al4V. This paper deals with the experimental study of Ti6Al4V T-joints welded through LFW, with particular focus on the effectiveness of ultrasonic control in detecting and distinguishing welding defects within the joints. Aiming to this scope, joints with different properties were manufactured and tested:some were free from defects but with different metallurgy, and some had different types of defects. The results obtained proved that the ultrasonic control was an effective method to detect and identify defects in linear friction welded titanium joints, moreover it was possible to get information regarding the microstructure and in particular the extension of the different metallurgical zones induced by the welding process.     

Characterization of Active Dry Wine Yeast During Starter Culture (Pied de Cuve) Preparation for Sparkling Wine Production

The preparation of yeast starter culture (Pied de Cuve) for producing sparkling wine with the traditional method is a key factor for manufacturing a good Prise de mousse. In this paper, the evolution of total yeast population, its viability during Pied de Cuve preparation, and the pressure profile during the 2nd fermentation in 2 different base wines made from Bombino bianco and Chardonnay grapes were investigated using 4 different commercial active dried yeasts. The study proves that despite the initial differences observed throughout the acclimatization phase, all the tested strains showed similar results on either the total population (from 8.2 × 10⁷ cells/mL to 1.3 × 10⁸ cells/mL) or cellular viability (from 70% to 84%). Independently from the base wine tested, the kinetic of sugar consumption was faster during the gradual acclimatization to the alcoholic medium (phase II) and slower during the preparation of starter culture in active growth phase (phase III). During both of these phases Saccharomyces cerevisiae bayanus Vitilevure DV10^® (Station ?notechnique de Champagne) proved to have a higher sugar consumption rate than the other strains. During the Prise de mousse, S. cerevisiae bayanus Lalvin EC‐1118^® (Lallemand) reached the maximum pressure increase within time in both base wines.     

A densification equation derived from the stress-deformation analysis of uniaxial cold compaction of metal powder mixes

A new densification equation for uniaxial cold compaction of four low alloy steel powders was determined from the deformation vs. mean axial stress correlation. Both deformation and stress are averaged along the height of the powder column. A power law relation, with two parameters representing the plasticity and the inverse of the resistance to deformation (densification) of the powder mix, respectively, fits the curves that are divided in two steps, distinguished by the prevailingdeformation/densification mechanism (rearrangement or plastic deformation).

Densification of the four powder mixes is greatly affected by the starting density in the die cavity, while the chemical composition of the base iron powder has a less significant effect.     

Comparison of Electromagnetic Wave Sensors with Optical and Low-frequency Spectroscopy Methods for Real-time Monitoring of Lead Concentrations in Mine Water

The feasibility of using novel electromagnetic wave sensors for real-time monitoring of metal pollution in water was assessed. Five solutions with different concentrations of lead (0, 1, 10, 50, 100 mg/L) were measured using several sensing methods: UV–Vis spectroscopy, low frequency capacitance and resistance measurements, and two sensing systems based on microwave technology. With this last approach, two sensing devices were used: a resonant cavity and a planar sensor with gold interdigitated electrode design printed on a PTFE substrate with a protective PCB lacquer coating. Results confirmed the ability of these systems to quantify the lead concentration as changes in spectrum signal at specific frequencies of the electromagnetic spectrum. Spectra were unique, with clearly observed shifts in the resonant frequencies of the sensors when placed in direct contact with different lead solutions, demonstrating the possibility of continuous monitoring with great sensitivity, selectivity, and high spatial and temporal resolution. Consequently, determination of trace and toxic metals using microwave spectroscopy is a promising alternative to traditional grab-sampling and laboratory based analyses. On-line and continuous monitoring of real-time metal concentrations offers the potential for a more effective emergency response and the platform for better scientific understanding and remediation of contaminated mine drainage.     

CFRP laminates under low‐velocity impact conditions: Influence of matrix and temperature

In this work, carbon fiber‐reinforced composites (CFRP), respectively, based on a vynilester and epoxy resin were loaded under low‐velocity impact condition to highlight the influences of different matrices and temperature on their dynamic response. In particular, measurements were performed at room and the low temperature of ?25°C on samples simply supported by air to exactly simulate the incidental impact during the structure service and having the same thickness. Impact tests were carried out at penetration to obtain the complete load–displacement curve and to measure the penetration energy, and at different energy levels, 5, 10, and 20 J, to investigate the influence of the matrix on the damage start and propagation. After the impact tests, the specimens were nondestructively investigated by the ultrasound technique to measure the delamination. The interesting results obtained on carbon fiber laminates impacted at room and lower temperature are here reported and compared. In general, better behavior was noted for vinyl ester‐based composites, extensively used in the naval field, thanks to their low absorption for humidity. POLYM. ENG. SCI., 59:2429–2437, 2019. © 2019 Society of Plastics Engineers     

Si-substituted hydroxyapatite nanopowders: Synthesis, thermal stability and sinterability

Synthetic hydroxyapatites incorporating small amounts of Si have shown improved biological performances in terms of enhanced bone apposition, bone in-growth and cell-mediated degradation.This paper reports a systematic investigation on Si-substituted hydroxyapatite (Si 1.40 wt%) nanopowders produced following two different conventional wet methodologies: (a) precipitation of Ca(NO₃)₂·4H₂O and (b) titration of Ca(OH)₂. The influence of the synthesis process on composition, thermal behaviour and sinterability of the resulting nanopowders is studied.Samples were characterised by electron microscopy, induced coupled plasma atomic emission spectroscopy, thermal analysis, infrared spectroscopy, N₂ adsorption measurements, X-ray diffraction and dilatometry. Semicrystalline Si-substituted hydroxyapatite powders made up of needle-like nanoparticles were obtained, the specific surface area ranged between 84 and 110 m²/g. Pure and Si-substituted hydroxyapatite nanopowders derived from Ca(NO₃)₂·4H₂O decomposed around 1000 °C. Si-substituted hydroxyapatite nanopowders obtained from Ca(OH)₂ were thermally stable up to 1200 °C and showed a distinct decreased thermal stability with respect to the homologous pure sample. Si-substituted hydroxyapatites exhibited higher sintering temperature and increased total shrinkage with respect to pure powders. Nanostructured dense ceramics were obtained by sintering at 1100 °C Si-substituted hydroxyapatites derived from Ca(OH)₂.     

Mixed Discontinuous Galerkin Approximation of the Maxwell Operator: Non-Stabilized Formulation

A non-stabilized mixed discontinuous Galerkin method for the discretization of the Maxwell operator on simplicial meshes is studied. In contrast to the stabilized scheme introduced in Houston, Perugia and Schötzau, Siam J. Numer. Anal., 42: 434–459, 2004, the proposed formulation contains no normal-jump stabilization; instead, it is based on discontinuous mixed-order elements for the approximation of the unknowns. A priori error bounds in the energy norm are derived that show convergence rates of the order in the mesh size h. The error analysis relies on suitable decompositions of discontinuous spaces and on stability properties of the underlying conforming spaces. The formulation is tested on a set of numerical examples in two space dimensions.This revised version was published online in July 2005 with corrected volume and issue numbers.     

Correlating structure with fluorescence emission in phase-separated conjugated-polymer blends

Blends of conjugated polymers are frequently used as the active semiconducting layer in light-emitting diodes and photovoltaic devices. Here we report the use of scanning near-field optical microscopy, scanning force microscopy and nuclear-reaction analysis to study the structure of a thin film of a phase-separated blend of two conjugated polymers prepared by spin-casting. We show that in addition to the well-known micrometre-scale phase-separated morphology of the blend, one of the polymers preferentially wets the surface and forms a 10-nm-thick, partially crystallized wetting layer. Using near-field microscopy we identify unexpected changes in the fluorescence emission from the blend that occurs in a 300-nm-wide band located at the interface between the different phase-separated domains. Our measurements provide an insight into the complex structure of phase-separated conjugated-polymer thin films. Characterizing and controlling the properties of the interfaces in such films will be critical in the further development of efficient optoelectronic devices.     

The Design Guidelines (DGLs), a knowledge-based system for industrial design developed accordingly to ISO-GPS (Geometrical Product Specifications) concepts

Product design and optimisation today involves so many fields of expertise, many of which are in rapid evolution, that it can be very difficult for the designer to manage them. This paper describes the development of the DGLs (Design Guidelines), a knowledge-based tool that could be of great help to designers and engineers in modifying their products to get compatibility with different manufacturing and verification technologies. The current release of the DGLs, heavily influenced by the adoption of some ISO-GPS (Geometrical Product Specification) concepts, has been validated using the Rapid Prototyping technique called FDM (Fluid Deposition Modelling) and the CMM (Coordinate Measuring Machine) verification technique.