Cooperative Catalysis: A New Development in Heterogeneous Catalysis

Whereas cooperative effect in catalysis, in which multiple chemical interactions participate cooperatively to achieve significant enhancement in catalytic activity and/or selectivity, is common in enzymatic reactions, it has been sparingly employed in heterogeneous catalytic systems. Here, some recent literature examples of abiotic catalysis, with emphasis on heterogeneous systems, that employ cooperation between acid and base and two metal centers are briefly described to demonstrate the principles involved. Since effective cooperation places strict demand on the positions of the different functional groups, new synthetic methods and strategies are needed to design and construct structures useful for cooperative catalysis. Recent progress in our laboratory in synthesizing new nanocage structures that possess molecular-size cavities, atomic layer thick, porous shells with internal functional groups is described. These recent developments suggest possibilities of new catalytic transformations that have not been attempted before. This is illustrated with two speculative examples utilizing cooperative catalysis: oxidative hydrolytic desulfurization and terminal carbon activation of hydrocarbon molecules.     

Manufacturing and structural safety evaluation of a composite train carbody

This paper explains the manufacturing process of a composite train carbody with a sandwich composite structure for bodyshell and a stainless steel structure for the under frame. In addition, the structural behavior and safety of the composite carbody of the Korean tilting train was investigated by the static load tests. From the test results, the stiffness of the composite carbody met the specified design. In the aspect of strength, the maximum stress of the composite bodyshell was of 12.2% of strength of CF1263 carbon/epoxy.     

Evaluation of recursive queries with extended rules in deductivedatabases

In order to extend the expressive power of deductive databases, a formula that can have existential quantifiers in prenex normal form in a restricted way is defined as an extended rule. With the extended rule, we can easily define a virtual view that requires a division operation of relational algebra to evaluate. The paper addresses a recursive query evaluation where at least one formula in a recursive rule set is of an extended rule. We investigate transformable recursions as well as four cases of non-transformable recursions of transitive-closure-like and linear type. The work reveals that occurrence of an existentially quantified variable in the extended recursive body predicate might dramatically limit the level of recursive search. In particular, the number of iterations to answer extended queries can be determined, independently of database contents     

The decision-making properties of discrete multiple exponentialbidirectional associative memories

A method for modeling the learning of belief combination in evidential reasoning using a neural network is presented. A centralized network composed of multiple exponential bidirectional associative memories (eBAM's) sharing a single output array of neurons is proposed to process the uncertainty management of many pieces of evidence simultaneously. The stability of the proposed multiple eBAM network is proved. The sufficient condition to recall a stored pattern pair is discussed. Most important of all, a majority rule of decision making in presentation of multiple evidence is also found by the study of signal-noise-ratio of multiple eBAM network. A guaranteed stable state condition, i.e., the condition for the fastest recall of a pattern pair, is also studied. The result is coherent with the intuition of reasoning.     

Information-theoretic distortion measures for speech recognition

A wide variety of speech recognition distortion measures have been proposed and tested, including some especially effective ones. It is shown that there is a general framework, based on the concepts of information theory, linking most of these measures. The distortion measure between any two speech spectra can be defined in terms of the distortions between the associated probability distributions. This general framework defines three broad families of distortion measures for speech recognition and provides a consistent way of combining the energy and the spectral information of a phonetic event. In addition, the cepstral-domain representation for several distortion measures is derived, allowing comparison of these measures in a domain that also yields convenient equations for their practical implementation     

Optimization of the power ascension path for a boiling water reactor using genetic algorithms

To ensure the core status can meet the requirements of thermal limits, stability and other constraints during the power ascension process of a nuclear power plant, operators usually gradually increase power based on onsite measurements and experience. To reduce the operator’s burden, this research develops a method to find an optimal power ascension path that can be followed by operators. The power ascension path is formulated as a multiobjective optimization problem with the following constraints: power ascension time, thermal limits, core stability and maximum rod line. A genetic algorithm is adopted to obtain the optimal power ascension path. The results show that using our approach full power can be achieved quickly, while maintaining reasonable margins of thermal limit and stability, in addition to satisfying maximum rod line criteria.