A hybrid DNN–LSTM model for detecting phishing URLs

Neural Computing and Applications - Phishing is an attack targeting to imitate the official websites of corporations such as banks, e-commerce, financial institutions, and governmental...     

Kinetics of emulsifier–free emulsion polymerization of methyl methacrylate

The influences of polymerization temperature, initiator and monomer concentrations, ionic strength of the aqueous phase, as well as ethylene glycol dimethacrylate (EGDM) co-monomer, on the kinetics of the emulsifier-free emulsion polymerization of methyl methacrylate (MMA) and on the properties of the resulting poly(methyl methacrylate) (PMMA) lattices were studied. The polymerizations were carried out using potassium persulfate (KPS) as the initiator. Monodisperse PMMA lattices with particle diameters varying between 0.14–0.37 μm and polymer molecular weights of the order 0.4 × 10⁶ to 1.2 × 10⁶ g/mol were prepared. The initial rate of polymerization increases with increasing temperature, KPS-MMA mole ratio, EGDM content, or with decreasing ionic strength of the aqueous phase. It was shown that the bead size can be limited by reducing the monomer concentration or by using the cross-linking agent EGDM. The ionic strength of the aqueous phase has a dominant effect on final particle diameter and polymer molecular weight. The uniformity of the latex particles increases as the temperature increases or as the initiator concentration decreases. The experimental results can be reasonably interpreted by the homogeneous nucleation mechanism of the emulsifier-free emulsion polymerization of MMA. © 1996 John Wiley & Sons, Inc.     

Photosynthetic bacterial growth and productivity under continuous illumination or diurnal cycles with olive mill wastewater as feedstock

Photofermentative hydrogen production from olive mill wastewater by Rhodobacter sphaeroides O.U.001 was investigated under different regimes of illumination. The analysis included measurements of biomass accumulation, H₂-production, high-value bio-product accumulation (polyhydroxybutyrate and carotenoid) and measurements of the medium pH as a function of growth and productivity. Batch cultures were grown under continuous light (CL) or 12 h light/12 h dark (12L/12D) diurnal cycles. Growth under CL or 12L/12D cycles yielded about the same amount of biomass (0.5 g dry cell weight per L culture) and volume of H₂ gas (50 ml H₂ per L culture). On the other hand, 12L/12D cultures showed a pronounced lag in biomass and H₂ accumulation. Advances described in the work would find application in lowering operational costs for hydrogen production by better management of the energy source and cheap feedstock utilization. Compare to CL, equivalent amount of hydrogen gas accumulation within shorter time interval denoted to have two times higher hydrogen production rate and light conversion efficiencies via diurnal cycles, which can yield 50% savings on consumed energy source.     

Preparation and characterization of sulfonated polysulfone/titanium dioxide composite membranes for proton exchange membrane fuel cells

In the present study, sulfonated polysulfone (sPS)/titanium dioxide (TiO₂) composite membranes for use in proton exchange membrane fuel cells (PEMFCs) were investigated. Polysulfone (PS) was sulfonated with trimethylsilyl chlorosulfonate in 1,2 dichloroethane at ambient temperatures. It was shown that the degree of sulfonation is increased with the molar ratio of the sulfonating agent to PS repeat unit. The degree of sulfonation was determined by elemental analysis and ¹H NMR was performed to verify the sulfonation reaction on the PS. Sulfonation levels from 15 to 40% were easily achieved by varying the content of the sulfonating agent. Composite membranes were prepared by blending TiO₂ with sPS solution in DMAC (5 wt.%) by the solution casting procedure. The membranes have been characterized by thermal analysis, water uptake, proton conductivity measurements and single cell performance. The addition of TiO₂ increased the thermal stability but high filler concentrations decreased the miscibility of the composite component, and resulted in brittle membranes. The conductivity values in the range of 10⁻³–10⁻² S/cm were obtained for composite membranes. The conductivities of the membranes show similar increasing trend as a function of operating temperature. The membranes were tested in a single cell operating at 60–85 °C in humidified H₂/O₂. Single fuel cell tests performed at different operating temperatures indicated that sPS/TiO₂ composite membrane is more hydrodynamically stable and also performed better than sPS membranes. The highest performance of 300 mA/cm² was obtained for sPS/TiO₂ membrane at 0.6 V for an H₂–O₂/PEMFC working at 1 atm and 85 °C. The results show that sPS/TiO₂ is a promising membrane material for possible use in proton exchange membrane fuel cells.     

Photofermentative hydrogen production from volatile fatty acids present in dark fermentation effluents

In the present study, the growth and hydrogen production of Rhodobacter sphaeroides O.U. 001, was investigated in media containing five different volatile fatty acids (VFA) individually (malate, acetate, propionate, butyrate and lactate) and in media containing mixtures of these acids that reflect the composition of dark fermentation effluents. The highest hydrogen production rate was obtained in malate (24 ml_hydrogen/l_reactor h) and the highest biomass concentration was obtained in acetate containing media (1.65 g/l). The substrate conversion efficiencies for different volatile fatty acids were found to vary between 14 and 50%. The malate and butyrate consumption rates were first order with consumption rate constants of 0.026 h⁻¹ and 0.015 h⁻¹, respectively. In the case of substrate mixtures, it was observed that the bacteria consumed acetate first, followed by propionate and then butyrate. It was also found that the consumption rate of the main substrate significantly increased when the minor substrates were depleted.     

Learning to rank by using multivariate adaptive regression splines and conic multivariate adaptive regression splines

Learning to rank is a supervised learning problem that aims to construct a ranking model for the given data. The most common application of learning to rank is to rank a set of documents against a query. In this work, we focus on point‐wise learning to rank, where the model learns the ranking values. Multivariate adaptive regression splines (MARS) and conic multivariate adaptive regression splines (CMARS) are supervised learning techniques that have been proven to provide successful results on various prediction problems. In this article, we investigate the effectiveness of MARS and CMARS for point‐wise learning to rank problem. The prediction performance is analyzed in comparison to three well‐known supervised learning methods, artificial neural network (ANN), support vector machine, and random forest for two datasets under a variety of metrics including accuracy, stability, and robustness. The experimental results show that MARS and ANN are effective methods for learning to rank problem and provide promising results.     

The effect of hydrodynamic parameters on the production of Pickering emulsions in a baffled stirred tank

Pickering emulsions are potential industrial scale alternatives to surfactant-based emulsions. The stability of Pickering emulsions depends on the physicochemical nature of the liquid–particle interface and the hydrodynamic conditions of the production process. This article investigates the effect of hydrodynamic conditions on the drop size of concentrated Pickering emulsions in baffled stirred tanks. Oil in water emulsions composed of silicon oil, water, and hydrophilic glass beads as stabilizing particles were produced. Two impellers were used at different sizes: Rushton turbine (RT) and pitched blade turbine. The effects of power per mass, Reynolds number, tip speed, and Weber number on the droplet sizes were studied. The energy dissipated around the impeller and the size of the impeller high shear zone were found to be critical to the emulsion droplet sizes. The breakup and droplet-particle contact mechanism of the RT was found to be more favorable for the production of the Pickering emulsions.     

Development of MgO:TiO2 thin films for gas sensor applications

In this study, structural, morphological and optical properties, and gas sensor performance of magnesium oxide (MgO) doped titanium dioxide (TiO₂) thin films were investigated in detail. Gas sensor metallic patterns were fabricated on Si substrate using traditional photolithographic technique. MgO doped TiO₂ thin films were deposited on formed Pt electrode surface by confocal sputtering (co-sputtering) system as the active layer. Thin film characterizations were realized by using secondary ion mass spectroscopy (SIMS), atomic force microscope (AFM) and UV–Vis Spectrometer (UV–Vis). Gas sensing measurements were performed by gas sensing test system against methane gas at working temperature of 300?°C. To evaluate deposition and thermal annealing effects on the sensing performance, sensors were tested under gas. The sensitivity and response/recovery time of gas sensors were measured in 1000?ppm. MgO doped TiO₂ based sensor at substrate temperature of 100?°C has high sensitivity and short response/recovery time.     

Shear strength of alluvial soils reinforced with PP fibers

Bulletin of Engineering Geology and the Environment - Alluvial soils can be defined as sediments that have not completed their geological formation have high void ratios, low bearing capacity, and...