Spiral growth of one dimensional titania nanostructures using anodic oxidation

One dimensional spiral titania nanostructures were obtained by anodization of pure titanium from fluoride containing solutions of phosphoric acid. The formation of nanotubes was found to be dependant on current density. Field Emission Scanning Electron Microscopy (FESEM) shows the diameter of tubes around 70-100 nm which is consistent with the High Resolution Transmission Electron Micrographs (HRTEM) and Atomic Force Microscopy (AFM) images. HRTEM showed the one dimensional growth as spiral in nature which was also supported by AFM images. This anisotropic growth is compared with the possible growth mechanisms.     

Microstructural modification and ageing behaviour of the Al–17Si–5Cu alloy using a novel approach

A novel short duration heat treatment schedule is proposed in the present investigation for the Al-17?wt-% Si-5?wt-% Cu alloy (AR alloy). The existing heat treatment uses long duration (4–24?h) holding at solutionising temperature prior to ageing treatment. In the present investigation, the AR alloy is subjected to isothermal holding at 590°C for 15?min followed by warm water quenching prior to the normal ageing schedule. Detailed microstructural investigations involving size and shape of primary as well as eutectic Si particles, porosity measurements along with hardness and tensile property characterisation are carried out to find the effect of isothermal heat treatment. The study reveals considerable improvement in microstructure and mechanical properties after this isothermal heat treatment.     

I: Dispersibility of robust alumina particles in non-aqueous solution

This article presents the preparation of well dispersed alumina slurries containing relatively large alumina particles that can withstand accelerated weather conditions. Besides using conventional dispersants such as phosphate esters and menhaden fish oil, dispersants widely used in the surface coatings industries such as Disperbyk 110 and Triton X 100 have also been employed. However, sedimentation tests, sediment density, viscosity and gloss measurements indicate the failure of the anionic dispersants as well as menhaden fish oil to disperse the alumina particles in non-aqueous medium. Instead the binder polyvinyl butyral itself acts as the best dispersant. The well dispersed alumina slurry is stabilized in the presence of a commercially available rheology modifier, Bentone SD2 for a period of 144 h at 60 °C. The rheological behavior of the aged sample was studied under various conditions. Although a rise in viscosity of the suspension was observed when the slurry was exposed to accelerated weather conditions, a lower shear thinning index and higher gloss values indicate a better dispersion state with aging.     

3D Coordination Network of Ag(I) Ions with μ 3 -Bridging Melamine Ligands

Abstract  

A new 3D silver complex [Ag(mela)(H₂O)(NO₃)]_n (1) (mela = melamine or 2,4,6-triaminotriazine) is synthesized and characterized by single crystal X-ray diffraction, IR, and elemental analysis. The structural characterization shows that the compound crystallizes in space group C c, a = 8.181(2), b = 10.269(3) c = 11.347(3) ?, β = 105.88(2)°, Z = 4. Out of several structurally characterized transition metal compounds comprising melamine, the titled complex represents a rare example of μ ₃ -melamine coordination mode realized through the heterocycle nitrogen donors. The fluorescent property of complex 1 was investigated and the mechanism was validated by means of a density functional theory (DFT) calculation.     

Evaluation of Load Distribution Factor by Series Solution for Orthotropic Bridge Decks

In bridge engineering, the three-dimensional behavior of a bridge system is usually reduced to the analysis of a T-beam section, loaded by an equivalent fraction of the applied live load, which is called the live load distribution factor (LDF). The LDF is defined in the both the AASHTO Standard Specifications and the LRFD Specifications primarily for concrete slabs and has inherent applicable limitations. This paper provides explicit formulas using series solutions for LDF of orthotropic bridge decks, applicable to various materials but intended for fiber-reinforced polymer (FRP) decks. The present formulation considers important parameters that represent the response characteristics of the structure that are often omitted or limited in the AASHTO Specifications. A one-term series solution is proposed based on the macroflexibility approach, in which the bridge system is simplified into two major components, deck and stringers. The governing equations for the two components are obtained separately, and the deflections and interaction forces are solved by ensuring displacement compatibility at stringer lines. The LDF is calculated as the ratio of the single stringer interaction force to the summation of total stringer interaction forces. To verify this solution, a finite-element (FE) parametric study is conducted on 66 simply supported concrete slab-on-steel girder bridges. The results from the series solution correlates well with the FE results. It is also illustrated that the series solution can be applied to predict LDF for FRP deck-on-steel girder bridges, by favorable comparisons among the analytical, FE, and testing results for a one-third-scale bridge model. The scale test specimen consists of an FRP sandwich deck attached to steel stringers by a mechanical connector. The series solution is further used to obtain multiple regression functions for the LDF in terms of nondimensional variables, which can be used for simplified design purposes.     

The Effect of Rock-crude Oil-fluid Interactions on Wettability Alteration of Oil-wet Sandstone in the Presence of Surfactants

The aim of the present work was to study the rock-fluid interaction in presence of surfactants and thereby their effects on wettability alteration of oil-wet sandstone for its essentiality in enhanced oil recovery. Characterization of sandstone sample and its interaction with crude oil, brine and surfactants were investigated by Fourier Transform Infrared spectroscopy. Scanning electron microscope and X-ray diffraction studies were performed to characterize the sandstone sample. Critical micelle concentrations of sodium dodecyl sulfate, cetyltrimethylammonium bromide, Tergitol 15-S-7, Tergitol 15-S-9, and Tergitol 15-S-12 were determined by interfacial tension measurement method. Wettability alteration of sandstone was studied by contact angle method.     

Enantioselective Synthesis of α‐Amino‐γ‐sulfonyl Phosphonates with a Tetrasubstituted Chiral α‐Carbon via Quinine‐Squaramide‐Catalyzed Michael Addition of Nitrophosphonates to Vinyl Sulfones

α‐Nitro‐γ‐sulfonyl phosphonates with a key tetrasubstituted chiral α‐carbon center have been synthesized for the first time in high yield and enantioselectivity through a quinine‐squaramide‐catalyzed conjugate addition of α‐nitro phosphonates to aryl vinyl sulfones. Representative examples presented here for the transformation of nitrosulfonyl phosphonates to aminosulfonyl phosphonates, alkylation at the α‐position of the sulfonyl group followed by desulfonation and scale‐up of the conjugate addition highlight the practical applications of the methodology.     

Thermal behaviour of hydroxides, hydroxysalts and hydrotalcites

Mass spectrometric analysis of gases evolved during thermal decomposition of divalent metal hydroxides, hydroxysalts and hydrotalcites show that all these compounds undergo dehydration in the temperature range 30 <T < 220°C followed by decomposition at temperatures above 250°C. The latter step involves simultaneous deanation and dehydroxylation of the layers. Our observations conclusively prove that alternative mechanisms which envisage CO₂ evolution due to deanation at lower temperatures proposed by Kanezaki to be wrong.     

Error Detecting Dual Basis Bit Parallel Systolic Multiplication Architecture over GF（2^m）

An error tolerant hardware efficient verylarge scale integration （VLSI） architecture for bitparallel systolic multiplication over dual base, which canbe pipelined, is presented. Since this architecture has thefeatures of regularity, modularity and unidirectionaldata flow, this structure is well suited to VLSIimplementations. The length of the largest delay pathand area of this architecture are less compared to the bitparallel systolic multiplication architectures reportedearlier. The architecture is implemented using Austria Micro System＇s 0.35 μm CMOS （complementary metaloxide semiconductor） technology. This architecture canalso operate over both the dual-base and polynomialbase.     

High-performance fully depleted silicon nanowire (diameter /spl les/ 5 nm) gate-all-around CMOS devices

This paper demonstrates gate-all-around (GAA) n- and p-FETs on a silicon-on-insulator with /spl les/ 5-nm-diameter laterally formed Si nanowire channel. Alternating phase shift mask lithography and self-limiting oxidation techniques were utilized to form 140- to 1000-nm-long nanowires, followed by FET fabrication. The devices exhibit excellent electrostatic control, e.g., near ideal subthreshold slope (/spl sim/ 63 mV/dec), low drain-induced barrier lowering (/spl sim/ 10 mV/V), and with I/sub ON//I/sub OFF/ ratio of /spl sim/10/sup 6/. High drive currents of /spl sim/ 1.5 and /spl sim/1.0 mA//spl mu/m were achieved for 180-nm-long nand p-FETs, respectively. It is verified that the threshold voltage of GAA FETs is independent of substrate bias due to the complete electrostatic shielding of the channel body.