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排序方式: 共有1641条查询结果,搜索用时 15 毫秒
21.
Jan Haas Karen S. Frese Farbod Sedaghat-Hamedani Elham Kayvanpour Rewati Tappu Rouven Nietsch Oguz Firat Tugrul Michael Wisdom Carsten Dietrich Ali Amr Tanja Weis Torsten Niederdrnk Michael P. Murphy Thomas Krieg Marcus Drr Uwe Vlker Jens Fielitz Norbert Frey Stephan B. Felix Andreas Keller Hugo A. Katus Benjamin Meder 《International journal of molecular sciences》2021,22(4)
With more than 25 million people affected, heart failure (HF) is a global threat. As energy production pathways are known to play a pivotal role in HF, we sought here to identify key metabolic changes in ischemic- and non-ischemic HF by using a multi-OMICS approach. Serum metabolites and mRNAseq and epigenetic DNA methylation profiles were analyzed from blood and left ventricular heart biopsy specimens of the same individuals. In total we collected serum from n = 82 patients with Dilated Cardiomyopathy (DCM) and n = 51 controls in the screening stage. We identified several metabolites involved in glycolysis and citric acid cycle to be elevated up to 5.7-fold in DCM (p = 1.7 × 10−6). Interestingly, cardiac mRNA and epigenetic changes of genes encoding rate-limiting enzymes of these pathways could also be found and validated in our second stage of metabolite assessment in n = 52 DCM, n = 39 ischemic HF and n = 57 controls. In conclusion, we identified a new set of metabolomic biomarkers for HF. We were able to identify underlying biological cascades that potentially represent suitable intervention targets. 相似文献
22.
Brillouin scattering (BS), photon correlation spectroscopy (PCS), and ultrasonic (US) measurements were conducted to study the curing process of diglycidyl ether of bisphenol A with butane-1,4-diol at a curing temperature of 100°C. The experimental techniques probe the primary glass-rubber transition during the curing reaction. The primary relaxation time τ obtained from the BS and US velocity and absorption increases with curing time and hence the BS experiment measures τ at earlier stages of cure than the US experiment. The relaxation times at a different extent of reaction and for different measuring temperatures are consistent with BS, US, PCS, and DSC measurements and conform to a single reduced Vogel–Fulcher–Hesse–Tamann equation. Furthermore, the US experiments show evidence of secondary relaxations in the epoxy system. 相似文献
23.
A novel technique for the preparation of secondary fatty amides 总被引:1,自引:0,他引:1
Alexander Bilyk Raymond G. Bistline Jr. George J. Piazza Stephen H. Feairheller Michael J. Haas 《Journal of the American Oil Chemists' Society》1992,69(5):488-491
A technique for the synthesis of monosubstituted fatty amides at low temperature and ambient pressure was developed. This
method involved the condensation of an amine with a triacylglycerol. The primary amine (ethyl,n-butyl,n-hexyl andn-octyl were tested) acted as reagent and solvent for the fatty substrates. No additional organic solvent or catalyst was added.
Tallow, vegetable oils and fish oil all served well as substrates, as did pure tripalmitin. The rate of amidation was dependent
upon temperature and the ratio of fat to amine. In a series of experiments conducted with tallow andn-butylamine at a fat:amine molar ratio of 1:16, amidation could be carried out at 20°C, producingn-butyltallowamide in 83% yield in 24 hr. When the fat:amine molar ratio was reduced to 1:8, and the temperature raised to
45°C, the amide yield was 87.6% in 24 hr. When the reaction was carried out at the boiling point ofn-butylamine (78°C) and at a fat:amine ratio of 1:8, the amide yield was 93.2% in 4 hr. The reaction progressed more rapidly
with higher molecular weight amines. The identity and purity of the amides was assessed by thin-layer chromatography and confirmed
by elemental analyses and infrared and C13 nuclear magnetic resonance spectroscopy. 相似文献
24.
S. A. G. R. Karunathilaka N. A. Hampson T. P. Haas R. Leek T. J. Sinclair 《Journal of Applied Electrochemistry》1981,11(5):573-582
The impedances of small (2400 mA h) alkaline Zn-HgO cells have been measured in the range 10 kHz-0.001 Hz at various states of charge from fully charged to fully discharged. The behaviour of the cell conforms to that expected for rate control by charge transfer at the zinc electrode and diffusion in solution. At low frequencies there is a relaxation in the diffusive circuit elements which ultimately results in a complete suppression of the capacitative component of the impedance at zero frequency. The low-frequency behaviour is analogous to convective diffusion and is due to the effective distance between the electrodes being small compared with the characteristic length (D/)1/2. The magnitude of the charge transfer resistance is the best measure of the state of charge.Nomenclature
a
effective electrode separation
-
C
DL
double-layer capacitance of cell
-
C
R
capacitative component of cell impedance
- C
concentration difference
-
D
percentage discharge in Equation 12
-
D
i
diffusion coefficient of speciesi
-
R
ohmic resistance of cell
-
R
R
resistive component of cell Faradaic impedance
-
Ui
constant defined by Equation 10
-
Z
total cell impedance
-
Z
F
cell Faradaic impedance
-
Z
F
cell impedance modified for porosity effect
-
Z
x
cell impedance of Faradaic component plus double layer
-
cell Warburg coefficient (slope ofR
R and 1/C
Rversus su}-1/2)
-
C
Warburg coefficient calculated fromC
r values
-
i
cell Warburg coefficient for speciesi
-
Warburg coefficient calculated fromR
R values
-
dihedral angle of tail of Sluyters plot (after coming-off high-frequency semicircle)
-
angular frequency 相似文献
25.
26.
IngoReinkensmeier HenkjanBuursen 《材料热处理学报》2004,25(5):597-600
The continuous constructive challenge to improve the functionality and efficiency of components always results in higher demands on production engineering, against the background of the generally increasing cost pressure. In many cases, you will just succeed in producing competitive and innovative products by combining and coupling of different procedures to an independent (hybrid) technology. The use of hybrid procedures for metal joining and heat treatment of metallic materials finds more and more industrial fields of application. Modern vacuum lines with integrated pressurized gas quenching are considered high-performance and flexible means of production for brazing and heat treatment tasks as well in the turbine industry as in the mould making and tool manufacturing industry. In doing so, the heat treatment is coupled with the brazing cycle in a combined process so that the brazing temperatures and soak times are adapted to the necessary temperatures and times for solution heat treatment and austeniting. This user-oriented article describes on the one hand examples of brazing of turbine components, but above all the practical experience from the plastics processing industry, where the requirement for a high-efficient cooling of injection moulding dies gains more and more importance.The combined procedure “Vacuum Brazing and Hardening” offers plenty of possibilities to produce mould inserts with an efficient tempering system in an economic way. 相似文献
27.
Mohammad Farhan Tanzim Nuno Fortunato Ilias Samathrakis Ruiwen Xie Ingo Opahle Oliver Gutfleisch Hongbin Zhang 《Advanced functional materials》2023,33(28):2214967
All-d Heuslers are a category of novel compounds combining versatile functionalities such as caloric responses and spintronics with enhanced mechanical properties. Despite the promising transport properties (anomalous Hall (AHC) and anomalous Nernst (ANC) conductivities) shown in the conventional Co2XY Heuslers with p-d hybridization, the all-d Heuslers with only d-d hybridization open a new horizon to search for new candidates with outstanding transport properties. In this work, the AHC and ANC are evaluated for thermodynamically stable ferro/ferri-magnetic all-d-metal regular Heusler compounds based on high-throughput first-principles calculations. It is observed that quite a few materials exhibit giant AHCs and ANCs, such as cubic Re2TaMn with an AHC of 2011 S cm-1, and tetragonal Pt2CrRh with an AHC of 1966 S cm-1 and an ANC of 7.50 A m-1K-1. Comprehensive analysis on the electronic structure reveals that the high AHC can be attributed to the occurrence of the Weyl nodes or gapped nodal lines in the neighborhood of the Fermi level. The correlations between such transport properties and the number of valence electrons are also thoroughly investigated, which provides a practical guidance to tailor AHC and ANC via chemical doping for transverse thermoelectric applications. 相似文献
28.
Recent advances in the field of kernel-based machine learning methods allow fast processing of text using string kernels utilizing suffix arrays. kernlab provides both kernel methods’ infrastructure and a large collection of already implemented algorithms and includes an implementation of suffix-array-based string kernels. Along with the use of the text mining infrastructure provided by tm these packages provide R with functionality in processing, visualizing and grouping large collections of text data using kernel methods. The emphasis is on the performance of various types of string kernels at these tasks. 相似文献
29.
Oliver Schreer Ingo Feldmann Isabel Alonso Mediavilla Pedro Concejero Abdul H. Sadka Mohammad Rafiq Swash Sergio Benini Riccardo Leonardi Tijana Janjusevic Ebroul Izquierdo 《Multimedia Tools and Applications》2010,48(1):23-49
Multimedia analysis and reuse of raw un-edited audio visual content known as rushes is gaining acceptance by a large number
of research labs and companies. A set of research projects are considering multimedia indexing, annotation, search and retrieval
in the context of European funded research, but only the FP6 project RUSHES is focusing on automatic semantic annotation,
indexing and retrieval of raw and un-edited audio-visual content. Even professional content creators and providers as well
as home-users are dealing with this type of content and therefore novel technologies for semantic search and retrieval are
required. In this paper, we present a summary of the most relevant achievements of the RUSHES project, focusing on specific
approaches for automatic annotation as well as the main features of the final RUSHES search engine. 相似文献