SIPmsign: a lightweight mobile signature service based on the Session Initiation Protocol

The development of mobile signatures could increase the spread and adoption of mobile services based on electronic signatures, such as mobile payments, mobile business transactions, and mobile government services. A Mobile Signature Service (MSS) means that a user in any of the scenarios mentioned can attach an electronic signature, anywhere, anytime, as with a handwritten signature with a device that is almost always on him or her. Several solutions have appeared, such as using the European Telecommunications Standard Institute MSS, the Mobile Signature Application Unit, and the Mobile Network Operator‐independent MSS. These solutions present two kinds of drawbacks. On the one hand, some of them require the service to be developed by all mobile network operators, whereas others are not based on efficient communications. In this paper, we present a new MSS named SIPmsign that solves these problems. Our proposal is based on the Session Initiation Protocol and defines how to exchange the information in a secure and more efficient way than previously. Thanks to Session Initiation Protocol, we provide the adoption of our proposal as a MSS for the new generation of mobile communications. In this paper, we also present the prototype we have developed as a proof of its feasibility as well as an evaluation of the performance of our solution. Copyright © 2012 John Wiley & Sons, Ltd.     

Response to N-fertilizer of Italian ryegrass grown alone and in mixture with berseem clover under continental irrigated mediterranean conditions

In a field experiment over three growing seasons, the potential benefits of planting berseem clover (Trifolium alexandrinum L) with Westerwold Italian ryegrass (Lolium multiflorum Lam.) were examined under irrigated continental Mediterranean conditions.Similar N rates (0, 30, 60, 90 and 120 kg N ha^–1 cut^–1) were applied to both pure Italian ryegrass stands and mixtures, each given three successive cuts. One previously unfertilized cut was performed in late winter. Species in the mixture were established at 50:50 seed ratio but the mean proportion of berseem clover was 14%. Mean winter survival of berseem was 87% but 88% of the plants had leaves damaged by the frost. Forage production varied with both N rate and cutting sequence in both the pure stand and the mixture but differences between the two types of swards were significant only at low levels of fertilizer N. Total DM production over the four cuts in plots with N applications of 0,90, 180, 270 and 360 kg N ha^–1 a^–1 were 7.14, 9.51, 11.66, 13.91 and 14.36 t DM ha^–1 a^–1 in pure stand, respectively. Corresponding values for the mixture were 8.80, 10.94, 12.90, 14.05 and 13.64 t DM ha^–1 a^–1. The mean response of Italian ryegrass in the range of 0–360 kg N ha^–1 a^–1 was 20 kg DM per kg N applied. The corresponding value for the mixture was 13 kg DM per kg N applied. At the berseem clover proportions reached in this work, N equivalence showed values of about 80 kg N ha^–1 a^–1. As rates of N increased from 0 to 120 kg N ha^–1 cut^–1, nitrogen concentration increased by 78%. In the applied range of N fertilizers, N0₃-N was not affected.

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Résumé Dans un essai réalisé au cours de trois saisons agricoles, on a étudié le potentiel de 1'association du bersim avec le raygrass italien. Les cultures ont été emenées et irrigué dans des conditions continentales méditerranéennes. On a appliqué, aussi bien pour la culture pure du raygrass que pour l'association, une fertilisation azotée avec les doses suivantes (0, 30, 60, 90 et 120 kg N/ha/coupe) après chacune des trois coupes successives. Une autre coupe avant fertilisation a été faite à la fin de 1'hiver. Les proportions du bersim et du raygrass dans le mélange de graines étaient de 50:50. Cependant, dans la culture en association, les plantes du bersim n'étaient préentés qu'avec un 14 pourcent. 87% des plantes du bersim ont pu survivre en hiver, dont 88% avaient des feuilles endommagées par les gelées. La production d'herbe a été proportionnelle aux doses de fertilisation pour la culture pure et l'association. Néanmoins, différence entre les rendements de chacune de ces dernières était d'autant plus nette que les doses d'azote incorporées dans le sol étaient faibles. La production de la MS pour les quatre coupes dans les parcelles avec les applications de 0, 90, 180, 270 et 360 kg N ha^–1 a^–1 étaient de 7.14, 9.51, 11.66, 13.51, 14.36 tMS ha^–1 a^–1. Le rendement moyen du raygrass italien dans un intervalle de 0-360 kg N ha^–1 a^–1 a été de 20 kg MS par kg de N de fertilisation. Concernant le bersim, les valeurs équivalentes de N étaient de 1'ordre de 80 kg N ha^–1 a^–1. Au fur et à mesure que les doses de fertilisation azotée augmente de 0 à 120 kg ha^–1 coupe, la concentration en azote augmente de 78%. Dans l'intervalle de la fertilisation azotée appliqué NO₃ -N n'a pas été affectée.

     

Thiyl radical-catalyzed isomerization of oils: An entry to the trans lipid library

The unsaturated fatty acyl moieties of TAG present in natural oils of borage, olive, and rice were converted to their corresponding geometrical trans isomers by thiyl radical-catalyzed isomerization. Thiyl radicals were generated from 2-mercaptoethanol under photolytic or thermal conditions. A relevant feature of this method is the absence of double-bond shifts, so that no positional trans isomers or conjugated polyenes are formed. Oils obtained after the isomerization were winterized to further increase their trans fatty acid content. Methanolysis and hydrolysis of the trans oil mixtures using an enzymatic method (lipase B from Candida antarctica) gave good conversions to the corresponding trans FAME and fatty acids, respectively. These results are relevant for the studies of lipid isomerism and trans fatty acid recognition, which is a growing concern in biochemistry and nutrition, and open new perspectives for the synthesis of glycerides and studies of their structure-activity relationships.     

Unprecedented J‐Aggregated Dyes in Pure Organic Solvents

The design and synthesis of the first organic dyes enabling spontaneous formation of stable J‐aggregates in common organic solvents without additives is described. The new dyes are O‐BODIPYs with a B‐spiranic 4,4‐diacyloxyl substitution pattern. Key to the effectiveness of the J‐aggregation process is the high conformational rigidity of the B‐spiranic molecular design as well as the orthogonal disposition of the B‐diacyloxyl substituent and the meso‐aryl group with respect to the mean plane of the boradiazaindacene. Atomistic simulations, both in vacuum and in a solvent cage, support the dynamics of the J‐aggregation process as well as its dependence on the alkylation pattern of the BODIPY chromophore. A detailed analysis of the photophysical and laser properties of the new dyes provides convincing evidence for the unambiguous assignment of these J‐aggregates and their dependence on the environmental conditions.     

Floating point arithmetic teaching for computational science

Computational science is based upon numerical computing and, consequently, requires excellent knowledge of floating point computer arithmetic. In general, the average computational science student has a relatively limited understanding of the implications of floating point computation. This paper presents an initiative to teach floating point number representation and arithmetic in undergraduate courses in computational science. The approach is based on carefully designed practical exercises which highlight the main properties and computational issues of finite length number representation and arithmetic. In conjunction to the exercises, an auxiliary educational tool constitutes a valuable support for students to learn and understand the concepts involved. Simpler formats are used as an introduction to the IEEE 754 standard, with the aim of presenting the fundamentals of the floating point computation and emphasizing its limitations. This approach could be included in courses related to computer organization, programming, discrete mathematics, numerical methods or scientific computing in computational science curricula.     

Older drivers, medical condition, medical impairment and crash risk

New evidence has appeared to support the fact that the over-involvement of older drivers in traffic accidents disappears when the low mileage bias is taken into account. As a group, older drivers are as safe as or safer than other age groups, and only low mileage older drivers have a high crash rate. Furthermore, the role of the medical condition of older drivers in traffic accidents, as well as the fitness to drive evaluation, are objects of controversy. We examined all this with a cohort of 4316 drivers attending Medical Driving Test Centres for a mandatory fitness to drive evaluation. Our data shows that older drivers (> or =75) have a lower crash rate. Medical conditions that impair fitness to drive, as a tendency, increased with advanced age and with lower mileage group. The multivariate analysis of variance showed that there is an effect (p<0.0001) of age-range and mileage on the annual crash rate per million kilometres driven, while a medical restriction ("fit to drive with restriction") has no effect (p>0.05). Our data suggests that health status is not associated with increased crash risk for the low mileage group, although further studies are needed.     

Photo-Fenton process as an efficient alternative to the treatment of landfill leachates

Advanced oxidation processes (AOPs), namely photo-Fenton, Fenton-like, Fenton and UV/H(2)O(2), have been investigated in the removal of organic matter and colour from landfill leachates. The leachate was characterised by high COD, low biodegradability and intense dark colour. Evaluation of COD removal as a function of the operation variables (H(2)O(2), Fe(2+), Cu(2+), UV) led to results that ranged between 30% and 77% and it was observed that the removal efficiencies decreased in the order: photo-Fenton>Fenton-like>Fenton>UV/H(2)O(2)>UV. Thus, a detailed experimental analysis was carried out to analyse the effect of the hydrogen peroxide and iron concentrations and the number of reagent additions in the photo-Fenton process, observing that: (i) the COD removal ranged from 49% to 78% depending on the H(2)O(2) dose, (ii) the total amount of organic matter removed was increased by adding the reagent in multiple steps (86%), (iii) iron concentration corresponding to a Fe(2+)/COD mass ratio=0.33 was found to be the most favourable and, (iv) after a neutralization step, the colour and residual concentrations of iron and H(2)O(2) were practically negligible in the final leachate solution.     

Arsenic speciation in river and estuarine waters from southwest Spain

An arsenic speciation survey was carried out in water samples from the Tinto and Odiel Rivers (southwest of Spain), as well as their common estuary. Both rivers are affected by acid mine drainage (AMD) and represent an input of heavy metals into the estuary, which also suffers from industrial water discharges. Samples were taken in December 2000 and July 2001. The arsenic species considered were arsenite (As(III)), arsenate (As(V)), monomethylarsonic (MMA) and dimethylarsinic (DMA) ions using coupled high-performance liquid chromatography-hydride generation-inductively coupled plasma-mass spectrometry (HPLC-HG-ICP-MS) for their determination. Parameters such as pH, salinity, redox potential and dissolved O2 were also measured. The results revealed that the acid mine drainage originating mainly during winter along the upper part of the Tinto River course causes high inorganic concentrations of dissolved arsenic, up to 600 microg l(-1) of As(III) and 200 microg l(-1) of As(V). In summer, As(III) levels decreased due to the diminution of the input from acid mine drainage and also because of oxidation, with a corresponding increase of As(V) level. Furthermore, the extreme acidic conditions of this river (pH 2.3-2-6) do not allow biological activity sufficient to produce significant concentrations of methylated arsenic species. The arsenic concentrations in the nearby Odiel River were always 5-10 times lower than in the Tinto River, with arsenic levels usually below 100 microg l(-1), dominated by As(V), indicating that it is less affected by acid mine drainage. The highest inorganic arsenic species concentrations were found where the river crosses a mining site, which corresponds to the highest As(III) values. Significant biological activity in this river produced methylated species that were detected along the water-course, with the highest concentrations at the lower course of the river, accounting for up to 53-61% of the total dissolved arsenic. At the common estuary formed by both rivers, only arsenate was detected in most samples at lower concentrations than in the riverine water samples. The tidal cycle showed a similar pattern of dilution of the arsenate when seawater comes into the estuary. Methylated species were not found either in summer or winter, at least at the 0.1 microg l(-1) level, possibly because of the high turbidity of the waters, producing an inhibition of the phytoplankton activity. In addition to the riverine inputs into the common estuary, industrial activity also represents an important source of arsenic as the discharge from a Cu smelter produced the highest arsenate level of all samples in estuary and also the only sample with significant arsenite concentration. Furthermore, the underlying iron-oxide-rich sediments represent an importance source of arsenic into the water column. In three nearby estuaries not affected by industrial activity or acid mine drainage, arsenic levels remained below detection limits.     

Effects of product information and consumer attitudes on responses to milk and soybean vanilla beverages

BACKGROUND: A study was made into how the type of information (picture of real package or card with beverage type and nutritional facts) and consumer attitudes (interest in eating healthily and food neophobia) affect hedonic ratings and purchase intention with respect to milk and soybean vanilla beverages and to what extent the expectations created by information influence the hedonic ratings of these products. RESULTS: A significant effect of the interaction between samples and information type was detected for both expected acceptability and purchase intention when only information about the samples was provided. The effect of this interaction was significant for acceptability ratings when the samples were evaluated together with corresponding information. The acceptability and purchase intention for two soymilk samples were significantly higher for consumers interested in eating healthily. Both types of information generated an assimilation effect for four samples; however, only for milk beverages was this effect complete. CONCLUSION: Information affected purchase intention to a greater extent than it did hedonic ratings. Type of information significantly affected hedonic ratings in most samples, although sensory quality seemed more decisive for two of the soymilk samples. The extent to which information influenced consumer behaviour was also dependent on some consumer attitudes, such as interest in eating healthily. Copyright © 2008 Society of Chemical Industry