The Effect of Aniline Hydrochloride Hydrotrope on the Phase Behavior of SDS/Water System

The aim of this work was to determine the detailed phase behavior of the sodium dodecyl sulfate/aniline hydrochloride/water system as a function of concentration of sodium dodecyl sulfate (SDS), aniline hydrochloride (AHC) to sodium dodecyl sulfate molar ratio (R = [AHC]/[SDS]) and temperature. Phase behavior information was obtained via polarizing microscopy, differential scanning calorimetry (DSC), cryo-scanning electron microscopy (Cryo-SEM) and oscillatory linear rheological measurements with good agreement among these techniques. It is well known that SDS in water forms spherical micelles at concentrations lower than 40 wt% and temperatures above its Krafft temperature (T _k = 16–21 °C). In this region, the SDS/water system exhibits Newtonian rheological behavior, which is characteristic of spherical micellar solutions. The addition of the hydrotrope, aniline hydrochloride, to SDS aqueous solutions produces a viscosity increase in this system as R augments, and a maximum of about five orders of magnitude was found at R = 0.47 for 5 wt% SDS at 20 °C. Moreover, the system shows a transition from viscous to strong viscoelastic behavior. These changes in the rheological behavior are produced by the transitions from sphere to rodlike micelles, which are induced by the hydrophobicity of AHC causing it to be absorbed into the core and the hydrophilic interface of the micelles, which screens the repulsions between the charged head groups.     

Effect of dentin pretreatment with potassium oxalate: A 6‐year follow‐up

Oxalate‐based products are effective against dentine sensitivity and have been studied as an option to improve long‐term adhesive bonding strength. Our aim was to evaluate the effect of potassium oxalate on the microtensile bond strength (µTBS) of the dentin/resin interface after 24 h, 1, and 6 years. Dentin on the occlusal surface of 16 human premolars was exposed and etched with 35% phosphoric acid. The teeth were divided into four groups. Two groups received 3% monohydrated potassium oxalate and the following adhesive systems and composites: Adper Scotchbond Multipurpose + FiltekZ350 (3M/ESPE) and Prime & Bond NT + Esthet‐X (Dentsply). Two control groups did not receive potassium oxalate. Teeth were cut into sticks and kept in distilled water at 37°C for 24 h, 1, and 6 years. The sticks underwent µTBS testing after storage. ANOVA, Tukey's post hoc test, and paired t test were used to compare storage times (α = 0.05). The fracture mode of the specimens was classified under a stereomicroscope (40×). Morphology of the hybrid layer and the fracture pattern were observed with scanning electronic microscopy (SEM). Mean µTBS was high at 24 h and decreased after 1 and 6 years. After 6 years, the mean µTBS values were similar with no statistically significant difference between the groups (p = .121). SEM images showed proper dentin hybridization. Dentin pretreatment with potassium oxalate did not affect hybrid layer formation, but bond strength decreased over time after 24 h. Therefore, the clinical use of potassium oxalate to increase dentin bond durability is not indicated.     

Bioactive Steroids and Triterpenes from Melilotus messanensis and Their Allelopathic Potential

The aerial parts of Melilotus messanensis (sweet clover) afforded, from moderately and polar bioactive fractions, 11 triterpenes and five steroids. A series of aqueous solutions at 10^–4–10^–9 M of five steroids and nine triterpenes was monitored to test their effects on germination and growth of the monocots Hordeum vulgare and Allium cepa, and the dicots Lactuca sativa (var. nigra and var. romana) and Lycopersicon esculentum. An important stimulatory effect on H. vulgare germination (between 40% and 80% for almost all tested compounds) was observed. Some considerations about the ecological role of triterpenes on M. messanensis are made. In addition to known lupane triterpenes (platanic acid and 3,28,30-lup-20(29)-enetriol), oleanane triterpenes (soyasapogenol B, soyasapogenol G, and messagenolide), a gammacerane triterpene (gammacer-16-en-3-one), five new lupane triterpenes (messagenic acids A–E: (27-cis-4-hydroxycinnamoyloxy)-betulinic acid; 27-(trans-4-hydroxycinnamoyloxy)betulinic acid; 20(S)-3-hydroxy-29-oxolupan-28-oic acid; 3,30-dihydroxylup-20(29)-en-28-oic acid; and 3,20-dihydroxylup-18(19)-en-28-oic acid, respectively), and sterols (-sitosterol, ergosterol peroxide, 7-hydroxysitosterol, 7-hydroxysitosterol, and 7-oxositosterol) were isolated and chemically characterized. Their structures and stereochemistry were elucidated by spectroscopic methods (one- and two-dimensional ¹H and ¹³C NMR, IR, MS).     

The numerical solution of a generalized Burgers–Huxley equation through a conditionally bounded and symmetry-preserving method

In this article, we propose a non-standard, finite-difference scheme to approximate the solutions of a generalized Burgers–Huxley equation from fluid dynamics. Our numerical method preserves the skew-symmetry of the partial differential equation under study and, under some analytical constraints of the model constants and the computational parameters involved, it is capable of preserving the boundedness and the positivity of the solutions. In the linear regime, the scheme is consistent to first order in time (due partially to the inclusion of a tuning parameter in the approximation of a temporal derivative), and to second order in space. We compare the results of our computational technique against the exact solutions of some particular initial-boundary-value problems. Our simulations indicate that the method presented in this work approximates well the theoretical solutions and, moreover, that the method preserves the boundedness of solutions within the analytical constraints derived here. In the problem of approximating solitary-wave solutions of the model under consideration, we present numerical evidence on the existence of an optimum value of the tuning parameter of our technique, for which a minimum relative error is achieved. Finally, we linearly perturb a steady-state solution of the partial differential equation under investigation, and show that our simulations still converge to the same constant solution, establishing thus robustness of our method in this sense.     

Experimental study and finite element analysis of simple X- and T-branch tube hydroforming processes

The tube hydroforming process is a relatively complex manufacturing process; the performance of this process depends on various factors and requires proper combination of part design, material selection and boundary conditions. Due to the complex nature of the process, the best method to study the behaviour of the process is by using numerical techniques and advanced explicit finite element (FE) codes. In this work, X- and T-branch components were formed using a tube hydroforming machine and experimental load paths (forming pressure and axial feed) were obtained for the processes via a data acquisition system integrated with the machine. Subsequently, the processes were simulated using LS-DYNA3D explicit FE code using the same experimental boundary, loading conditions and the simulation results were compared with the experimental results. It was found that the developed branch height and the wall thickness distribution along different planes were in good agreement with the experimental results.     

Hydrogen adsorption characteristics of magnesium combustion derived graphene at 77 and 293 K

Bulk graphene was prepared by the method of magnesium combustion in a CO₂ atmosphere, producing large quantities of material which had a different morphology and importantly, a more ordered carbon lattice than reduced graphene oxide and other bulk graphene synthetic methodologies. Despite a low surface area of 235.5 m²/g and ca 9 at.% of magnesium and its oxides which do not contribute to hydrogen adsorption, we observe 0.85 wt.% of H₂ at 65 bar and 77 K, and 0.9 wt.% of H₂ at 300 bar and 293 K. As this methodology readily produces many-gram quantities with cheap starting materials, we anticipate that with further enhancements to the synthetic methodology, improving both surface area and reducing reaction by-products, this material will provide a robust platform for further H₂ adsorption investigations.     

Collaboratively envisioning the future of community psychology in Canada: From talk to action.

Community Psychology (CP) is a relatively young and marginalized discipline in Canada, with only four graduate programs, concentrated in two provinces–Ontario and Québec. Recognising the need to develop cohesion and an identity as a field, several senior Canadian community psychologists proposed hosting a biennial conference, which began in 2002 at the University of Ottawa. Starting in 2006, the conference became a forum for CP faculty, students, and community partners to collaboratively develop a vision for the future of CP in Canada. Diverse teams of conference participants were engaged in facilitated discussions, culminating in a plenary session in which delegates shared their perspectives with the larger group. Eight themes emerged from the visioning exercises in 2006, which led to the development of special interest groups in the following areas: developing a sense of identity; clarifying and defining the field of CP; raising the profile of CP in Canada; promoting a CP education across Canada; enhancing recognition, credibility, and accreditation; establishing links within the field of psychology; building interdisciplinary bridges; international and diverse perspectives; and promoting healthy communities through grassroots social action. (PsycINFO Database Record (c) 2010 APA, all rights reserved)