Structural,mechanical, and antibacterial features of curcumin/polyurethane nanocomposites

Various types of bacteria inhabit many surfaces thus causing problems which can have very strong impact on human health. Here we present a study of photophysical, mechanical, and antibacterial properties of curcumin/polyurethane nanocomposites prepared by swell-encapsulation-shrink method. The prepared nanocomposites have been characterized for degree of swelling, surface morphology, mechanical properties, chemical contents, photoluminescence, hydrophobicity, potentials for singlet oxygen generation, and antibacterial activity. Dynamic mechanical analysis has shown slight changes of glass temperature of curcumin/polyurethane nanocomposites due to blue light irradiation. It was found that nanocomposites have very strong photoluminescence, become photoactive upon blue light irradiation at 470 nm and generate singlet oxygen. Conducted antibacterial tests have shown very strong activity of these nanocomposites especially toward Escherichia coli. These bacteria strains have been eliminated completely only after 1 h irradiation by blue light. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47283.     

A Comparative Study of the Two Isomers of Bicalicene

Two isomers of bicalicene are possible. The trans-isomer is a stable aromatic compound, known since the 1980s. The cis-isomer has never been experimentally prepared and has so far attracted little attention of theoretical chemists. The properties of cis-bicalicene are now studied theoretically, using the B3LYP/6-311G(d,p) quantum-chemical method. All data obtained (geometric, energetic, as well as those based on harmonic oscillator model of aromaticity and nucleus-independent chemical shift indices of local aromaticity) unequivocally indicate that the “missing” isomer of bicalicene is an unstable antiaromatic species, and that the lack of its existence is no surprise whatsoever.     

High‐pressure recovery of anthocyanins from grape skin pomace (Vitis vinifera cv. Teran) at moderate temperature

The objective was to evaluate the influences of the high hydrostatic pressure extraction parameters on the recovery of anthocyanins from the grape skin pomace extracts (Vitis vinifera cv. Teran) under moderate temperatures. Studied parameters were: solvents (methanol and ethanol); solvent concentrations (30, 50, and 70%); pressures (300, 400, and 500 MPa); times (3, 6.5, 10 min); and temperatures (22, 26, 30 °C). Predominant anthocyanins in all extracts were malvidins (malvidin‐3‐glucoside as the main compound) representing 55.77% of overall anthocyanin content. The type of solvent did not significantly influence anthocyanin extraction yield, while decreased solvent concentration (increased solvent‐to‐water ratio) significantly improved extraction of anthocyanins. Increase of pressure enhanced extraction yield of the anthocyanins but temperature showed stronger impact on the anthocyanins recovery. This investigation evidenced that the best conditions for HHPE of anthocyanins from grape pomace were extraction time 3.39 min, extraction temperature 29.48 °C, pressure 268.44 MPa and solvent concentration 70%.

Practical applications

Due to increased interest for the use of cheap winery byproducts as a source of expensive polyphenols for functional food production, skins from grape pomace became valuable raw material. Therefore, there is a need to evaluate the influence of HHPE innovative extraction technology on its nutritive value during processing. Optimizing parameters for polyphenolic recovery from grape pomace is directly related with nutritional value and economics of food engineering during industrial processing. Obtained results showed that the HHPE under lower temperatures is suitable for the extraction process of anthocyanins from grape skin pomace, but more research is needed to identify other food‐grade solvents with their corresponding concentrations that are useful for the extraction assisted with high hydrostatic pressure.     

Numerical Method for Calculation of Complete Casting Processes—Part I: Theory

This article presents a method for calculation of the complete casting process, including the pouring of the liquid metal into the mold, its solidification, the deformation of the solidified cast, the formation of airgaps between the cast and the mold and their influence on the heat transfer, and the residual stresses. An original phase-change procedure is developed, valid for an arbitrary number of pure metals and/or alloys. A collocated version of a segregated finite-volume method is used to calculate both the liquid metal flow and the deformations and stresses in solids.     

Experience with an On‐board Weighing System Solution for Heavy Vehicles

Mining, construction, and other special vehicles for heavy use are designed to work under high‐performance and off‐road working conditions. The driving and executive mechanisms of the support structures and superstructures of these vehicles frequently operate under high loads. Such high loads place the equipment under constant risk of an accident and can jeopardize the dynamic stability of the machinery. An experimental investigation was conducted on a refuse collection vehicle. The aim of this research was to determine the working conditions of a real vehicle: the kinematics of the waste container, that is, a hydraulic rotate drum for waste collection; the dynamics of the load manipulator (superstructure); the vibrations of the vehicle mass; and the strain (stress) of the elements responsible for the supporting structure. For an examination of the force (weight) on the rear axle of a heavy vehicle, caused by its own weight and additional load, a universal measurement system is proposed. As a result of this investigation, we propose an alternative system for continuous vehicle weighing during waste collection while in motion, that is, an on‐board weighing system, and provide suggestions for measuring equipment designs.     

1D linear-phase band-pass multiplierless FIR Hilbert transformers and filters

An original analytical method, based on modified Christoffel–Darboux formula, is used in the paper in order to synthesise a linear-phase band-pass finite impulse response (FIR) filter function that can have an effect of Hilbert transformer. New structure of the band-pass FIR filter in recursive realisation, together with the corresponding difference equation, is presented providing the efficient filter solution without multipliers. Several examples of filter types for different parity of two real free integer parameters, including a particular solution of Hilbert transformer, are considered in terms of required number of adders and values of cut-off frequencies of the pass and stop bands. A comparison of the proposed band-pass filter characteristics with those of a classical filter solution is provided in the paper.     

Second‐order statistics of system with N‐branch microdiversity and L‐branch macrodiversity operating over gamma shadowed Nakagami‐m fading channels

The problem concerning short‐term fading and long‐term fading (shadowing) and their deleterious effects on wireless systems performance has been in focus for a long time. In this paper, motivated by the results of propagation measurements in land‐mobile and indoor‐mobile systems, and by the fact that gamma distribution can describe shadowing reliably, Nakagami‐m distribution is used to model the signal envelope and gamma distribution is used to model the average signal power. Receive diversity with maximal‐ratio combining and selection combining is implemented at the microlevel and macrolevel, respectively. The general case is explored, which assumes that microdiversity and macrodiversity are provided through arbitrary number of channels. Because shadowing has larger correlation distance than short‐term fading, correlated macrodiversity channels are studied. This paper investigates the dynamics of the received signal. A novel rapidly converging infinite‐series expression for average level crossing rate and average fade duration are obtained. Numerical results are graphically presented to examine the impact of fading severity, shadowing severity, number of diversity branches at the microlevel, number of base stations and correlation between base stations to the system's performance. Computer simulations are also performed to verify the validity and the accuracy of proposed theoretical analysis. Copyright © 2012 John Wiley & Sons, Ltd.