首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   515篇
  免费   4篇
  国内免费   9篇
电工技术   7篇
综合类   1篇
化学工业   96篇
金属工艺   10篇
机械仪表   26篇
建筑科学   19篇
矿业工程   1篇
能源动力   27篇
轻工业   16篇
水利工程   1篇
石油天然气   1篇
无线电   70篇
一般工业技术   140篇
冶金工业   23篇
自动化技术   90篇
  2024年   16篇
  2023年   14篇
  2022年   24篇
  2021年   33篇
  2020年   21篇
  2019年   18篇
  2018年   25篇
  2017年   23篇
  2016年   20篇
  2015年   8篇
  2014年   23篇
  2013年   52篇
  2012年   27篇
  2011年   42篇
  2010年   23篇
  2009年   26篇
  2008年   8篇
  2007年   17篇
  2006年   10篇
  2005年   17篇
  2004年   7篇
  2003年   6篇
  2002年   2篇
  2001年   4篇
  2000年   7篇
  1999年   3篇
  1998年   8篇
  1997年   7篇
  1996年   5篇
  1995年   2篇
  1994年   5篇
  1993年   3篇
  1991年   2篇
  1990年   3篇
  1989年   2篇
  1988年   2篇
  1987年   3篇
  1986年   1篇
  1985年   3篇
  1983年   2篇
  1979年   1篇
  1966年   2篇
  1965年   1篇
排序方式: 共有528条查询结果,搜索用时 15 毫秒
501.
    
A nickel‐ or palladium‐catalyzed cascade approach to afford indolines‐fused triazoles with tetrasubstituted olefins in good yields with excellent control of regio‐ and stereoselectivity is described. We have also discussed the synthesis of unsaturated carbonyl species when the alkyne was appended to an alkyl chain. The synthetic methodology has been extended to construct the biologically active spiroindoline core via a vinylcylopropane (VCP) intermediate. The synthesized tetrasubstituted scaffolds were investigated for their photophysical properties and all of the them exhibited good absorption and fluorescence emission in the UV‐visible region.

  相似文献   

502.
    
A novel method has been developed for the synthesis of 3‐pyrrolines from β‐ketopropargylamines via a 5‐endodig carbocyclization. This transformation involves a silver‐catalyzed Conia‐ene type reaction tolerating broad substrate scope with good to excellent yields. Furthermore, this methodology has been extended for the construction of 2‐substituted pyrroles under base‐mediated conditions.

  相似文献   

503.
Wavelength division multiplexed (WDM) networks are matured to provide, scalable data centric infrastructure, capable of delivering flexible, value added, high speed and high bandwidth services directly from the optical (WDM) layer. But, providing fault-tolerance at an acceptable level of overhead in these networks has become a critical problem. This is due to the size of the current and future networks and diverse quality of service (QoS) requirements for multimedia and mission critical applications. Several distributed real-time applications require communication services with fault-tolerance apart from guaranteed timeliness at acceptable levels of overhead. Several methods exist in the literature which attempt to guarantee recovery in a timely and resource efficient manner. These methods are centered around a priori reservation of network resources called spare resources along a protection path. This protection path is usually routed from source to destination along a totally link disjoint path from primary path. This paper considers the problem of routing and wavelength assignment (RWA) in wavelength routed WDM optical networks. In particular, we propose an efficient algorithm to select routes and wavelengths to establish dependable connections (D-connections), called segmented protection paths. Our algorithm does not insist on the existence of totally disjoint paths to provide full protection. We present experimental results which suggest that our scheme is attractive enough in terms of average call acceptance ratio, spare wavelength utilization, and number of requests that can be satisfied for a given number of wavelengths assuming that the requests come one at time, and wavelengths are assigned according to fixed ordering. Furthermore, the results suggest that our scheme is practically applicable for medium and large sized networks, which improves number of requests that can be satisfied and helps in providing better QoS guarantees such as bounded failure recovery time and propagation delays without any compromise on the level of fault-tolerance for a given number of wavelengths and fibers. We conduct extensive simulation experiments to evaluate the effectiveness of the proposed scheme on different networks and compare with existing methods.This work was supported by the Department of Science and Technology, New Delhi, India. An earlier version of this paper was presented at Opticomm 2002 conference, July 29-August 2, Boston, USA.  相似文献   
504.
Surya  Mulugundam Siva  Prasanthi  G. 《SILICON》2022,14(3):1083-1092
Silicon - In aerospace and automobile industries, because of high strength and excellent anti-wear properties, aluminium silicon carbide composites are widely used. Hence, the current work...  相似文献   
505.
Trans-nail permeability is limited due to the innate nature of the nail plate and the recent investigations indicated the potential of iontophoresis in enhancing the transungual drug delivery in normal nails. However, the onychomycotic nails differ from the normal nails with respect to the anatomical and biological features. The current study investigated the effect of iontophoresis (0.5 mA/cm(2) for 1 h) on the transungual delivery of terbinafine in onychomycotic finger and toe nails. The presence of fungi in the onychomycotic nails was diagnosed by potassium hydroxide (KOH) microscopy. Passive and iontophoretic delivery of terbinafine across the infected nail was studied in Franz diffusion cell. Further, the release profile of terbinafine from the drug-loaded nails was investigated by agar diffusion method. KOH microscopy confirmed the presence of fungi in all the nails used. The amount of drug permeated across the nail plate was enhanced significantly during iontophoresis over passive delivery, that is, by 21-fold in case of finger and 37-fold in case of toe nails. Further, the total drug load in the onychomycotic nail was enhanced by ~12-fold (in both finger and toe nails) due to iontophoresis. Release of terbinafine from the iontophoresis-loaded nails into agar plates exhibited two phases, a rapid phase followed by a steady release, which extended >2 months. This study concluded that the drug delivery in onychomycotic nails did not differ significantly when compared with normal nails, although the extent of drug permeation and drug load differs between finger and toe nails.  相似文献   
506.
Liu M  Li X  Karuturi SK  Tok AI  Fan HJ 《Nanoscale》2012,4(5):1522-1528
Atomic layer deposition (ALD) provides a tool for conformal coating on high aspect-ratio nanostructures with excellent uniformity. It has become a technique for both template-directed nanofabrications and engineering of surface properties. This Feature Article highlights the application of ALD in selected fields including photonics, SERS and energy materials. Specifically, the topics include fabrication of plasmonic nanostructures for the SERS applications, fabrication of 3-D nanoarchitectured photoanodes for solar energy conversions (dye-sensitized solar cells and photoelectrochemical cells), and coating of electrodes to enhance the cyclic stability and thus device life span of batteries. Dielectric coating for tailoring optical properties of semiconductor nanostructures is also discussed as exemplified by ZnO nanowires. Future direction of ALD in these applications is discussed at the end.  相似文献   
507.
Azzam RM  Perla SR 《Applied optics》2006,45(7):1650-1656
An all-transparent symmetric trilayer structure, which consists of a high-index center layer coated on both sides by a low-index film and embedded in a high-index prism, can function as an efficient polarizer or polarizing beam splitter under conditions of frustrated total internal reflection over a wide range of incidence angles. For a given set of refractive indices, all possible solutions for the thicknesses of the layers that suppress the reflection of either the p or s polarization at a specified angle, as well as the reflectance of the system for the orthogonal polarization, are determined. A 633 nm design that uses a MgF2-ZnS-MgF2 trilayer embedded in a ZnS prism achieves an extinction ratio (ER) > 40 dB from 50 degrees to 80 degrees in reflection and an ER > 20 dB from 58 degrees to 80 degrees in transmission. IR polarizers that use CaF2-Ge-CaF2 trilayers embedded in a ZnS prism are also considered.  相似文献   
508.
This paper presents the analysis of automatic generation control of a two-area interconnected thyristor controlled phase shifter based hydrothermal system in the continuous mode using fuzzy logic controller under open market scenario. Open transmission access and the evolving of more socialized companies for generation, transmission and distribution affects the formulation of AGC problem. So the traditional AGC two-area system is modified to take into account the effect of bilateral contracts on the dynamics. It is possible to stabilize the system frequency and tie-power oscillations by controlling the phase angle of TCPS which is expected to provide a new ancillary service for the future power systems. A control strategy using TCPS is proposed to provide active control of system frequency. Further dynamic responses for small perturbation considering fuzzy logic controller and PI controller (dual mode controller) have been observed and the superior performance of fuzzy logic controller has been reported analytically and also through simulation.  相似文献   
509.
Camptothecin (CPT), a monoterpene indole alkaloid, is a potent inhibitor of eukaryotic topoisomerase I (Top 1). Because of this property, several derivatives of CPT are widely used as chemotherapeutic agents. The compound is produced by several plant species, including Nothapodytes nimmoniana (Family: Icacinaceae) presumably as a deterrent to insect pests. Here, we report, a lepidopteran larva, Lymantria sp. of Lymantriidae family which feeds voraciously on the leaves of N. nimmoniana, without any adverse consequences. Larval body weight and molting period were unaffected despite captive feeding of the larva with CPT enriched leaves. Mass spectrometric analysis indicated that nearly 46% of the ingested CPT was excreted while the rest was sequestered predominantly in the exuviae and setae (~35%). Although most of the CPT was in the parental form as found in the plant, traces of inactive, sulfated forms of CPT were recovered from the larva. Compared to that in plant, there were no critical mutations at the CPT binding domain of the insect’s Top 1. The gut pH of the larva was alkaline (pH 10.0). The alkaline gut environment converts CPT from its active, lactone form to inactive, carboxylate form. It is likely that such conversion might help the larva to reduce the overall burden of CPT in its gut. We discuss the results in the context of the mechanisms of resistance adapted by insects to plant toxins.  相似文献   
510.
    
Carbon-based materials, such as graphene oxide and reduced graphene oxide membranes have been recently used to fabricate ultrathin, high-flux, and energy-efficient membranes for ionic and molecular sieving in aqueous solution. However, these membranes appeared rather unstable during long-term operation in water with a tendency to swell over time. Membranes produced from pristine, stable, layered graphene materials may overcome these limitations while providing high-level performance. In this paper, an efficient and “green” strategy is proposed to fabricate µm-thick, graphene-based laminates by liquid phase exfoliation in Cyrene and vacuum filtration on a PVDF support. The membranes appear structurally robust and mechanically stable, even after 90 days of operation in water. In ion transport studies, the membranes show size selection (>3.3 Å) and anion-selectivity via the positively charged nanochannels forming the graphene laminate. In antibiotic (tetracycline) diffusion studies under dynamic conditions, the membrane achieve rejection rates higher than 95%. Sizable antibacterial properties are demonstrated in contact method tests with Staphylococcus aureus and Escherichia coli bacteria. Overall, these “green” graphene-based membranes represent a viable option for future water management applications.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号