Flavour development in pork. Influence of flavour precursor concentrations in longissimus dorsi from pigs with different raw meat qualities

Flavour development and overall eating quality of pan-fried pork chops of longissimus dorsi from eight different raw meat qualities aged for 4 and 15 days were assessed by a trained sensory panel. The raw meat qualities were obtained through combinations of strategic feeding/fasting (control vs. low glycogen concentration), slaughter live-weight (84kg vs. 110kg), and gender (female vs. castrate). The flavour development was investigated for possible correlation with the concentrations of selected individual flavour precursors present in the raw meat: monosaccharides, IMP and degradation products, fatty acids, lactate and thiamine. Differences in precursor concentrations between the raw meat qualities were observed with feeding/fasting and ageing as the main factors with the largest influence of all experimental factors. However, the concentrations of the precursors could not explain the differences in sensory perception of the pan-fried pork chops. Overall, the differences were small.     

On-line drug metabolism in capillary electrophoresis. 1. Glucuronidation using rat liver microsomes

A rat liver microsome pseudostationary phase has been used for the on-line capillary electrophoresis monitoring of glucuronidation. Uridine diphosphate glucuronosyltransferase (EC 2.4.1.17) containing microsomes was isolated from rat liver and directly injected onto neutrally coated capillary containing polymeric replaceable gels followed by injection of the substrate mixture. On-line glucuronidation was observed within 15 min without any sample preparation. The factors affecting the separation of glucuronides and parent compounds were investigated by varying the applied electric fields and the size (length and internal diameter) of capillary. The Michaelis-Menten parameters (Km and Vmax) for the glucuronidation of 4-methyl-7-hydroxy coumarin and 4-nitrophenol were determined using the CE method and by off-line microsomal incubation. No significant differences were observed for Km and Vmax values for 4-methyl-7-hydroxycoumarin and 4-nitrophenol between on-line and off-line glucuronidation of these two compounds. This method was also used to determine the inhibition constant (IC50 value) for the competitive inhibition of morphine glucuronidation by codeine, IC50 (on-line) = 170 vs 580 microM (off-line). The results demonstrate that this method can be used to screen for the glucuronidation of test compounds and should reduce the time required for this screening process.     

Meeting modern grid codes with large direct‐drive permanent magnet generator‐based wind turbines—low‐voltage ride‐through

Ambitious offshore wind energy targets continue to drive technological innovation, with the latest direct‐drive permanent magnet generator‐based wind turbines promising higher efficiency and availability. However, these machines have fixed rotor flux, provided by the magnets, which means that their voltage rises with speed. Further, high machine stator reactance leads to significant magnetic energy storage in the stator windings. Both these aspects provide new challenges for the power converter when designing to meet modern low‐voltage ride‐through requirements. This paper therefore proposes a novel control strategy, using a minimally rated chopper and dynamic brake resistor (DBR) integrated with the wind turbine's power converter, to help these systems to meet the demands of modern grid codes. This control method may allow the chopper and DBR to be rated at only 40% of a fully rated version. Despite only partially rating the DBR system, the control method minimizes the torsional oscillations in the drive train, thereby protecting the mechanical system. Copyright © 2011 John Wiley & Sons, Ltd.     

Hydraulic and Sedimentological Characterizations of a Reach on the Anaktuvuk River, Alaska

Rivers located on the North Slope of Alaska’s Brooks Range are typically not well characterized with respect to basic hydraulic and sedimentological data. In order to obtain basic hydrosedimentological information on the Anaktuvuk River, a pristine stream located in the Colville River basin, we conducted an extensive field campaign from late May to early June 2009. The study reach was located at N69°27.785′, W151°09.858′, latitude and longitude, respectively. The Anaktuvuk River flows north from the Brooks Range to the Colville River, drains an area of 7,058?km2, and encompasses 2,063 m of vertical relief. During the field campaign, the field crew measured discharge and water-surface slope, collected water samples, and characterized bed sediment. As a result of fieldwork and laboratory work, we present an initial rating curve for the Anaktuvuk River, as well as the calculated roughness coefficient and suspended sediment concentrations. In addition, we compare the observed bankfull discharges with the bankfull discharge predicted by a recently published model.     

The effects of observation and gender on psychogenic symptoms.

Objective: To assess the effects of modeling and its interaction with gender in the production of psychogenic symptoms. Design: Healthy volunteers were asked to inhale an inert substance described as a suspected environmental toxin that had been reported to provoke 4 physical symptoms. Subsequently, half of the participants observed a confederate inhale and display the 4 expected symptoms. To control for the general tendency of women to report more physical symptoms than men, participants were also asked to rate the presence of 4 unexpected symptoms. Main Outcome Measures: Symptom ratings at 10-min intervals over a 1-hr period. Results: With unexpected symptoms controlled, observation of symptom displays increased reports of expected symptoms significantly. In addition, the presence of another person of the same gender as the participant increased the production of expected symptoms, even when symptoms were not modeled by the confederate. There was also a trend for women to show more expected symptoms than men. Conclusion: Although the effect of modeling was independent of gender, the mere presence of a same-gender individual, as opposed to a person of the opposite gender, increased reports of expected symptoms, regardless of whether the second person (i.e., the confederate) displayed symptoms. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Self-organized TiO2 nanotube arrays: synthesis by anodization in an ionic liquid and assessment of photocatalytic properties

Self-organized TiO(2) nanotube (NT) arrays were produced by anodization in ethylene glycol (EG) electrolytes containing 1-n-butyl-3-methyl-imidazolium tetrafluoroborate (BMI.BF(4)) ionic liquid and water. The morphology of the as-formed NTs was considerably affected by changing the anodization time, voltage, and water and ionic liquid electrolyte concentrations. In general, a nanoporous layer was formed on the top surface of the TiO(2) NTs, except for anodization at 100 V with 1 vol % of BMI.BF(4), where the NT's mouth was revealed. The length and bottom diameter of the NTs as well as the pore diameter of the top layer showed a linear relationship with increased anodization voltage. These TiO(2) NTs were tested as photocatalysts for methyl orange photodegradation and hydrogen evolution from water/methanol solutions by UV light irradiation. The results show that the TiO(2) NTs obtained by anodization in EG/H(2)O/BMI.BF(4) electrolytes are active and efficient for both applications.     

THE ROLE OF WATER IN METHANOL SYNTHESIS

Abstract

This work focuses on the influence of water in determining the rate of methanol synthesis over CuO/ZnO/Al₂O₃ catalysts. The experimental investigations were conducted in a 1-L slurry reactor based on the novel liquid phase methanol synthesis process. The liquid medium used was a blend of paraffinic and naphthenic mineral oils with a mean molecular mass of 250. It was found that the methanol rates attained a maximum at an optimal water content which was dependent on the reaction temperature. The catalytic activity was found to decline with time at lower temperatures in the presence of a relatively large excess of water. The influence of water was also found to be firmly linked to the corresponding carbon dioxide content in the reactor feed. The experimental data bear additional significance because this was the first such study to be performed on the liquid phase process. Emphasis was therefore placed on the use of a CO-rich syngas in order to simulate anticipated process conditions.     

Differential evolution algorithm for static and multistage transmission expansion planning

A novel differential evolution algorithm (DEA) is applied directly to the DC power flow-based model in order to efficiently solve the problems of static and multistage transmission expansion planning (TEP). The purpose of TEP is to minimise the transmission investment cost associated with the technical operation and economical constraints. Mathematically, long-term TEP using the DC model is a mixed integer nonlinear programming problem that is difficult to solve for large-scale real-world transmission networks. In addition, the static TEP problem is considered both with and without the resizing of power generation in this research. The efficiency of the proposed method is initially demonstrated via the analysis of low, medium and high complexity transmission network test cases. The analysis is performed within the mathematical programming environment of MATLAB using both DEA and conventional genetic algorithm and a detailed comparative study is presented.