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61.
Hirosuke Oku Jyutaro Shudo Kunio Mimura Akinori Haratake Junichi Nagata Isao Chinen 《Lipids》1995,30(2):169-172
A neutral lipid class was isolated by thin-layer chromatography from the skin surface lipids of the hairless mouse. The fraction
migrated faster than triglycerides and had a migration rate similar to that of diacyl alkanediols (diester wax). Upon deacylation,
however, the long-chain diols were identified as 1-alkylglycerol ethers based on their chromatographic properties and on the
mass spectra of their nicotinylidene derivatives. Thus, the skin lipid fraction was identified as 1-O-alkyl-diacylglycerol. The alkyl moieties were all saturated and even-numbered and ranged in chainlength from C16 to C22 with 1-O-hexadecylglycerol amounting to 34% of the total glycerol ether moieties. The fatty acids derived from this lipid fraction
were mostly monoenoic with chainlengths ranging from C16 to C24. The major acyl component was eicosenoic acid (20∶1) representing 61% of the total fatty acids. 相似文献
62.
Individual action and synergistic effect in the combination of 6-anilino-1,3,5-triazine-2,4-dithiol (AF), zinc stearate, and barium stearate on the color stabilization of PVC were investigated. In this system, AF selectively reacts with allylic chlorine atoms in PVC. Consequently, unstable allylic chlorine units were converted to thermally stable allylic structures, thus retarding the development of polyene sequences. Zinc stearate accelerated the reaction of AF with allylic chlorine atoms in PVC, forming the zinc salts of AF (AFZnSt, St?C1–H35COO? ) by reacting with AF. Barium stearate reacted with ZnCl2 which is formed in the above reaction to give St2Zn and BaCl2. Consequently, barium stearate led to the selective reaction of AF with allylic chlorine atoms in PVC and the remarkable retarding effect of discoloration of PVC. 相似文献
63.
Selective modification by ozonation for the surface of polyvinyl chloride (PVC) was evaluated to separate PVC from the other plastics, polyethylene terephthalate (PET), polycarbonate (PC) and polymethyl methacrylate (PMMA), with almost the same density as PVC by the froth flotation process. Ozonation could selectively decrease the contact angles of flexible PVC from 87.5 degrees to 68.4 degrees and rigid PVC from 90.3 degrees to 66.9 degrees, whereas little decreases in the contact angle were observed for other plastics. This would be due to the replacement of the chloride group on the surface of PVC, into hydrophilic functional groups; carbonyl, carboxyl and ester group. The PVC was successfully separated from the other plastics by the froth flotation process after the selective surface modification by ozonation. 相似文献
64.
A new non-heating technique was developed for the sterilization of food stuff. Applying a roller compactor, ultra-high pressure sterilization has experimentally demonstrated its ability to sterilize dry powders, such as corn flour and Chinese herbs, with little quality deterioration. Also, the degree of food sterilization was found correlated well with the linear press forces between the rollers, roller gaps, and number of compaction passes. In comparison to the conventional high pressure sterilization technique, the new dry continuous processing method has the advantage of lower investment cost and is more versatile for sterilizing various food powders. 相似文献
65.
Yan Song Wenming Qiao Seong‐Ho Yoon Isao Mochida Quangui Guo Lang Liu 《应用聚合物科学杂志》2007,106(4):2151-2157
Adsorption of low concentration formaldehyde on pitch‐based, rayon‐based, and PAN‐based activated carbon fibers (ACFs) and an unactivated PAN‐based carbon fiber (PAN‐CF) was investigated by a dynamic method. The pore structure and surface chemistry of these samples were characterized by liquid nitrogen adsorption, elemental analysis, and X‐ray photoelectron spectroscopy. Results revealed that the pore structure, especially surface chemical composition, greatly influence the formaldehyde adsorption. PAN‐based ACFs showed the highest formaldehyde adsorption capacity because there are more abundant nitrogen‐containing groups, especially pyrrolic, pyridonic, pyridinic, and quaternary on the surface. The breakthrough time and formaldehyde adsorption capacity of one kind of PAN‐ACF were 361 min and 0.478 mmol/g, respectively. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 相似文献
66.
Toshio Kimura Yoshikatu Okada Takashi Yamaguchi Yuzo Shimada Kazuaki Utsumi 《The Journal of Adhesion》1994,47(1):179-190
Bondability and interfacial reaction between dielectric and insulator layers have been examined to obtain a basic understanding of bonding mechanisms. Lead-containing complex perovskite was used as a dielectric material. Two kinds of glass-ceramics were used as insulator material; lead borosilicate glass containing Al2O3 (insulator A) and the same containing Al2O3 and MgO (insulator B). Dielectric and insulator layers did not bond when insulator A was used. When insulator B was used, however, strong bonding was achieved between the two layers by firing the powder compacts at temperatures between 800° and 1000°C. Addition of MgO to lead borosilicate glass increased the thermal expansion coefficient to that of the dielectric and enhanced the formation of reaction layers, resulting in good bonding. Two reaction layers were identified. The main reaction products were enstatite and bredigite for one layer contacting the dielectric, and enstatite and a compound with the same diffraction pattern as that of faujasite for the other layers contacting insulator B. 相似文献
67.
The pre-treatment of a silica-supported gallium oxide catalyst with H2 at 823 K increased the yield of aromatics and the selectivity to aromatics in the dehydrogenation of propane over the catalyst at 823 K. Gallium oxide in the catalyst was partially reduced with H2 at 823 K. NH3 desorption and DRIFTS studies on the gallium oxide catalyst suggest that the dehydrogenation of propane over a silica-supported gallium oxide catalyst would proceed in the following way: (1) the dehydrogenation of propane to produce propene would occur on Ga sites including Gaδ+–H sites and (2) the aromatization of propene to aromatics on Ga–O–H acid sites. 相似文献
68.
The compositions of ester- and amide-linked fatty acids from ceramides of human vernix caseosa were described with emphasis
on the distribution of the branched-chain fatty acid (BCFA). Two novel ceramides were isolated from vernix caseosa in the
course of this study: the acylated type of esterified α-OH-hydroxyacid/sphingosine ceramide (Cer[EAS]) and nonacylated type
of non-OH fatty acid/hydroxysphingosine ceramide (Cer[NH]). Their chemical structures were identified by nuclear magnetic
resonance and chemical procedure. The Cer[EAS] was an acylceramide and consisted of the highest concentrations of ester- and
amide-linked BCFA (62 and 67%, respectively). The iso- or anteiso-branching structures of the aliphatic chains were confirmed
by the mass spectra of their picolinyl or pyrrolidide derivatives. As a whole, amide-linked fatty acids of ceramides 1–7 and
Cer[NH] were normal types of straight-chain fatty acids with or without α- or ω-hydroxylation. The BCFA concentrations of
amide-linked fatty acids in these ceramides (ceramides 1–7 and Cer[NH]) were low and less than 10%. The BCFA thus occurred
exclusively in a novel acylceramide of Cer[EAS] in the vernix caseosa. 相似文献
69.
Time‐resolved fluorescence properties of 9‐methylanthracene (9MAn) dispersed in film of polyvinylchloride (PVC) containing carbon black were studied under tensile loadings. The fluorescence lifetime of 9MAn decreased from 5.70 to 5.55 ns, whereas the stresses acting on the films increased from 0 to 3 MPa. The change in fluorescence lifetimes of 9MAn during the stress relaxation process showed that the fluorescence lifetimes were correlated with the stresses, not with the strains. The results suggest that 9MAn is a useful probe for monitoring stresses acting on the matrix. With the use of the fluorescence properties of 9MAn, the residual tensile stresses on the skin‐layer of PVC injection‐molded test pieces were estimated. The estimated residual stresses were about ~ 1 MPa. The residual stresses were relaxed to 0 MPa with annealing at 100°C. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 2600–2603, 2002 相似文献
70.
The wettability of cement particles is related to the fluidity of cement paste. This paper describes the mechanism of the higher fluidity imparted by the spherical cement particles in light of their wettability. In addition, the effects of gypsum on the wettability were also studied. This study has shown the following: (1) The weight of water and water-reducing agent solution penetrating the spherical cement powder bed is 24-150% higher than that for the ordinary Portland cement powder bed. This results in the improvement of the wettability of the particle surfaces of spherical cement. The high wettability of spherical cement contributes to its high fluidity. (2) The presence of many fine gypsum particles on the spherical cement particle surface reduces the wettability. (3) To prepare spherical cement, the optimum amount of gypsum added is determined by the acceleration of the formation of spherical particles and the wettability of particle surfaces. 相似文献