Modification of glass ionomer cement by incorporating hydroxyapatite-silica nano-powder composite: Sol–gel synthesis and characterization

A nanohydroxyapatite–silica powder was synthesized using an ethanol based sol–gel technique. The synthesized powder was incorporated into commercial glass ionomer powder (Fuji II GC) and characterized using FTIR, ²⁹Si CP/MAS NMR, EDX and XRD spectroscopy. ²⁹Si CP/MAS NMR results showed the presence of higher degree of cross-linking of silyl species between silica and GIC, which makes the Nano-HA–Silica–GIC composite much stronger. High-resolution transmission electron microscopy (TEM) and scanning electron microscopy (TEM) was employed to investigate the morphology of the synthesized powder. Results revealed that higher content of nanosilica produced a denser and stronger GIC. Thus, the application of nanohydroxyapatite–silica–GIC with improved properties are envisioned to be of great clinical importance, especially in stress bearing areas.     

Structural and Magnetic Studies of Rare-Earth Substituted Nickel Ferrites

Polycrystalline ferrites NiFe₂O₄ and NiFe_1.99R_0.01O₄ (R=Sm, Gd, Eu, and La) samples were prepared by usual ceramic method. The structural and the magnetic properties of the samples were characterized by X-ray powder diffraction (XRD), Mössbauer Effect (ME) spectroscopy, and vibrating sample magnetometer (VSM). Indexed XRD patterns confirm the formation of pure cubic spinel phase. The lattice parameters (a) of the rare earth (R) doped samples were smaller than that of the pure Ni-ferrite. Mössbauer effect spectroscopy was used to study the distribution of cations in tetrahedral (A) and octahedral [B] sites of the spinel. The hysteresis loops indicated that the saturation magnetization and coercivity increased with R-substitution and appeared to be greatly affected by the nature of R ions. The obtained results are interpreted based on the rearrangement of cations between the A-site and B-site.     

Enclothed cognition and hidden meanings in important Ottoman textiles

This paper illustrates how hidden details in garment design may reveal important clues about the motives of the wearer or designer that are of considerable cultural relevance. We suggest these hidden design features may reflect key psychological factors previously not considered. We illustrate this by doing a multilevel analysis of two important sixteenth century examples of Ottoman court clothing from the Topkapi Palace Museum. We show that these garments contain early examples of the use of “enclothed cognition” where the designs themselves are likely to have influenced the mind of the wearer. We suggest that the historical-social analysis of clothing may benefit from considering the concealed, as well as the explicit, psychologically relevant design features. We suggest that psychosocial interpretations of clothing may help further our understanding of textile and apparel design more generally, even within an historical context.     

Measurement Uncertainty Analysis of Temperature Based Solar Radiation Estimation Models

Solar radiation is the main energy source for activities in the earth. It is important that the solar radiation values are known accurately. In cases where parameters about solar radiation cannot be measured, solar radiation estimation models are used. These are mathematical functions derived from the measured meteorological parameters. In this study, temperature-based estimation models that commonly used in the literature were examined, and uncertainty analysis of the models were applied. These solar radiation estimation models are Allen model, Hargreaves model, Chen model and Bristow–Campbell model. These models calculate the total global solar radiation with the difference between the maximum and minimum air temperatures. Measurement uncertainty budgets of the models and an example calculation can be found in the study.     

Experimental characterization and performance study of an ammonia–water–hydrogen refrigerator

We present in this paper an experimental study of a commercial diffusion-absorption refrigeration machine (DAR) operating on the Platen and Munters cycle. The temperatures at the inlet and outlet of every component of the machine, as well as the cabinet and ambient temperature are measured continuously. The tests are repeated for various electric power inputs to the refrigerator. The global heat transfer coefficient of the cabinet (UA)_cab is determined using both theoretical and experimental methods. This coefficient is found equal to 0.2 W/°C. The global heat transfer coefficient of the evaporator (UA)_evap is deduced using dynamic and steady state methods. This global heat transfer coefficient (UA)_evap is found equal to 0.3 W/°C. Finally the cooling capacity of the unit and the coefficient of performance are evaluated. The heating power supply to the generator necessary to ensure the desired state of this machine is found to be in the range of 35 W–45 W.     

Reliability-Aware Heterogeneous 3D Chip Multiprocessor Design

Ability to stack separate chips in a single package enables three-dimensional integrated circuits (3D ICs). Heterogeneous 3D ICs provide even better opportunities to reduce the power and increase the performance per unit area. An important issue in designing a heterogeneous 3D IC is reliability. To achieve this, one needs to select the data mapping and processor layout carefully. This paper addresses this problem using an integer linear programming (ILP) approach. Specifically, on a heterogeneous 3D CMP, it explores how applications can be mapped onto 3D ICs to maximize reliability. Preliminary experiments indicate that the proposed technique generates promising results in both reliability and performance.     

Feasibility of recycled newspaper as cellulose source for regenerated cellulose membrane fabrication

An environmental friendly regenerated cellulose membrane (RCM) was successfully prepared via NaOH/urea aqueous solution system by utilizing recycled newspaper (RNP) as the cellulose source. The morphological and chemical structure of resulting membrane were characterized using scanning electron microscopy (SEM), atomic force microscopy (AFM), transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, X‐ray diffraction (XRD) spectroscopy, and thermogravimetric analysis (TGA). Results from FTIR and XRD verified that the transparent RCM possesses cellulose II structure. SEM observation revealed that the transparent RCM consist of homogeneous dense symmetric membrane structure and composed of a skin layer with mean roughness parameter R_a, obtained from AFM analysis of 29.53 nm. Pure water flux, water content, water contact angle, porosity, and pore size of the resulting membrane were also measured. This study promotes the potential of the cellulose‐based membrane obtained from low cost cellulose source for application in filtration and separation system. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42684.     

Influence of metal‐oxide‐supported bentonites on the pyrolysis behavior of polypropylene and high‐density polyethylene

In this article, we report on the pyrolysis of polypropylene (PP) and high‐density polyethylene (HDPE) in the absence and presence of plain and metal‐oxide‐impregnated bentonite clays [BCs; acid‐washed bentonite clay (AWBC), Zn/AWBC, Ni/AWBC, Co/AWBC, Fe/AWBC, and Mn/AWBC] into useful products. Thermal and catalytic runs were performed at 300°C in the case of PP and at 350°C in the case of HDPE for a contact time of 30 min. The effects of different catalysts and their concentrations on the overall yields and the yields of liquid, gas, and residue were studied. The efficacy of each catalyst is reported on the basis of the highest liquid yields (in weight percentage). The derived liquid products were analyzed by Fourier transform infrared spectroscopy and gas chromatography–mass spectroscopy; this confirmed the presence of paraffins, olefins, and naphthenes. The results indicate the catalytic role of impregnated BCs compared to plain BC with the optimum efficiency shown by Co/AWBC in the case of PP and Zn/AWBC in the case of HDPE toward the formation of liquid products in a desirable C range with the enrichment of olefins and naphthenes in the case of PP and paraffins and olefins in the case of HDPE compared to the thermal run. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41221.     

Augmented reality assisted facility layout digitization and planning

Journal of Mechanical Science and Technology - Facility layout planning (FLP) has an important role in manufacturing industries. There are few approaches to solve FLP such as procedural,...     

A new application of giant reed waste material for ammonium removal

Excess nitrogen is one of the main causes of eutrophication in water bodies. In this study, the undesirable agricultural lignocellulosic material giant reed was used to remove ammonium ions from aqueous solutions. Batch experiments were conducted to investigate the effect of various parameters such as contact time, initial ammonium concentration, adsorbent dosage, pH, particle size, agitation rate and phosphate coexisting during the ammonium adsorption process. The ammonium sorption capacity of fibrous giant reed (FGR) at equilibrium was 12.49?mg?N/g with a maximum removal efficiency of 76% observed within 30?min at pH range of 6.5–9.5. Results revealed that the Freundlich isotherm model fitted better with the sorption process than the Langmuir model, and the adsorption process was well described by pseudo-second-order kinetic model. FT-IR analyses indicated that complexation and ion exchange could be the main mechanisms for the ammonium removal by FGR. Results revealed that FGR has a sorption capacity comparable to that of other natural sorbents with the advantage of greater availability with no cost.