Influence of accelerated ageing on methacrylate‐based denture resins heterogeneity as viewed by ESR‐spin‐probe method

The electron‐spin‐resonance (ESR) spin‐probe method, was used to study the heterogeneity of denture resins based on poly(methyl methacrylate). Results for three resins processed by microwave energy, conventional curing and cold curing (depending on the curing procedure and exposed to ageing in various environmental conditions) were compared. All three cured resins were stored over the same time (1200 h) in distilled water at ambient temperature and in artificial saliva at 348 K. The temperature‐dependent ESR spectra of a spin probe dispersed in the denture resins are analyzed in terms of line‐shapes and line‐widths. The appearance of two spectral components was taken as an indication of resin heterogeneity. The results reveal that the cold‐cured resin has a lower local density in comparison with microwave and conventionally cured resin. The amount of residual monomer also contributes to the local motion of polymer segments. The change of denture resins exposed to ageing is influenced both by the structure of the original resin and the ageing conditions. Restricted motion of a spin probe incorporated into the acrylic resins exposed to accelerated ageing suggests additional crosslinking of polymer chains. The differences are observed for all the investigated resins, but the highest change is observed with the cold‐cured resin. The ESR results are accompanied by T_g and T_m measurements. Copyright © 2005 Society of Chemical Industry     

Correlation of reactivity with chemical structure: Thermal hydrogenation of gas oils

The relationship between chemical structure and reactivity for thermal hydroprocessing was studied for five gas oils derived from Alberta bitumens. Chemical structure was characterized by combining data from ¹ H and ¹³ C nuclear magnetic resonance spectroscopy, class fractionation, and elemental analysis to calculate structural parameters. Thermal hydrotreating was performed in a continuous-flow stirred reactor at 420 and 440°C, 13.9 MPa hydrogen pressure, and 1.5 h¹ LHSV. Conversion of the 343–525°C boiling fraction of the gas oils was correlated with the concentration of naphthenic methylene groups in the feed. Formation of methane and ethane was dependent on the degree of condensation of the aromatic rings in the feed oils. Thermal desulfurization was highly correlated with the amount of saturates in the feed, and the aromaticity of the resin fraction. Hydrogen consumption increased with the aromaticity of the gas oil…     

Theory of porous electrodes—XI. The positive plate of the lead-acid battery

Partial differential equations describing the transport of mass and electricity in the pores of the positive electrode of a lead acid battery were derived. The theory is based on exact transport equations and on the assumption that the solid porous matrix has a metallic conductivity. Volume changes in both phases are taken into account. Numerical solutions obtained on a computer are presented for the case where the influence of electrolyte between the electrodes can be neglected. The solutions depend on the product of electrode thickness times current density, and on the initial porosity.     

Localization-limited exciton oscillator strength in colloidal CdSe nanoplatelets revealed by the optically induced stark effect

2D materials are considered for applications that require strong light-matter interaction because of the apparently giant oscillator strength of the exciton tra...     

New voltage-mode universal filter and sinusoidal oscillator using only single DBTA

In this article, a new voltage-mode second-order universal frequency filter and sinusoidal oscillator using only single differential-input buffered and transconductance amplifier (DBTA) is presented. The proposed voltage-mode filter structure using single DBTA and four passive elements can provide all standard filter functions, i.e. low-, band-, high-pass, band-stop, and all-pass without changing the circuit topology and enables independent control of the quality factor Q using single passive element. The circuit requires the minimal number of active and passive elements with no conditions for component matching. By slight modification of the proposed filter structure, the new DBTA-based sinusoidal oscillator is easily obtained. The oscillation condition and the oscillation frequency are independently adjustable by different virtually grounded passive elements. The proposed sinusoidal oscillator employs only grounded capacitors. The passive and active sensitivities of all the proposed circuit configurations are low. PSPICE simulations using a BJT realisation of DBTA and experimental results based on commercially available amplifiers OPA860 and MAX436 are included, which prove the workability of the proposed circuits.     

Power and Speed-Efficient Code Transformation of Video Compression Algorithms for RISC Processors

Upcoming multi-media compression applications will require high memory bandwidth. In this paper, we estimate that a software reference implementation of an MPEG-4 video decoder typically requires 200 Mtransfers/s to memory to decode 1 CIF (352×288) Video Object Plane (VOP) at 30 frames/s. This imposes a high penalty in terms of power but also performance.However, we also show that we can heavily improve on the memory transfers, without sacrificing speed (even gaining about 10% on cache misses and cycles for a DEC Alpha), by aggressive code transformations. For this purpose, we have manually applied an extended version of our data transfer and storage exploration (DTSE) methodology, which was originally developed for custom hardware implementations.     

A Scalable Architecture for MPEG-4 Wavelet Quantization

Wavelet-based image compression has been adopted in MPEG-4 for visual texture coding. All wavelet quantization schemes in MPEG-4—Single Quantization (SQ), Multiple Quantization (MQ) and Bi-level Quantization—use Embedded Zero Tree (EZT) coding followed by an adaptive arithmetic coder for the compression and quantization of a wavelet image. This paper presents the OZONE chip, a dedicated hardware coprocessor for EZT and arithmetic coding. Realized in a 0.5 m CMOS technology and operating at 32 MHz, the EZT coder is capable of processing up to 25.6 Mega pixel-bitplanes per second. This is equivalent to the lossless compression of 31.6 8-bit grayscale CIF images (352 × 288) per second. The adaptive arithmetic coder processes up to 10 Mbit per second. The combination of the performance of the EZT coder and the arithmetic coder allows the OZONE to perform visual-lossless compression of more than 30 CIF images per second. Due to its novel and scalable architecture, parallel operation of multiple OZONEs is supported. The OZONE functionality is demonstrated on a PC-based compression system.