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排序方式: 共有600条查询结果,搜索用时 15 毫秒
51.
Ufuk Yildiz Ignác Capek Dušan Berek Yanko Sarov Ivo W Rangelow 《Polymer International》2007,56(3):364-370
The inverse microemulsion copolymerization of acrylamide and butyl acrylate initiated by ammonium peroxodisulphate, a water‐soluble initiator, and stabilized by anionic emulsifiers sodium bis‐2‐ethylhexylsulfosuccinate and sodium dodecylsulphate (SDS) has been studied. An increase of SDS concentration was observed to increase both the rate of polymerization and the particle size. The average number of radicals per particle (n?) is much below 0.5, which indicates desorption of monomeric radicals from polymer particles. The exit (desorption) rate constants k′des (cm2 s?1) and kdes (s?1) were evaluated as a function of SDS concentration (or the particle size) according to the Ugelstad/O'Toole (I), Nomura (II) and Gilbert (III) models. The value of kdes (s?1) decreases with increasing particle size (or SDS concentration) for all three (I, II and III) models. A complex trend appears for k′des (cm2 s?1): the Ugelstad/O'Toole model estimates a decrease, the Nomura model finds no variation and the Gilbert model estimates even a slight increase in k′des with increasing SDS concentration. Copyright © 2006 Society of Chemical Industry 相似文献
52.
Aqueous solutions of poly(vinyl alcohol) and poly(vinyl pyrrolidone) are blended and films are produced by casting method with the further intention of being used as bio‐materials with latent medical application. Glutaraldehyde, 4,4′‐diazido‐2,2′‐stilbenedisulfonic acid disodium salt tetra‐hydrate are used as crosslinker agents, whereas lactic acid is the plasticizer in the blend. The obtained films are characterized by differential scanning calorimetry (DSC), mechanical properties, swelling and solubility behavior. DSC measurements show that the blends exhibit a single glass transition temperature indicating that they are miscible, even in the presence of the plasticizer and crosslinker agents. By the combination of all mentioned additives, a relevant enhancement of the swelling is observed, accompanied by a stabilization of the solubility during the tested time. Finally, mechanical properties show an appropriate performance in the studied parameters. As a consequence, the obtained films could be suitable for use as medium or long‐term implants. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
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Leena Maunula Agnieszka Kaupke Petra Vasickova Kirsi Söderberg Iwona Kozyra Sava Lazic Wim H.M. van der Poel Martijn Bouwknegt Saskia Rutjes Kris A. Willems Rita Moloney Martin D'Agostino Ana Maria de Roda Husman Carl-Henrik von Bonsdorff Artur Rzeżutka Ivo Pavlik Tamas Petrovic Nigel Cook 《International journal of food microbiology》2013
In recent years, numerous foodborne outbreaks due to consumption of berry fruit contaminated by human enteric viruses have been reported. This European multinational study investigated possible contamination routes by monitoring the entire food chain for a panel of human and animal enteric viruses. 相似文献
55.
The subject of this study is the influence of traces of mercury present in the hydrogen originating e.g. from the amalgam technology of brine electrolysis on the lifetime of PEM-type fuel cell. Accelerated tests were used in order to record deterioration of laboratory fuel cells’ performance. The power output decrease observed was only partly reversible. As was proven by XPS spectroscopy, the cell performance deterioration originates from the interaction between mercury and the platinum catalyst. The lifetime of the fuel cell was assessed on the basis of the experiments performed as 7000 h for an average mercury concentration in the hydrogen of 10 μg N m−3. This is a sufficient value to permit utilization of the hydrogen from this source as a fuel for the fuel cell. It should be kept in the mind, however, that this value was obtained on the basis of the accelerated durability tests. 相似文献
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Porous Materials: Submicrometer‐Sized ZIF‐71 Filled Organophilic Membranes for Improved Bioethanol Recovery: Mechanistic Insights by Monte Carlo Simulation and FTIR Spectroscopy (Adv. Funct. Mater. 4/2015) 下载免费PDF全文
58.
The knowledge of the behaviour of radioactive aerosol particles in the uranium mine atmosphere is very important due to the evaluation of the effective dose for uranium miners. During the research of the project SUJ200402-'Study of behaviour of natural long-lived radionuclides in the mine atmosphere', several measurement campaigns were performed in the last active Central Europe uranium mine Rozna I. The main purpose of this paper is characterisation the radionuclides which creating the main part of the airborne radioactivity in the uranium mine atmosphere. The present paper introduces results of the measurements of airborne radioactivity in stopes of the uranium mine Rozna I. The measurements were performed at the 21st floor at a depth of ~1100 m under the ground. In addition to the concentration of (222)Rn, its progenies, long-lived radionuclides and also the concentration of aerosol particles were measured. 相似文献
59.
As JET is developing and testing operational scenarios for higher fusion performance, an increase in pulse disruptivity is being observed. On a deeper analysis, we find that several radiative phenomena play an active role in determining the outcome of the pulse. The analysis is enabled by the use of real-time tomography based on the bolometer diagnostic. Even though plasma tomography is an inverse problem, we use machine learning to train a forward model that provides the radiation profile directly, based on a single matrix multiplication step. This model is used to investigate radiative phenomena including sawtooth crashes, ELMs and MARFE, and their relationship to the radiated power in different regions of interest. In particular, we use real-time tomography to monitor the core region, and to throw an alarm whenever core radiation exceeds a certain threshold. Our results suggest that this measure alone can anticipate a significant fraction of disruptions in the JET baseline scenario. 相似文献
60.
Enrico Rebufello Fabrizio Piacentini Alessio Avella Muriel A.de Souza Marco Gramegna Jan Dziewior Eliahu Cohen Lev Vaidman Ivo Pietro Degiovanni Marco Genovese 《光:科学与应用(英文版)》2021,10(6):963-968
Is it possible that a measurement of a spin component of a spin-1/2 particle yields the value 100? In 1988 Aharonov, Albert and Vaidman argued that upon pre-and... 相似文献