ALUM SHALE BITUMEN MATURATION AND MIGRATION: IMPLICATIONS FOR GOTLAND'S OIL

Thermal maturation of Swedish Alum Shale kerogen and bitumen has been determined from core samples from Eastern and Central Sweden. In samples from Eastern Sweden (Öland and Gotland), the kerogen and bitumen are thermally immature with respect to petroleum generation. In some areas of Central Sweden (Närke, ÖstergÖtland, and Kinnekulle in VästergÖtland), the kerogen is immature, whereas the bitumen is marginally mature to mature. In other areas of Central Sweden (Halleberg-Hunneberg in VästergÖtland), the kerogen is supermature and the bitumen mature. This suggests that bitumen from a mature source-rock has migrated into the Alum Shales of Central Sweden. Migration in Central Sweden is further evidenced by the occurrence of obviously-migrated bituments in vugs and voids in the organicpoor Ordovician limestone overlying the Alum Shale in Central Sweden, and in concretions within the Alum Shale itself. Based on biomarker distributions of extracted bitumen, Alum Shale kerogen pyrolysate and obviously-migrated oils, and the fact that the Alum Shale in most of the areas studied is the only petroleum source-rock extant, it is suggested that the migrated bitumen in Central Sweden is from the Alum Shale itself. Bitumen has migrated from areas where the Alum Shale is in close proxmity to Permo-Carboniferous intrusions, such as Halleberg-Hunneberg, into nearby areas such as Närke and ÖstergÖtland, where there is no evidence of intrusion and the indigenous organic matter is thermally immature. Other areas, where Alum Shales were associated with intrusions and consequently sourced oil, may have been eroded away. There are producing wells on the island of Gotland, where the Alum Shale is also thermally immature. It is therefore assumed that heating which was responsible for generating Gotland's oil was very localized (such as by an intrusion) or that the oil has migrated from a thermally moremature, distant area. On the basis of reservoir rock porosity, and the fact that the Alum Shale of Gotland contains no migrated component, localized heating is favored.     

Fine-line conductor manufacturing using drop-on demand PZT printingtechnology

An emerging selective metallization process to fabricate fine-line conductors based on drop-on-demand (DOD) ink jet printing and novel nano-particle fluid suspensions (NPFS) was studied. The suspensions consist of 1-10 nm silver or gold particulates that are homogeneously suspended in an organic carrier. A piezo-electric droplet generator driven by a bipolar voltage signal is used to dispense 50-70 μm diameter droplets traveling at 1-3 m/s before impacting a compliant polyimide substrate. The deposit/substrate composite is subsequently processed at 300°C for 15 min to allow for complete evaporation of the carrier and for sintering of the nano-particles, thereby yielding a finished circuit interconnect. Test vehicles created using this technique exhibit features as fine as 120 μm wide and 1 μm thick with resistivities on the order of 3.5×10^-5 Ωcm. The circuitry performed well under environmental conditioning. As expected, repeatability of circuitry fabrication showed sensitivity to the generation of steady, satellite-free droplets. In an effort to generate droplets consistently, it is essential to develop a strong fundamental understanding of the correlation between device excitation parameters and dispensed fluid properties, and to resolve the microrheological behavior of the NPFS when flowing through the droplet generator     

Solution of process flowsheets by formal gauss elimination

The paper describes the principles involved in two computer programs which calculate mass and heat balances for ammonia and methanol loops. Non-linear conditions are solved in an outer loop whereas the inner loop solves a set of linear equations by a formal Gauss triangulation and numerical back substitution.     

A Compositional Framework for Hardware/Software Co-Design

We describe a compositional framework, together with its supporting toolset, for hardware/software co-design. Our framework is an integration of a formal approach within a traditional design flow. The formal approach is based on Interval Temporal Logic and its executable subset, Tempura. Refinement is the key element in our framework because it will derivefrom a single formal specification of the system the software and hardware parts of the implementation, while preserving all properties of the system specification. During refinement simulation is used to choose the appropriate refinement rules, which are applied automatically in the HOL system. The framework is illustrated with two case studies. The work presented is part of a UK collaborative research project between the Software Technology Research Laboratory at the De Montfort University and the Oxford University Computing Laboratory.     

The Climate for Creativity and Change in Teams

This article reports the results of a study conducted to examine the ability of the Situational Outlook Questionnaire (SOQ^TM) to effectively discern climates that either encourage or discourage creativity and the ability to initiate change in a team setting. The purpose of the study is to examine the concurrent criterion–related validity of the SOQ. The article explores the characteristics in an organisational climate that promote teamwork and some of the tripwires one needs to be aware of in the formation and management of teams. Nine dimensions of the climate for creativity and change as measured by the Situational Outlook Questionnaire are put forward and defined in relation to teams. The methodology and results of the study are reported. The results show that when subjects (N7equals;154) complete the SOQ based on their recollection of a best– and worst–case team experience, the measure is able to consistently and significantly discriminate between the two types of experiences. Conclusions, implications, and areas for future research to further examine the validity of the SOQ are explored.     

High-power P-i-N diode with the local lifetime control based on theproximity gettering of platinum

We demonstrate for the first time a high-power P-i-N diode with local lifetime control using the proximity gettering of platinum in the FZ silicon. The region of maximal damage resulting from the low-dose helium implantation was decorated by substitutional platinum that diffused from the PtSi anode contact at low temperature (700°C) through the P⁺-P anode doping at the distance of 70 μm. The diodes show very low forward voltage drop with negative temperature coefficient and very low leakage current even at elevated temperatures while keeping the major advantages of the ion irradiated devices like low turn-off losses and soft recovery     

Combined shape and sizing optimization of truss structures

 In this paper, an evolutionary optimization method is presented for weight minimum problem of a 3-dimensional truss structure in terms of nodal coordinates and element cross-sectional areas. The structure is subject to stress, local buckling and displacement constraints. Two types of design variables with different natures are optimized separately: (1) a fully stressed design (FSD) and scaling techniques are applied to sizing variables and (2) the evolutionary node shift method is applied to shape variables. Alternating procedure is utilized to couple the two types of variables and to combine the results. The optimum solution is achieved gradually from the initial configuration design. Two typical truss structures are examined to illustrate the validity of the method. Received: 22 October 2001 / Accepted: 04 June 2002 This research work is supported by the National Natural Science Foundation of China under the guarantees no. 10072050 and 10172072, respectively.