Anchoring single Pt atoms on hollow Ag3VO4 spheres for improved activity towards photocatalytic H2 evolution reaction

The high cost of noble metal catalysts has been a great bottleneck for the catalyst industry. Using the noble metal at a single-atom level for catalytic applications could dramatically decrease the cost. The impacts of single Pt atoms on the photocatalytic performance of Ag₃VO₄ have been investigated and reported. In this report, single Pt atoms were anchored on the surface of Ag₃VO₄ (AVO) as a cocatalyst, and the resultant composite photocatalyst has been studied for photocatalytic H₂ production from water driven by visible light. The as-prepared AVO particles are hollow nanospheres in the monoclinic phase with a bandgap of 2.20 eV. The light absorption edge of AVO/Pt is slightly red-shifted compared to that of the pristine AVO, indicating more visible light absorption of AVO/Pt. The XPS peaks of Ag, V, and Pt exhibit a significant shift after AVO and Pt get into contact, suggesting the strong interaction between the surface Ag and V atoms, and single Pt atoms. After 3-h illumination, the photocatalytic H₂ evolution amount from AVO/Pt is improved up to 1400 μmol, which is 2.8 times that on the bare AVO. Such efficient photocatalytic H₂ evolution on AVO/Pt is still maintained after five reaction cycles. The better photocatalytic performance of AVO/Pt has been attributed to the more efficient visible light utilization and the lower interfacial charge transfer resistance, as demonstrated in the DRS and EIS spectra. The presence of the surface Pt atoms also leads to a higher amount of reactive radicals, which could efficiently promote the surface redox reactions.     

氢化物原子荧光光谱法测定酱油中微量铅的方法研究

建立了一种快速、高效的QuEChERS-高效液相色谱-质谱联用法（QuEChERS-HPLC-MS/MS）测定谷类杂粮制品中脱氧雪腐镰刀菌烯醇（DON）、3-乙酰脱氧雪腐镰刀菌烯醇（3-ADON）、15-乙酰脱氧雪腐镰刀菌烯醇（15-ADON）和玉米赤霉烯酮（ZON）共4种真菌毒素。样品前处理采用乙腈-水溶剂提取，经Florisil+C18+无水硫酸镁净化后检测。以0.10%甲酸-乙腈作为流动相，在质谱检测器的多反应监测模式下进行分析。结果表明，4种真菌毒素在各自的线性范围内线性关系良好，相关系数R2均大于0.999，回收率在85.1%～102.0%，相对标准偏差（RSD）为2.11%～6.22%。该方法具有前处理简单、净化效果好、灵敏度高和检测速度快的优点，适用于谷类杂粮制品中DON、3-ADON、15-ADON 和ZON的分析和定量检测。     

一种基于Spark的不确定数据集频繁模式挖掘算法

如何在海量不确定数据集中提高频繁模式挖掘性能是目前研究的热点.传统算法大多是以期望、概率或者权重等单一指标为数据项集支持度，在大数据背景下，同时考虑概率和权重支持度的算法难以兼顾其执行效率.为此，本文提出一种基于Spark的不确定数据集频繁模式挖掘算法（UWEFP），首先，为了同时兼顾数据项的概率和权重，计算一项集的最大概率权重值并进行剪枝；然后，为了减少对数据集的多次扫描，结合Spark框架的优点，设计了一种具有FP-tree特征的新颖的UWEFP-tree结构进行模式树的构建及挖掘；最后在Spark环境下，以UCI数据集进行实验验证.实验结果表明本文的方法在保证挖掘结果的同时，提高了效率.     

Model Selection for Unsupervised Learning of Visual Context

This study addresses the problem of choosing the most suitable probabilistic model selection criterion for unsupervised learning of visual context of a dynamic scene using mixture models. A rectified Bayesian Information Criterion (BICr) and a Completed Likelihood Akaike’s Information Criterion (CL-AIC) are formulated to estimate the optimal model order (complexity) for a given visual scene. Both criteria are designed to overcome poor model selection by existing popular criteria when the data sample size varies from small to large and the true mixture distribution kernel functions differ from the assumed ones. Extensive experiments on learning visual context for dynamic scene modelling are carried out to demonstrate the effectiveness of BICr and CL-AIC, compared to that of existing popular model selection criteria including BIC, AIC and Integrated Completed Likelihood (ICL). Our study suggests that for learning visual context using a mixture model, BICr is the most appropriate criterion given sparse data, while CL-AIC should be chosen given moderate or large data sample sizes.     

新安江电站进水口快速闸门动水闭门鉴定试验

本文叙述了应用现代科学方法和实验原型观测技术对新安江水电站进水口快速闸门进行安全检测鉴定，并介绍了水电站快速闸门动水闭门试验程序，对水电站快速闸门试验及相关鉴定有重要参考意义。     

变频器调速装置节能浅析

1概述 近十多年来,随着电力电子技术、微电子技术及现代控制理论的发展,变频调速技术已经广泛地用于交流电动机的速度控制,其最主要的特点是具有高效率的驱动性能及良好的控制特性.它是一种高新技术电力节能装置,它通过改变（降低）电源工作频率,来降低动力设备（电机）的转速,减少设备的输出功率,达到输出功率与工作负荷的最佳匹配,实现节能目的,有效地提高了经济效益和产品质量.几乎可以说,有电动机的地方就有变频器,在一切需要进行速度控制的场合,变频器以其操作方便、体积小、控制性能高而获得广泛应用.     

腐蚀磨损过程中材料的环境脆性

从腐蚀磨损的交互作用、腐蚀磨损与应力腐蚀及氢脆的异同出发，论述了磨损加速腐蚀及腐蚀加速磨损的微观机制，指出材料的环境脆性与腐蚀对磨损的加速作用程度有关．从腐蚀对磨损的加速作用、比能耗、磨痕硬度等方面分析了不锈钢 Cl^-体系、Ni-P镀层 NaOH溶液、H4340钢与Ti6A14V合金 稀硫酸溶液体系、铜合金 NH4^ (NH3)或S^2-溶液中的环境脆化行为和规律，总结出材料环境脆性的力学判据，展望了今后腐蚀磨损的研究方向．     

水驱前缘测试技术在复杂砂岩油藏中的应用

对平面剩余油分布的认识，是油田开发后期的一项重要工作，水驱前缘测试是当前平面剩余油监测比较好的方法之一。水驱前缘测试技术是利用注水产生的微地震，通过检测分析微震信号来确定裂缝发育状况、水驱波及范围、优势注水方向，为评价区块水驱状况和平面剩余油分析提供直接依据。因此开展该项技术的现场试验与运用研究，对油田开发和产油增效具有重要意义。文章介绍了该技术方法的原理以及在华北复杂砂岩油藏水驱特征分析中的应用效果。     

复杂土坝的渗流安全分析评价

根据福华山土坝的渗流观测资料,建立了测压管水位的回归统计模型,定量分析了各影响量(水位分量、时效分量)对测压管水位的影响效应。在此基础上,结合观测资料,采用有限元法反演了大坝各填筑区的渗透系数,并综合评价了大坝的渗流性态。     

USB数据传输中CRC校验码的并行算法实现

文章介绍了用于USB总线数据传输的CRC校验的原理和算法，并且采用并行电路实现USB2．0中的CRC产生和CRC校验，与传统的串行电路实现相比，并行电路实现方法虽然在芯片面积上大于串行电路实现，但由于降低了时钟频率，电路更容易综合实现，并且大大降低了功耗，有利于低功耗电路设计。