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951.
In this paper, we are concerned with identification of a discrete uniform mixture by the posterior mean. An exact formula
for a prior distribution is given. Also some examples featuring negative binomial, negative hypergeometric and beta-Pascal
distributions are provided. 相似文献
952.
Angela D. Lueking Hye-Young Kim Jacek Jagiello Kevin Bancroft J. Karl Johnson Milton W. Cole 《Journal of Low Temperature Physics》2009,157(3-4):410-428
An adsorption isotherm provides indirect information about the geometry of the host material and its interaction with the adsorbed fluid. This paper presents a critical study of the “inversion” of experimental data to elucidate desired information about this geometry. Using Ar and H2 as representative classical and quantum fluids and a carbon slit-pore geometry, we compare the accuracy of isotherms derived from non-local density functional theory with isotherms from grand canonical Monte Carlo simulations, using a quantum-corrected potential for H2. We determine the pore size distributions (PSDs) for a series of model and experimental materials by inverting the adsorption integral equation, with the goal of probing the ability of the inversion procedure to reproduce faithfully the input pore size distribution and ascertain the reality of anomalous gaps often deduced in the literature. Drawing from the GCMC simulations, we then explore the concept of effective porous materials, or ‘iso-PSDs’, which have similar adsorption isotherms, despite very different pore size distributions. 相似文献
953.
Alicja Nowaczyk Magdalena Kowalska Jacek Nowaczyk Grzegorz Grzek 《International journal of molecular sciences》2021,22(11)
The year 2021 is the 100th anniversary of the confirmation of the neurotransmission phenomenon by Otto Loewi. Over the course of the hundred years, about 100 neurotransmitters belonging to many chemical groups have been discovered. In order to celebrate the 100th anniversary of the confirmation of neurotransmitters, we present an overview of the first two endogenous gaseous transmitters i.e., nitric oxide, and carbon monoxide, which are often termed as gasotransmitters. 相似文献
954.
Radek Zaleski Wojciech Stefaniak Małgorzata Maciejewska Jacek Goworek 《Journal of Porous Materials》2009,16(6):691-698
The porosity of porous copolymer 1-vinyl-2-pyrrolidone-divinylbenzene has been studied by nitrogen adsorption, temperature
programmed desorption, and positronium annihilation lifetime spectroscopy. It was shown that the pore structure characteristics
depends on the swelling of the polymer material in various solvents. The structural features of polymeric materials restructured
under different conditions are described and the structural changes are discussed. The applicability of PALS technique in
structural investigations is presented. 相似文献
955.
956.
957.
Willy Maenhaut Jacek Ptasinski Jan Cafmeyer 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》1999,150(1-4):422-427
As part of the 1996 summer intensive of the Aerosol, RAdiation and CHemistry Experiment (ARACHNE-96), the mass size distribution of various airborne particulate elements was studied at a remote site in the Negev Desert, Israel. Aerosol collections were made with 8-stage PIXE International cascade impactors (PCIs) and 12-stage small deposit area low pressure impactors (SDIs) and the samples were analyzed by PIXE for about 20 elements. The mineral elements (Al, Si, Ca, Ti, Fe) exhibited a unimodal size distribution which peaked at about 6 μm, but the contribution of particles larger than 10 μm was clearly more pronounced during the day than during night. Sulphur and Br had a tendency to exhibit two modes in the submicrometer size range, with diameters at about 0.3 and 0.6 μm, respectively. The elements V and Ni, which are indicators of residual fuel burning, showed essentially one fine mode (at 0.3 μm) in addition to a coarse mode which represented the mineral dust contribution. Overall, good agreement was observed between the mass size distributions from the PCI and SDI devices. The PCI was superior to the SDI for studying the size distribution in the coarse size range, but the SDI was clearly superior for unravelling the various modes in the submicrometer size range. 相似文献
958.
Alexander Kyrychenko Jerzy Herbich Marcin Izydorzak Michał Gil Jacek Dobkowski Feiyue Wu Randolph P. Thummel Jacek Waluk 《Israel journal of chemistry》1999,39(3-4):309-318
Photoinduced two-proton tautomerization has been studied in two types of chromophores: (i) alcohol complexes of azaaromatic molecules possessing both proton donor and acceptor groups; (ii) constitutional isomers of porphyrin. The reaction path for the intermolecular process may involve solvent reorientation around the excited chromophore. In this case, rapid internal conversion is activated, efficiently competing with proton transfer. Another possibility arises if cyclic, doubly-hydrogen-bonded complexes exist already in the ground state. Excitation of such species leads to a fast tautomerization, which is not stopped even at low temperatures. Excited-state double proton transfer also has been observed in cyclic dimers in the crystal phase. In porphyrin isomers, the rate of the process is a function of the strength of the intramolecular hydrogen bond. Dependence of the phototautomerization rate on temperature and on the nature of the surrounding matrix has also been studied. 相似文献
959.
Rafa Czerwieniec Andrzej Kapturkiewicz Jacek Nowacki 《Inorganic chemistry communications》2005,8(12):1101-1104
Reaction of Re(CO)5Cl with 2-phenylbenzothiazole (HΦBT) afforded the cyclometalated Re(CO)4(ΦBT) complex with the molecular structure of the obtained product confirmed by X-ray investigations. Re(CO)4(ΦBT) shows intense, hardly dependent on environment, luminescence originating from the π–π* ΦBT intraligand electronic transition. The investigated Re(CO)4(ΦBT) complex can be considered as a potentially applicable “triplet emitter” for OLED devices. 相似文献
960.