The effects of nanoparticle shape and orientation on the low frequency dielectric properties of nanocomposites

In this paper, we examine the effects of aspect ratio and orientational order of nanoparticles on the dielectric properties of nanocomposites. The motivation is to clearly establish the effects of orientational order, since ambiguities exist in the literature. We focus on metallic nanoparticles, and show that, in the dilute concentration limit, theory, experiments and numerical simulations all unequivocally indicate that the effective dielectric constant increases with increasing aspect ratio and increasing degree of alignment of rod-like nanoparticles when they orient in direction of the electric field.     

Solid-state synthesis of multicomponent equiatomic rare-earth oxides

Phase formation in multicomponent rare-earth oxides is determined by a combination of composition, sintering atmosphere, and cooling rate. Polycrystalline ceramics comprising various combinations of Ce, Gd, La, Nd, Pr, Sm, and Y oxides in equiatomic proportions were synthesized using solid-state sintering. The effects of composition, sintering atmosphere, and cooling rate on phase formation were investigated. Single cubic or monoclinic structures were obtained with a slow cooling of 3.3°C/min, confirming that rare-earth oxides follow a different structure stabilization process than transition metal high-entropy oxides. In an oxidizing atmosphere, both Ce and Pr induce a cubic structure, while only Ce plays that role in an inert or reducing atmosphere. Samples without Ce or Pr develop a single monoclinic structure. The structures formed at initial synthesis may be converted to a different one, when the ceramics are annealed in an additional atmosphere. Phase evolution of a five-cation composition was also studied as a function of sintering temperature. The binary oxides used as raw materials completely dissolve into a single cubic structure at 1450°C in air.     

Basic study of ceramic lithium strontium borates as thermal neutron scintillators

A special group of luminescence materials are scintillators for thermal neutron detection. Due to the properties of neutrons (contrary to e.g. electrons or gamma photons), a different approach has to be utilized—the high content of atoms with the sufficient absorption cross-section toward neutrons and lower material density are needed. This work pursues a basic study of LiSrBO₃ and LiSr₄(BO₃)₃ doped with cerium or europium—materials promising as thermal neutron scintillators. These borates exhibit promising properties such as the high content of lithium and boron, suitable density, and proper environment for luminescent ions. Radioluminescence of these ceramic borates doped with cerium and europium was examined and promising samples were further characterized by photoluminescence spectroscopy and radioluminescence and photoluminescence kinetics measurement. The radioluminescence study of these borates is published for the first time. Cerium-doped borates, in particular, exhibit a very promising response to an X-ray excitation.     

Effects of sodium citrate plus sodium diacetate and buffered vinegar on Escherichia coli O157:H7 and psychrotrophic bacteria in brine-injected beef

The objective of this research was to examine the effects of sodium citrate plus sodium diacetate or buffered vinegar on Escherichia coli O157:H7 and psychrotrophic bacteria when incorporated in brine solutions for injected beef. Two experiments were conducted in which 30 top rounds and 30 top sirloins were injected (110%) to contain (i) 0.5% sodium chloride and 0.4% sodium tripolyphosphate as the control (CNT); (ii) CNT with a 1% solution of 80% sodium citrate plus 20% sodium diacetate (SC + D); or (iii) CNT with 2% buffered vinegar (VIN) in the final product. For the E. coli challenge, muscles were surface inoculated to target 6 log CFU/cm(2). After injection and 10 days of storage in a vacuum package (4°C), one half of each muscle was sampled raw and the other half was cooked to an internal temperature of 60°C with a 12-min hold. For raw samples, a significant reduction of 0.6 and 1.0 log CFU/g of E. coli O157:H7 was observed in both SC + D- and VIN-injected top rounds and sirloins, respectively. All cooked samples were E. coli O157:H7 negative. For psychrotrophic analysis, subprimals were injected and vacuum packaged for 10 days at 0 ± 1°C. After 10 days of storage, steaks were fabricated and placed in aerobic display (4 ± 1°C) for 1, 7, 14, and 21 days. Psychrotrophic organism growth was restricted in SC + D and VIN samples when compared with CNT on all days except day 1. Sodium citrate plus sodium diacetate or buffered vinegar may improve the safety and shelf life of multineedle brine-injected beef.     

Virus‐Templated Plasmonic Nanoclusters with Icosahedral Symmetry via Directed Self‐Assembly

The assembly of plasmonic nanoparticles with precise spatial and orientational order may lead to structures with new electromagnetic properties at optical frequencies. The directed self‐assembly method presented controls the interparticle‐spacing and symmetry of the resulting nanometer‐sized elements in solution. The self‐assembly of three‐dimensional (3D), icosahedral plasmonic nanosclusters (NCs) with resonances at visible wavelengths is demonstrated experimentally. The ideal NCs consist of twelve gold (Au) nanospheres (NSs) attached to thiol groups at predefined locations on the surface of a genetically engineered cowpea mosaic virus with icosahedral symmetry. In situ dynamic light scattering (DLS) measurements confirm the NSs assembly on the virus. Transmission electron micrographs (TEM) demonstrate the ability of the self‐assembly method to control the nanoscopic symmetry of the bound NSs, which reflects the icosahedral symmetry of the virus. Both, TEM and DLS show that the NCs comprise of a distribution of capsids mostly covered (i.e., 6–12 NS/capsid) with NSs. 3D finite‐element simulations of aqueous suspensions of NCs reproduce the experimental bulk absorbance measurements and major features of the spectra. Simulations results show that the fully assembled NCs give rise to a 10‐fold surface‐averaged enhancement of the local electromagnetic field.     

Construction of a Black consciousness measure: Psychotherapeutic implications.

Describes the Developmental Inventory of Black Consciousness (DIB-C). Empirical, theoretical, autobiographical, and biographical studies suggest there are 4 distinct stages of Black consciousness: the preconscious stage, confrontation, internalization, and integration. Items were written for each of these domains and administered to 160 Black male undergraduates. The DIB-C was analyzed by using a sequentially organized psychometric strategy of item discrimination and tests of homogeneity, social desirability, and differential validity. A construct validational study was also performed using the unpublished "Nadanolitization Scale," which measures the degree of internalization by Blacks of stereotypic attitudes held by Whites about Blacks. Results show 65 items remaining for the DIB-C following the sequential analysis. Construct validation showed an inverse linear relationship between the degree of "Nadanolitization" and progressive DIB-C scores. Psychotherapeutic implications are discussed. (12 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

On-shot focal-spot characterization technique using phase retrieval

We present an on-shot focal-spot characterization technique based on a phase-retrieval scheme that retrieves near-field phase from multiplane focal-spot measurements in an experimental target chamber. The technique is easy to implement inside a target chamber and is demonstrated in a multiterawatt laser system. It is also found that phase retrieval can quantitatively detect residual angular dispersion coming from the pulse compressor misalignment.     

Retention mechanism in reversed-phase liquid chromatography: a molecular perspective

A detailed, molecular-level understanding of the retention mechanism in reversed-phase liquid chromatography (RPLC) has eluded analytical chemists for decades. Through validated, particle-based Monte Carlo simulations of a model RPLC system consisting of dimethyloctadecylsilanes at a coverage of 2.9 micro mol/m2 on an explicit silica substrate with unprotected residual silanols in contact with a water/methanol mobile phase, we show that the molecular-level retention processes for nonpolar and polar analytes, such as alkanes and alcohols, are much more complex than what has been previously deduced from thermodynamic and theoretical arguments. In contrast to some previous assumptions, the simulations indicate that both partitioning and adsorption play a key role in the separation process and that the stationary phase in RPLC behaves substantially different from a bulk hydrocarbon phase. The retention of nonpolar methylene segments is dominated by lipophilic interactions with the retentive phase, while solvophilic interactions are more important for the retention of the polar hydroxyl group.     

Effects of Thermodiffusion and Nanoparticles on Convective Instabilities in Binary Nanofluids

In this article, the effects of thermodiffusion of nanoparticles and solute in binary nanofluids and nanoparticles on the convective instabilities of a binary nanofluid is theoretically investigated. Thermodiffusion implies that mass diffusion is induced by thermal gradient, which is the so-called Soret effect. In order to analyze the convective instabilities of a binary nanofluid, a new stability criterion is obtained based on the linear stability theory and new factors g and f are proposed. The results show that the Soret effect of solute makes the binary nanofluids unstable significantly and the convective motion in a binary nanofluid sets in easily as the ratio of Soret coefficient of nanofluid to that of binary basefluid δ₄ increases for δ₄ > ?1. It is also found that with an increase of the volume fraction of nanoparticles, the nanofluid becomes stable, but at or near ψ _bf = ? 0.3 the state of nanofluid changes from stable to unstable. The results from the addition factor analysis show that an asymptotic point of ψ _bf where the maximum value of g diverges infinitely exists in the range of ? 1.2 < ψ _bf < ? 1.1 with given conditions. The binary addition factor g is always higher than the normal addition factor f, which means that the heat transfer enhancement by the Soret effect in binary nanofluids is more significant than that in normal nanofluids.     

Quantile Autoregression for Censored Data

Quantile autoregression (QAR) is particularly attractive for censored data. However, unlike the standard regression models, the autoregressive models must take account of censoring on both response and regressors. In this article, we show that the existing censored quantile regression methods produce consistent estimators for QAR models when using only the fully observed regressors. A new algorithm is proposed to provide a censored QAR estimator by adopting imputation methods. The algorithm redistributes probability mass of censored points appropriately and iterates towards self‐consistent solutions. Monte Carlo simulations and empirical applications are conducted to demonstrate merits of the proposed method.