全文获取类型
收费全文 | 757篇 |
免费 | 47篇 |
专业分类
电工技术 | 46篇 |
化学工业 | 200篇 |
金属工艺 | 9篇 |
机械仪表 | 8篇 |
建筑科学 | 31篇 |
能源动力 | 36篇 |
轻工业 | 58篇 |
水利工程 | 11篇 |
无线电 | 47篇 |
一般工业技术 | 166篇 |
冶金工业 | 57篇 |
原子能技术 | 2篇 |
自动化技术 | 133篇 |
出版年
2023年 | 15篇 |
2022年 | 25篇 |
2021年 | 32篇 |
2020年 | 18篇 |
2019年 | 36篇 |
2018年 | 26篇 |
2017年 | 17篇 |
2016年 | 26篇 |
2015年 | 43篇 |
2014年 | 32篇 |
2013年 | 50篇 |
2012年 | 42篇 |
2011年 | 60篇 |
2010年 | 17篇 |
2009年 | 24篇 |
2008年 | 22篇 |
2007年 | 29篇 |
2006年 | 27篇 |
2005年 | 24篇 |
2004年 | 18篇 |
2003年 | 19篇 |
2002年 | 13篇 |
2001年 | 10篇 |
2000年 | 12篇 |
1999年 | 5篇 |
1998年 | 27篇 |
1997年 | 19篇 |
1996年 | 8篇 |
1995年 | 7篇 |
1994年 | 15篇 |
1993年 | 7篇 |
1992年 | 2篇 |
1991年 | 6篇 |
1990年 | 6篇 |
1989年 | 6篇 |
1987年 | 4篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1980年 | 2篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1936年 | 2篇 |
1933年 | 6篇 |
1932年 | 5篇 |
1931年 | 11篇 |
1930年 | 3篇 |
1920年 | 1篇 |
1919年 | 2篇 |
1910年 | 2篇 |
排序方式: 共有804条查询结果,搜索用时 10 毫秒
51.
Several new eco-friendly materials have the potential to replace conventional petroleum-derived materials and monomers. Among them are natural polysaccharides. The use of polysaccharides in polyurethane (PU) synthesis has not yet been studied extensively, even though as multihydroxyl compounds, they can easily serve as crosslinkers in PU synthesis. One naturally occurring (hyper-)branched polymer is amylopectin, a component of starch. In this work, we report the PU synthesis and film-forming capacity using the asymmetric cyclic aliphatic diisocyanate—isophorone diisocyanate (IPDI) with acetylated and pristine partially hydrolyzed amylopectin/white dextrin (AVEDEX W80) as a crosslinker. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47454. 相似文献
52.
Dr. Wojciech Schönemann Dr. Jonathan Cramer Tobias Mühlethaler Dr. Brigitte Fiege Marleen Silbermann Dr. Said Rabbani Dr. Philipp Dätwyler Dr. Pascal Zihlmann Dr. Roman P. Jakob Dr. Christoph P. Sager Dr. Martin Smieško Dr. Oliver Schwardt Prof. Dr. Timm Maier Prof. Dr. Beat Ernst 《ChemMedChem》2019,14(7):749-757
Antimicrobial resistance has become a serious concern for the treatment of urinary tract infections. In this context, an anti-adhesive approach targeting FimH, a bacterial lectin enabling the attachment of E. coli to host cells, has attracted considerable interest. FimH can adopt a low/medium-affinity state in the absence and a high-affinity state in the presence of shear forces. Until recently, mostly the high-affinity state has been investigated, despite the fact that a therapeutic antagonist should bind predominantly to the low-affinity state. In this communication, we demonstrate that fluorination of biphenyl α-d -mannosides leads to compounds with perfect π–π stacking interactions with the tyrosine gate of FimH, yielding low nanomolar to sub-nanomolar KD values for the low- and high-affinity states, respectively. The face-to-face alignment of the perfluorinated biphenyl group of FimH ligands and Tyr48 was confirmed by crystal structures as well as 1H,15N-HSQC NMR analysis. Finally, fluorination improves pharmacokinetic parameters predictive for oral availability. 相似文献
53.
54.
The solubility of commercially available natural gas in commercially available diesel fuel at room temperature and defined pressure is investigated experimentally. The gas phase is considered to be pure methane. The use of Henry's law to model the solubility is discussed. Solubility is given in terms of the mole fraction and the volumetric mass concentration of dissolved gas and the corresponding Henry's coefficients. The solubility is compared to that of pure methane in pure hexadecane, which is similar to diesel fuel with respect to the mean carbon number. 相似文献
55.
Schröder Jakob Evans Alexander Polatidis Efthymios Čapek Jan Mohr Gunther Serrano-Munoz Itziar Bruno Giovanni 《Journal of Materials Science》2022,57(31):15036-15058
Journal of Materials Science - The manufacturability of metallic alloys using laser-based additive manufacturing methods such as laser powder bed fusion has substantially improved within the last... 相似文献
56.
Ralph F. Jr. Krause Sheldon M. Wiederhorn Jakob J. Kübler 《Journal of the American Ceramic Society》2001,84(1):145-152
In this paper, we have examined the possibility that elastic bending induced by load misalignment can affect creep measurements on pin-loaded tension specimens of silicon nitride (Si3N4). We have shown that elastic bending at room temperature can be as great as 42% of the axial strain when clean pins were used but was reduced to ∼3% when lubricated pins were used. Creep tests at the same applied stress and temperature were conducted on two groups of Si3N4 test specimens: one group used clean pins, and the other group used lubricated pins. By measuring the shapes of the specimens before and after the creep tests, we have determined that the loading holes were slightly misaligned before the creep tests and that small amounts of bending were induced by the creep tests. Bending occurred both in the gauge section of the specimen and in the transition region between the gauge section and the heads of the specimen (the latter phenomenon is defined as hinge bending). Our study indicated that the secondary creep rate, the hinge bending, and the bending of the gauge section was not dependent on pin lubrication, because the results from the clean and lubricated groups were statistically indistinguishable. Hinge bending was dependent on initial misalignment of the loading holes, whereas bending of the gauge section was independent of such factors. 相似文献
57.
Efficient removal of phthalate esters (PE) in wastewater treatment plants (WWTP) is becoming an increasing priority in many countries. In this study, we examined the fate of dimethyl phthalate (DMP), dibutyl phthalate (DBP), butylbenzyl phthalate (BBP), and di-(2-ethylhexyl) phthalate (DEHP) in a full scale activated sludge WWTP with biological removal of nitrogen and phosphorus. The mean concentrations of DMP, DBP, BBP, and DEHP at the WWTP inlet were 1.9, 20.5, 37.9, and 71.9 μg/L, respectively. Less than 0.1%, 42%, 35%, and 96% of DMP, DBP, BBP, and DEHP was associated with suspended solids, respectively. The overall microbial degradation of DMP, DBP, BBP, and DEHP in the WWTP was estimated to be 93%, 91%, 90%, and 81%, respectively. Seven to nine percent of the incoming PE were recovered in the WWTP effluent. Factors affecting microbial degradation of DEHP in activated sludge were studied using [U-14C-ring] DEHP as tracer. First order rate coefficients for aerobic DEHP degradation were 1.0×10−2, 1.4×10−2, and 1.3×10−3 at 20, 32, and 43 °C, respectively. Aerobic degradation rates decreased dramatically under aerobic thermophilic conditions (<0.1×10−2 h−1 at 60 °C). The degradation rate under anoxic denitrifying conditions was 0.3×10−2 h−1, whereas the rate under alternating conditions (aerobic-anoxic) was 0.8×10−2 h−1. Aerobic DEHP degradation in activated sludge samples was stimulated 5-9 times by addition of a phthalate degrading bacterium. The phthalate degrading bacterium was isolated from activated sludge, and maintained a capacity for DEHP degradation while growing on vegetable oil. Collectively, the results of the study identified several controls of microbial PE degradation in activated sludge. These controls may be considered to enhance PE degradation in activated sludge WWTP with biological removal of nitrogen and phosphorus. 相似文献
58.
Jakob Ruess Andreas Milias-Argeitis John Lygeros 《Journal of the Royal Society Interface》2013,10(88)
Exploiting the information provided by the molecular noise of a biological process has proved to be valuable in extracting knowledge about the underlying kinetic parameters and sources of variability from single-cell measurements. However, quantifying this additional information a priori, to decide whether a single-cell experiment might be beneficial, is currently only possible in systems where either the chemical master equation is computationally tractable or a Gaussian approximation is appropriate. Here, we provide formulae for computing the information provided by measured means and variances from the first four moments and the parameter derivatives of the first two moments of the underlying process. For stochastic kinetic models for which these moments can be either computed exactly or approximated efficiently, the derived formulae can be used to approximate the information provided by single-cell distribution experiments. Based on this result, we propose an optimal experimental design framework which we employ to compare the utility of dual-reporter and perturbation experiments for quantifying the different noise sources in a simple model of gene expression. Subsequently, we compare the information content of a set of experiments which have been performed in an engineered light-switch gene expression system in yeast and show that well-chosen gene induction patterns may allow one to identify features of the system which remain hidden in unplanned experiments. 相似文献
59.
Jesper Mller Jakob Lichtenberg Henrik R. Andersen Henrik Hulgaard 《Electronic Notes in Theoretical Computer Science》2001,23(2)
Current approaches for analyzing timed systems are based on an explicit enumeration of the discrete states and thus these techniques are only capable of analyzing systems with a handful of timers and a few thousand states. We address this limitation by describing how to analyze a timed system fully symbolically, i.e., by representing sets of discrete states and their associated timing information implicitly. We demonstrate the efficiency of the symbolic technique by computing the set of reachable states for a non-trivial timed system and compare the results with the state-of-the-art tools Kronos and Uppaal. With an implementation based on difference decision diagrams, the runtimes are several orders of magnitudes better. The key operation in obtaining these results is the ability to advance time symbolically. We show how to do this efficiently by essentially quantifying out a special variable z which is used to represent the constant zero. The symbolic manipulations given in this paper are sufficient to verify TCTL-formulae fully symbolically. 相似文献
60.
Nina Orlovskaya Sergey Yarmolenko Jag Sankar Jakob Kuebler Mykola Lugovy 《Journal of Materials Science》2008,43(17):5942-5947
A study of hot pressed B4C-based laminates, after rolling and without rolling, has been performed to elucidate the existence of fracture resistance/crack
length anisotropy induced by this processing technique. While the crack lengths/fracture resistance was affected significantly
by the presence of the residual stresses in B4C/B4C–ZrB2 laminates, no differences in Vickers crack lengths were observed in B4C/B4C laminates prepared by rolling and hot pressing, as compared to the crack lengths seen in pure B4C ceramics prepared by hot pressing without rolling. X-ray diffraction analysis confirmed that no texture has been formed
during the rolling and hot pressing of B4C ceramics. 相似文献