Viscosity and Thermal Expansion of Mixed-Alkali Borate Glasses

Transformation-range viscosity and thermal expansion measurements were made for five series (Li-Na, Li-K, Li-Cs, Na-Cs, and K-Rb) of mixed-alkali borate glasses containing 30 mol% total alkali oxide. In each case, negative deviations from additivity were observed in the isokom and glass transformation temperatures. Positive deviations from additivity were observed in the thermal expansion coefficients for the Li-Na, Li-K, and K-Rb glasses, while the Li-Cs and Na-Cs glasses exhibited negative deviations. Maximization of the deviation from additivity in the viscosity and glass transformation temperatures occurred when the radius ratio of the two alkali ions was approximately 1.7 to 1.8. Combination of the results of this study with those of earlier studies indicates that the deviations from additivity observed for these properties are independent of the identity of the glass former.     

Flow patterns in granulating systems

Particle flow patterns were investigated for wet granulation and dry powder mixing in ploughshare mixers using Positron Emission Particle Tracking (PEPT). In a 4-l mixer, calcium carbonate with mean size 45 μm was granulated using a 50 wt.% solution of glycerol and water as binding fluid, and particle movement was followed using a 600-μm calcium hydroxy-phosphate tracer particle. In a 20-l mixer, dry powder flow was studied using a 600-μm resin bead tracer particle to simulate the bulk polypropylene powder with mean size 600 μm. Important differences were seen between particle flow patterns for wet and dry systems. Particle speed relative to blade speed was lower in the wet system than in the dry system, with the ratios of average particle speed to blade tip speed for all experiments in the range 0.01–0.25. In the axial plane, the same particle motion was observed around each blade; this provides a significant advance for modelling flow in ploughshare mixers. For the future, a detailed understanding of the local velocity, acceleration and density variations around a plough blade will reveal the effects of flow patterns in granulating systems on the resultant distribution of granular product attributes such as size, density and strength.     

Morphological, mechanical and gas-transport characteristics of crosslinked poly(propylene glycol): homopolymers, nanocomposites and blends

Linear polyethers possess unusually high CO₂ solubility and, hence, selectivity due to the presence of accessible ether linkages that can interact with the quadrupolar moment of CO₂ molecules. In this work, membranes derived from crosslinked poly(propylene glycol) diacrylate (PPGda) oligomers differing in molecular weight (M), as well as PPGda nanocomposites containing either an organically-modified montmorillonite clay or a methacrylate-terminated fumed silica are investigated and compared with highly CO₂-selective poly(ethylene glycol) diacrylate (PEGda) homopolymer and nanocomposite membranes previously reported. The rheological and permeation properties of PPGda depend sensitively on M, with the elastic modulus decreasing, but CO₂ permeability and CO₂/H₂ selectivity increasing, with increasing M. Incorporation of either nanofiller into PPGda enhances the elastic modulus and reduces the gas permeability in the resultant nanocomposites without strongly affecting CO₂/H₂ selectivity. Blending PPGda and PEGda prior to chemical crosslinking yields binary membranes that exhibit intermediate gas-transport properties accurately described by a linear rule of mixtures.     

Foam fractionation of spent sulphite liquor: Part I: Separation of surfactants

The surface activity of spent sulphite liquor (SSL) and the separation of surface active components by foam fractionation were studied. The maximum activity (lowest surface tension) of SSL was observed at a high pH. The surface tension was found to be 42 mN/m and 38 mN/m at acidic and basic pH values, respectively, and also a maximum foaminess (Σ) of 7 min was observed at pH 10. Foam fractionation reduced the surfactant concentration by 90% at an optimum pH of 10. The surfactants were concentrated in the collapsed foam as shown by the fact that the critical micelle concentrations of the unfractionated SSL and foam were 70% (v/v) and 10% (v/v), respectively. The removed surfactants were concentrated in 20% of the original liquid volume.     

Comparison of relative viscosity measurement of polyvinylpyrrolidone in water by glass capillary viscometer and differential dual‐capillary viscometer

The relative viscosity (RV) of polyvinylpyrrolidone (PVP) with different molecular weights was measured with a glass capillary viscometer and with a differential dual‐capillary viscometer in water at different concentrations. For the differential dual‐capillary viscometer, RV increases with a decreasing flow rate, especially for high molecular weight PVP at a 1% concentration. A good agreement in the RV between the two methods can be obtained for PVP with different molecular weights and at various concentrations if an appropriate flow rate is selected for the differential dual‐capillary viscometer. Special precaution is needed when using the differential dual‐capillary viscometer to measure the viscosity of a pure solvent. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1312–1315, 2002     

Mechanical properties of biorenewable fiber/plastic composites

Plastic fiber composites, consisting of polypropylene (PP) or polyethylene (PE), and pinewood, big blue stem (BBS), soybean hulls, or distillers dried grain and solubles (DDGS), were prepared by extrusion. Young's modulus, tensile and flexural strengths, melt flow, shrinkage, and impact energy, with respect to the type, amount, and size of fiber on composites, were evaluated. Young's moduli under tensile load of wood, BBS, and soybean‐hull fiber composites, compared with those of pure plastic controls, were either comparable or higher. Tensile strength significantly decreased for all the PP/fiber composites when compared with that of the control. Strength of BBS fiber composites was higher than or comparable to that of wood. When natural fibers were added there was a significant decrease in the melt flow index for both plastic/fiber composites. There was no significant difference in the shrinkage of all fiber/plastic composites compared to that of controls. BBS/PE plastic composites resulted in higher notched impact strength than that of wood or soybean‐hull fiber composites. There was significant reduction in the unnotched impact strength compared to that of controls. BBS has the potential to be used as reinforcing materials for low‐cost composites. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 2484–2493, 2004     

A simplified method for analyzing mold filling dynamics. Part II: Extensions and comparisons with experiment

A dimensional analysis based on four parameters has been developed previously to predict injection pressure; clamp force, and bulk temperature for the injection molding of amorphous materials in center-gated disk-shaped cavities. In this paper geometric and semicrystalline-materials approximations are introduced and tested for extending the previous analysis to include multigated thin cavities and semicrystalline materials. The combination of these approximations and the previous analysis, known hereafter as the Radial Flow Method (RFM), greatly simplifies the analysis of mold filling. The geometric approximation, which is based on a simple model for the axial stress distribution in the cavity, is shown to give reasonable predictions when compared with experimental data and a numerical two-directional flow simulation for the filling of an off-center-gated rectangular cavity with acrylonitrilebutadiene-styrene copolymer (ABS). The semicrystallinematerials approximation, in which heat capacity and viscosity changes during crystallization are neglected, is shown to give good agreement with experimental data for the filling of a center-gated disk-shaped cavity with polypropylene. As an illustration, the Radial Flow Method is used to analyze the molding of a large, thin-wall automobile interior trim panel. The inlet melt temperature, mold-wall temperature, part thickness, injection rate, viscosity and gate locations are varied in a series of calculations to determine the relative effectiveness of these variables in lowering the injection pressure and Clamp force. The results obtained with the Radial Flow Method are in good agreement with those obtained by a finiteelement simulation of two-directional flow.     

Apparatus and procedure for measuring release rates from formulations of lepidopteran semiochemicals

An apparatus was developed wherein a vacuum source was used to pull air across a controlled-release-formulation dispenser or a planchet containing a known quantity of a semiochemical and into a collector filled with a polymeric adsorbent. After a set time, the semiochemical was eluted with solvent and was quantified by gas-liquid chromatography (GLC). High percentages of known quantities of the lepidopteran semiochemicals (Z)-7-dodecen-l -ol acetate (Z7DDA), boiling point (bp) 275 ° C/1 atm, (Z)-9-tetradecen-1-ol formate (Z9TDF), bp 289 °C/1 atm, and (Z,Z)-3,13-octadecadien-1-ol acetate (ZZODDA), bp 490 °C/1 atm, were recovered. The semiochemicals did not oxidize and were recovered quantitatively from the adsorbent. The release rates of Z9TDF from a controlled-release dispenser were found to be directly proportional to the airflow rates. Release rate measurements on the Z9TDF dispensers were made for the purpose of estimating the method's precision. The method was shown to give internally consistent results by measurements on another Z9TDF formulation. The accuracy of the method is discussed.Mention of a commercial or proprietary product in this paper does not constitute an endorsement by the USDA.     

Low‐velocity impact of nanocomposite and polymer plates

Nanocomposites are more widely studied today because of higher stiffness, decreased permeability, thermal stability, and many other properties superior to those of regular polymers. However, manufacturers are concerned about implementing nanocomposites because of their lower impact properties with respect to the base polymer. This study focused on low‐velocity impact tests of a thermoplastic olefin by itself and with 5 wt % nanoclay. The impact tests were conducted at ?40, 23.9, and 65.6°C until the polymer and nanocomposite plates experienced complete striker penetration. The force–time and force–deflection responses obtained from the impact testing provided a means of comparing the impact performances of the two materials. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 2309–2315, 2005     

Empirical evaluation of H.264/SVC streaming in resource-constrained multihomed mobile networks

Nomadic users of streamed multimedia content in mobile networks are often faced with resource-constrained network paths that suffer from low bandwidth. Streaming high-quality video in such a challenging scenario demands a set of highly adaptive schemes, which have not been sufficiently explored in particular for the emerging H.264 Scalable Video Coding (H.264/SVC) standard. In this paper, we empirically investigate the performance of streaming H.264/SVC scalable video streams to users in multihomed mobile networks containing multiple available transmission paths. Previous work has demonstrated the feasibility of aggregating bandwidth of multiple paths to deliver video streams when no single, sufficiently high bandwidth path is available. We focus on evaluating the enhanced performance of multipath bandwidth-aggregation streaming by exploiting a quality-layers based, H.264/SVC-specific packet prioritisation scheme for quality-aware multipath packet scheduling and selective packet dropping in case of bandwidth shortage even after aggregation. Additionally, we explore a base-layer rate control scheme for H.264/SVC delivery in ultra-low bandwidth environments. Through extensive experimentation on a realistic hardware-based testbed, we obtain a comprehensive and insightful understanding of the behaviour of H.264/SVC streams when transmitted across multiple paths in mobile networks. We quantify the improvements offered by the use of H.264/SVC-specific packet prioritisation schemes compared with an existing generic scalable video prioritisation scheme, and the benefits by the use of base-layer rate control in ultra-low bandwidth situations. The performance of the multipath streaming schemes is further compared with that of an ideal single high bandwidth path. We also identify the remaining challenges that must be overcome if such streaming schemes are to offer performance close to that of the ideal single high bandwidth path.