Mechanical properties of rigid thermoplastic foams—Part II: Stiffness and strength data for modified polyphenylene oxide foams

The through-thickness variation in the porosity of structural foam material is known to result in different “material properties” when mechanics based on homogeneous materials is used to interpret data from standard tensile and bend tests. Procedures for determining the mechanical properties of rigid thermoplastic structural foams and for the application of these properties to the design of load-bearing components were developed in a companion paper. This paper reports the mechanical properties of modified polyphenylene oxide foams, such as elastic moduli, ultimate stress and strain, as determined by tests on specimens cut from large, edge-gated foam plates. Tests were conducted to study plate-to-plate variations in properties and to evaluate the effect of specimen thickness. Correlations of tensile and flexural data with the average specimen density are also discussed.     

Copper Sulfide (CuxS) Nanowire‐in‐Carbon Composites Formed from Direct Sulfurization of the Metal‐Organic Framework HKUST‐1 and Their Use as Li‐Ion Battery Cathodes

Li‐ion batteries containing cost‐effective, environmentally benign cathode materials with high specific capacities are in critical demand to deliver the energy density requirements of electric vehicles and next‐generation electronic devices. Here, the phase‐controlled synthesis of copper sulfide (Cu_xS) composites by the temperature‐controlled sulfurization of a prototypal Cu metal‐organic framework (MOF), HKUST‐1 is reported. The tunable formation of different Cu_xS phases within a carbon network represents a simple method for the production of effective composite cathode materials for Li‐ion batteries. A direct link between the sulfurization temperature of the MOF and the resultant Cu_xS phase formed with more Cu‐rich phases favored at higher temperatures is further shown. The Cu_xS/C samples are characterized through X‐ray diffraction (XRD), thermogravimetric analysis (TGA), transmission electron microscopy, and energy dispersive X‐ray spectroscopy (EDX) in addition to testing as Li‐ion cathodes. It is shown that the performance is dependent on both the Cu_xS phase and the crystal morphology with the Cu_1.8S/C‐500 material as a nanowire composite exhibiting the best performance, showing a specific capacity of 220 mAh g^?1 after 200 charge/discharge cycles.     

DYNAMICS OF SEDIMENT-ASSOCIATED METALS IN A HIGHLY URBANISED CATCHMENT: BRADFORD, WEST YORKSHIRE

Urban watercourses are potential hazards because of their rapid flow changes, poor water quality and contaminated sediments. This study is a preliminary field investigation into fine sediment-associated metal contamination and its transport dynamics in a highly urbanised catchment in West Yorkshire, UK. Spatial and temporal changes in the concentration of channel-bed sediment-associated metals are investigated, and the fluxes of selected suspended sediment-associated metals, during an extreme high flow event, are determined. Channel-bed sediments were more contaminated at the most heavily urbanised sites. Data suggest that contaminated bed sediments could accumulate and possibly become increasingly contaminated between high-flow events, prior to being flushed from the system. Fluxes of contaminated suspended sediments were very high at the peak of the high flow event. The spatial and temporal dynamics of contaminated fine sediment which were identified in this study could inform planners with regard to future monitoring strategies.     

A phenomenological study of the mechanical properties of long‐fiber filled injection‐molded thermoplastic composites

Tensile and flexural tests on specimens cut from rectangular injection‐molded plaques show that long‐fiber filled thermoplastic composites are complex, non‐homogeneous, anistropic material systems. Like all fiber‐filled materials, they exhibit through‐thickness nonhomogeneity as indicated by differences between tensile and flexural properties. The in‐plane orientation of fibers in through‐thickness layers causes the material to have in‐plane anisotropic properties. However, these long‐fiber filled materials exhibit an unexpectedly large level of in‐plane nonhomogeneity. Also, the effective mechanical properties of these materials are strongly thickness dependent. The thinnest plaques exhibit the largest differences between the flow and cross‐flow tensile properties. These differences decrease with increasing thickness. A methodology for part design with this class of materials is discussed.     

Syntheses of Ag, PbSe, and PbTe nanocrystals and their binary self-assembly exploration at low size-ratio

Nanocrystals of Ag, PbSe, and PbTe were prepared via a high-temperature organic solution approach, respectively. Using a size-selection technique, the size-distribution of each set of nanocrystals could be fine-tuned and finally monodisperse products were achieved. Superlattice structure of binary self-assemblies in low size-ratio were also explored and characterized by transmission electron microscopy. It is realized that a success of achieving binary self-assembly pattern is greatly dependent on several key factors including particle size-distributions, relative concentrations of both components, as well as the size-ratios between Ag and PbSe (or PbTe) nanocrystals.     

Lean-Thinking: Implementation and Measurement in Healthcare Settings

Abstract

Despite positive reports about lean approaches to spearhead quality and patient safety improvement efforts, it is still difficult to determine if healthcare employees have transformed into effective lean thinkers. Lean thinking refers to individuals who operate with thoughtful reflection on organizational issues, are committed to continuous improvement efforts, and demonstrate the willingness to lead change. The objective of this theory building research is to contribute a survey instrument and conceptual model to measure individual transformation to lean thinking. Our learnings from the case study suggest that healthcare a professional’s transition to lean thinking via a complex combination of awareness issues at both the unit and individual levels, and both levels should be considered when moving individuals toward readiness and through a personal transformation to lean thinking.     

Effect of NiTe Nanoinclusions on Thermoelectric Properties of Bi2Te3

Metal nanoinclusions in bulk thermoelectric matrix create metal?Csemiconductor interfaces, which can result in improvement in the thermoelectric power factor due to low-energy electron filtering and a simultaneous reduction in lattice thermal conductivity due to increased phonon scattering at grain boundaries. The combined effect results in enhancement of the thermoelectric figure of merit. We report the effect of NiTe nanoinclusions in a Bi₂Te₃ matrix. The Bi₂Te₃/NiTe nanocomposite was synthesized by planetary ball milling. Different volume fractions of NiTe nanoinclusions were incorporated into the bulk (Bi₂Te₃) matrix and uniaxially hot pressed at 100?MPa and 500°C. The presence of nanoinclusions was confirmed by x-ray diffraction and transmission electron microscopy. The Seebeck coefficient, electrical conductivity, and thermal diffusivity were measured from room temperature to 150°C. The carrier concentration of the matrix (Bi₂Te₃) and the nanocomposites (NiTe/Bi₂Te₃) at room temperature were deduced from Hall-effect measurements. Addition of NiTe decreased the carrier concentration, and the power factor increased in the 1?vol.% NiTe/Bi₂Te₃ compared with inclusion-free Bi₂Te₃ matrix due to an increase in mobility.     

Identifying efficient dairy producers using data envelopment analysis

The objective of this research was to calculate the efficiency of a group of Pennsylvania dairy farms to determine factors that contributed to efficiency in production and business management. Data envelopment analysis (DEA) was used to estimate the efficiency. Two models were developed to measure the efficient use of physical (land, cows, and labor) inputs to produce physical (milk and butterfat) outputs, and the use of physical and economic (debt capital) inputs to produce physical and economic (income) outputs. The results showed that about 29% of the producers in our sample were DEA-efficient and demonstrated that there was no combination of inputs used by efficient producers that was best. In addition, the method of analysis illustrated the benefits of DEA in that it is possible to identify the set of efficient producers that inefficient producers can benchmark to in an effort to achieve similar levels of efficiency. Finally, the analysis demonstrated that producers should not benchmark to the highest level of production, but rather should combine resources in land, labor, cows, and debt capital to achieve an efficient level of production, which indeed may be less than the maximum production level of the group.     

Ruminal digestion and microbial utilization of diets varying in type of carbohydrate and protein.

Three ruminally and duodenally cannulated, lactating Holstein cows were used in a 3 x 3 Latin square experiment to study the effects of differing levels of nonstructural carbohydrate and degradable intake protein on ruminal digestibility and microbial protein production. Three diets were formulated to contain 1) 38 and 13.2%, 2) 31 and 11.8%, and 3) 24 and 9% nonstructural carbohydrate and degradable intake protein as percentages of the DM, respectively. Dry matter intakes were similar for all diets (21.9, 21.1, and 18.3 kg/d for diets 1, 2, and 3, respectively). Likewise, microbial efficiency, as estimated from purine analysis, was unaffected by diet and averaged 24 g of microbial N/kg of OM digested for all treatments. Ruminal digestion of OM averaged 66.6, 65.1, and 55.7% for diets 1, 2, and 3, respectively, resulting in lower microbial N flow per day for diet 3 (317, 333, and 202 g, respectively). Digestion of nonstructural carbohydrate and CP followed similar trends as did OM digestion, whereas NDF digestion remained similar across all diets. These results indicate that nonstructural carbohydrate greater than 24% and ruminally degradable protein greater than 9% of DM will enhance microbial protein flow from the rumen.     

Producer breeding objectives and optimal sire selection

Information from an online survey of dairy producers was used to determine how important producers perceived three different objectives in the breeding problem. The objectives were: maximizing expected net merit of the progeny, minimizing the expected progeny inbreeding coefficient, and minimizing semen expenditure. Producers were asked to rank the three objectives and then to weight the importance of each objective relative to the others. This information was then used to determine weights to be used in a multiple-objective integer program designed to select individual mates for a herd of 76 Jersey cows with known genetic background and cow net merit. The results of the multiple-objective models show that rank and relative importance of producer objectives can affect the portfolio of sires selected. Producers whose primary objective was to maximize expected net merit had a range of average expected progeny net merit of $306 to $310, but the level of expected progeny inbreeding was from 6.99 to 10.45%, with a semen cost per conception of $35 to $41. For producers who selected minimizing progeny inbreeding as the primary goal in their breeding programs, the range of inbreeding was from 6.11 to 6.60%, with lower net merit range of $274 to $301 and semen expenditure of $30 to $37 per conception. One producer selected minimizing semen cost as the primary objective. For that producer's portfolio, the semen cost was $27 per conception and net merit was $288, with a progeny inbreeding coefficient of 10.68%. The results of this research suggest that producer information and goals have a substantial impact on the portfolio of sires selected by that producer to attain these goals.