Enterprise architecture is a model-based IT and business management discipline. Enterprise architecture analysis concerns using enterprise architecture models for analysis of selected properties to provide decision support. This paper presents a framework based on the ArchiMate metamodel for the assessment of four properties, viz., application usage, system availability, service response time and data accuracy. The framework integrates four existing metamodels into one and implements these in a tool for enterprise architecture analysis. The paper presents the overall metamodel and four viewpoints, one for each property. The underlying theory and formalization of the four viewpoints is presented. In addition to the tool implementation, a running example as well as guidelines for usage makes the viewpoints easily applicable. 相似文献
Summary In the presence of ZnCl2 phenyl glycidyl ether reacts to different products owing to the ring-opening reaction of the oxirane and the cleavage of the ether bond. Using HPLC and offline mass spectrometry most of the reaction products could be identified.A reaction scheme and the supposed reaction mechanism were described involving the formation of chlorine — containing oligomers and low molecular weight by — products resulting from the cleavage of the ether bond of the monomer. Conclusions were drawn for original polyfunctional epoxy resin systems. 相似文献
Micro-mesoporous aluminosilicates based on ZSM-5 zeolite, obtained by a dual template method, as well as in the presence of a dual-functional template (i.e. a Gemini-type surfactant), were tested in the oxidation of furfural with hydrogen peroxide. Even substantial changes in acidity and porosity of the catalysts result in minor variations of selectivity towards the desired products. Application of the synthesized zeolite-based materials in the oxidation of furfural with hydrogen peroxide leads to formation of 2(5H)-furanone (yield up to 28.5%) and succinic acid (up to 19.5%) as the main C4 reaction products. The kinetic model developed previously to treat the results for oxidation of furfural over sulfated zirconia was able to describe the data also for micro-mesoporous aluminosilicates.
Triacylglycerols of the seed oils rich in α- and/or γ-linolenic acid moieties were separated by silver-ion high-performance
liquid chromatography (HPLC) followed by on-line atmospheric pressure chemical ionization-mass spectrometric (APCI-MS) detection.
Mass spectra of most triacylglycerols exhibited abundant [M + H]+ and [M − RCO2]+ ions, which defined the molecular weight and the molecular association of fatty acyl residues of a triacylglycerol, respectively.
Silver ions formed weaker complexes with triacylglycerols containing γ-linolenic acid than with those containing α-linolenic
acid, i.e., the elution order of molecules wasXYTγ>XYTα’,XTγTα>XTαTα>, andTγTγTγ>TγTγTα>TγTαTα>TαTαTα, whereTα=α-linolenic acid,Tγ=γ-linolenic acid, andX, Y=fatty acids different from linolenic acid. Furthermore, silver-ion HPLC resulted in partial separation within equally unsaturated
triacylglycerols according to differences in the combined number of acyl carbons. Regioisomeric forms of triacylglycerols
were not determined from the seed oil samples, although differences were measured with reference compounds in the relative
abundances of [M − RCO2]+ ions formed by a loss of a fatty acyl residue from thesn-2 position and thesn-1/3 positions. Silverion HPLC/APCI-MS provided valuable information for structure elucidation of seed oil triacylglycerols:
43 molecular species were identified from cloudberry seed oil, 39 from evening primrose oil, 79 from borage oil, 44 from alpine
currant, and 56 from black currant seed oils. The quantitation requires to be studied further, especially in those cases where
several molecular weight species of triacylglycerols eluted in a single chromatographic peak. 相似文献
A new interdisciplinary approach is discribed to identifying unknown parameters using an extended version of the known interval bisection method. This developed method is based on the use of finite elements for calibrating the simulation calculation. The resulting thermo-elastic deformations which occur in drilling processes with impaired cooling lubrication are to be used as correction values for tool positioning in the NC control. Based on the strong impact on workpiece temperature of machining, a simulation approach is presented for calculating the temperature fields and their thermo-elastic consequences. In addition, methods are presented to correct these effects. This paper particularly deals with the temperature fields of drilling operations. Special attention is paid to the technique employed for iterative numerical determination of the unknown heat flux ηw and heat transfer coefficient \(\bar {\gamma }\) values. Finally, the data obtained from experiments are compared with those achieved by numerical simulation in order to verify the efficiency of simulation and determination of parameters. 相似文献
The hydroisomerization of two long-chain n-alkane mixtures was investigated over bifunctional Pt/H-ZSM-5 catalysts before and after dealumination of preshaped zeolite/binder pellets. The hydroisomerization over the dealuminated catalysts leads to more isomers and less cracking products. Consequently, higher ratios of multi- to mono-branched isomerization products are formed as expected for large- rather than medium-pore zeolites. This indicates a higher availability of space in the vicinity of the active sites and provides an attractive route to make medium-pore zeolites suitable for upgrading higher boiling hydrocarbon feeds. 相似文献
Journal of Chemical Ecology - There is increasing evidence that microorganisms, particularly fungi and bacteria, emit volatile compounds that mediate the foraging behaviour of insects and therefore... 相似文献
The oxidation of an auriferous pyrite ore sample was evaluated in biological leaching experiments for subsequent gold recovery via cyanidation. In batch cultures, organisms derived from the mine site oxidized pyrite and ferrous iron at pH values as low as pH 0.6. The recovery of gold was variable in shake flask experiments. In stirred tank bioreactor leaching, gold recovery was proportional to the extent of iron dissolution by bioleaching. The leaching of arsenic from the sample was also directly proportional to iron dissolution. 相似文献
The flame spraying process, which is a common industrial thermal spraying application, has been analyzed by means of three-dimensional
computational fluid dynamics (CFD) simulations. The process used at the Volvo Aero Corporation for the coating of fan and
compressor housings has been modeled. The process uses the Metco 6P torch (Metco, Westbury, NY), which ejects a mixture of
acetylene and oxygen at high speed through a ring of 16 orifices to form the flame. A stream of argon gas flowing through
an orifice in the center of the ring carries a powder of nickel-covered bentonite through the flame to the spray substrate.
The torch is cooled by a flow of air through an outer ring of 9 orifices. The simulation emulated reality closely by including
the individual inlets for fuel, cooling air, and injected particles. The gas combustion was simulated as a turbulent, multicomponent
chemically reacting flow. The standard, two-equation k-ε turbulence model was used. The chemical reaction rates appeared as
source terms in the species transport equations. They were computed from the contributions of the Arrhenius rate expressions
and the Magnussen and Hjertager eddy dissipation model. The first simulations included several intermediate chemical substances
whose predicted concentration agreed favorably with measurements. Later, more simplified simulations incorporated only the
global chemical reaction involving the initial and the final products, with corrections to the thermal properties being made
to account for the missing intermediaries. The gas velocity and temperature fields predicted by the later simulations compared
satisfactorily to those predicted by the earlier, more elaborate, ones. Therefore, the final simulations, which incorporated
injected particles, were conducted employing the simplified model with only the global reaction. An in-house finite difference
code was developed to calculate particle properties. Allowance was made for elliptical shapes, phase changes, and internal
heat transfer with regard to the composite material. The particle velocities and temperatures predicted by the final simulations
compared fairly well with experimental results obtained with the optical DPV2000 system. 相似文献