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21.
Daniel X. Gouveia Odair P. Ferreira Antonio G. Souza Filho M. G. da Silva J. A. C. de Paiva Oswaldo L. Alves Josué Mendes Filho 《Journal of Materials Science》2007,42(2):534-538
The thermal decomposition properties of Mg–Fe hydrotalcites were studied through in situ 57Fe Mössbauer spectroscopy and in situ X-ray diffraction. Abrupt changes in the quadrupolar splitting measured in the Mössbauer spectra revealed a phase transition from the starting lamellar structure to a new crystalline arrangement. By analyzing the Mössbauer parameters we show that the material is highly disordered in the 300–400 °C temperature range. This hypothesis is confirmed by the X-ray results whose diffractograms indicated the collapse of the lamellar structure and the formation of a solid solution. 相似文献
22.
Modelling of effects of ultrastructural morphology on the hygroelastic properties of wood fibres 总被引:1,自引:0,他引:1
Wood fibres constitute the structural framework of e.g. wood, paper, board and composites, where stiffness and dimensional
stability are of importance. An analytical modelling approach has been used for prediction of hygroelastic response, and assessment
of the stresses in thick-walled cylinder models of wood fibres. A wood fibre was idealised as a multilayered hollow cylinder
made of orthotropic material with helical orientation. The hygroelastic response of the layered assembly due to axisymmetric
loading and moisture content changes was obtained by solving the corresponding boundary value problem of elasticity. A simple
solution scheme based on the state space approach and the transfer matrix method was employed. This was combined with an analytical
ultrastructural homogenisation method, used to link hygroelastic properties of constituent wood polymers to properties of
each layer. Predicted hygroelastic response captured experimentally measured behaviour. Fibres that were constrained not to
twist showed a stiffer response than fibres allowed twisting under uniaxial loading. It was also shown that the ultrastructure,
i.e. the microfibril angle, will control the hygroexpansion in the same way as it controls the compliance of the cell wall.
Qualitative failure trends comparable with experimental observations could be established with stress analysis and a simple
plane-stress failure criterion. 相似文献
23.
Dielectric and thermal characteristics of gel grown single crystals of ytterbium tartrate trihydrate
Dielectric and thermal characteristics of gel grown single crystals of ytterbium tartrate trihydrate have been carried out.
The dielectric constant has been measured as a function of frequency in the range 2 kHz–1 MHz and temperature range 30–300 °C.
The dielectric constant increases with temperature, attains a peak near 215 °C, and then decreases as the temperature exceeds
215 °C. The dielectric anomaly at 215 °C is suggested to be due to phase transition brought about in the material. The dielectric
behaviour of the material is correlated with the results on thermal analysis. Thermogravimetric and differential thermal analysis
have been used to study the thermal characteristics of the material. The experimental results show that the material is thermally
stable up to 200 °C. The decomposition process occurs in two stages until ytterbium oxide is formed at 700 °C. The non-isothermal
kinetic parameters e.g., activation energy and the frequency factor have been evaluated for each stage of thermal decomposition
by using the integral method, applying the Coats–Redfern approximation. 相似文献
24.
Christian P. Romero Jonathan I. Avila Edgardo Cisternas Guerau B. Cabrera Alejandro L. Cabrera Kristiaan Temst Margriet J. Van Bael 《Journal of Materials Science》2007,42(18):7667-7672
Hydrogen desorption curves were obtained from a sample composed of a square arrangement of Co dots with average diameter of
4.4 μm, separated by a distance of 11.6 μm. A macroscopic sample of Co dots grown on a 2.5 × 2.5 cm Si substrate was made
by standard lithographic techniques and used in these experiments. Thermal programmed desorption (TPD) was performed under
ultra-high vacuum conditions. Hydrogen TPD curves were obtained from a 1 × 1 cm Co dots samples displaying a maximum of intensity
at 425 K. Hydrogen TPD curve was also obtained from 1 cm× 1 cm samples of Co films and Co foils for comparison. The hydrogen
TPD curves have decreasing intensity from the Co foils to the Co dots and finally to the Co films. This indicates that there
are more sites for hydrogen adsorption on the Co dots than in the Co films. This is a surprising result because there is approximately
8.7 times less Co atoms exposed in the Co dots that in the Co film sample. A desorption energy of 27 kcal/mol was obtained
for the Co dots suggesting that hydrogen is adsorbed on an hcp hollow site of the Co dot crystalline structure. 相似文献
25.
The aim of the present paper is to review the recent progress in the synthesis of in situ particle reinforced aluminum composites
using thermal, mechanical and combined mechanical-thermal activation of aluminothermic reduction reactions. The combination
of combustion synthesis (CS) and mechanosynthesis (MS) is the most recent development in the processing of advanced materials
like micro and nano aluminum based composites. The combined mechanical thermal synthesis (MTS) has widened the possibilities
for both CS and MS. MTS holds great potential for commercial viability and offers exciting processing route for the synthesis
of advanced materials. Enhanced reaction kinetics and extended concentration limits in MTS are demonstrated by illustrating
the synthesis of aluminum based nanocomposite involving Al–CeO2. 相似文献
26.
Hideo Sawada Hiroshi Kakehi Masashi Koizumi Yoshihiro Katoh Masashi Miura 《Journal of Materials Science》2007,42(17):7147-7153
Fluoroalkyl end-capped N-(1,1-dimethyl-3-oxobutyl)acrylamide oligomer [RF-(DOBAA)
n
-RF] reacted with tetraethoxysilane (TEOS) and silica nanoparticles in the presence of low-molecular weight biocides such as
hibitane, hinokitiol, and hinokioil under alkaline conditions to afford RF-(DOBAA)
n
-RF/silica nanocomposites-encapsulated these biocides in excellent to moderate isolated yields. Fluoroalkyl end-capped N,N-dimethylacrylamide oligomer [RF-(DMAA)
n
-RF] and acrylic acid oligomer [RF-(ACA)
n
-RF]/silica nanocomposites-encapsulated hibitane were obtained under similar conditions. Dynamic light scattering measurements
showed that the size of these fluorinated nanocomposites-encapsulated biocides thus obtained is nanometer size-controlled.
Additionally, these fluorinated nanocomposites were shown to have a good dispersibility and stability in methanol and water.
Of particular interest, these fluorinated nanocomposites-encapsulated biocides were found to have a good antibacterial activity
against Staphylococcus aureus, and these nanocomposites were applied to the surface modification of traditional organic polymers such as poly(methyl methacrylate). 相似文献
27.
28.
29.
Mamiko Hori Cécile Pagnoux Jean-François Baumard Masayuki Nogami 《Journal of Materials Science》2007,42(1):80-86
A new method is proposed to produce gold nanoparticles (GNP) by in situ reduction of a gold salt dissolved in water. The reducing
agent used is Tiron instead of the citrate anion most often mentioned in literature. The influence of various parameters has
been investigated, such as the content of Tiron with respect to that of the precursor of gold HAuCl4, or the initial pH of the solution after mixing of reactants. It is shown that Tiron also exerts a positive influence as
a dispersant, which impedes agglomeration of gold nanoparticles. The typical average size of GNP synthesized in the present
work is close to 7 nm. 相似文献
30.
Nguyen An Tien I. Ya. Mittova O. V. Almjasheva S. A. Kirillova V. V. Gusarov 《Glass Physics and Chemistry》2008,34(6):756-761
Nanocrystalline LaFeO3 is prepared by the dehydration of coprecipitated lanthanum and iron(III) hydroxides. It is shown that the behavior of the samples during heating and the size distribution of LaFeO3 nanocrystals can be considerably different depending on the scheme used for coprecipitation of lanthanum and iron hydroxides; independently of the method employed for coprecipitation of the initial compounds, sintering of the samples at 950°C leads to the formation of lanthanum orthoferrite crystals up to 100 nm in size. 相似文献