Mössbauer spectroscopic studies of Fe-substituted YIG

Compositional dependence of hyperfine parameters, determined through Mössbauer spectral analysis has been studied for Y_3−xFe_5+xO₁₂ (x = 0.0, 0.1, 0.3 and 0.5) garnet system at 300 K. The Mössbauer spectra have been fitted with three sextets in the ferrimagnetic state corresponding to Fe³⁺ ions at tetrahedral (d), octahedral (a) and dodecahedral (c) sites of the crystal structure. It is observed that isormershift, quadrupole shift and hyperfine field of d-site show no significant variation with Fe³⁺ concentration. The change in hyperfine fields of a- and c-sites with composition (x) has been explained on the basis of strength of exchange integrals, change in isomershift can be understood due to s-electron charge distribution and asymmetric displacement of oxygen ions surrounding the a- and c-sites seems to be responsible for observable quadrupole shift. The magneton number values obtained from magnetization and Mossbauer data are in agreement to those calculated using Neel's three sublattice model of ferrimagnetism.     

Extending the color gamut and dynamic range of an sRGB image using a residual image

Image sources, such as digital camera captures and photographic negatives, typically have more information than can be reproduced on a photographic print or a video display. The information that is lost during the tone/color rendering process relates to both the extended dynamic range and color gamut of the original scene. In conventional photographic systems, most of this additional information is archived on the photographic negative and can be accessed by adjusting the way the negative is printed. However, most digital imaging systems have traditionally archived only a rendered video RGB image. As a result, it is not possible to make the same sorts of image manipulations that historically have been possible with conventional photographic systems. This suggests that there would be an advantage to storing images using an extended dynamic range/color gamut color encoding. However, because of file compatibility issues, digital imaging systems that store images using color encoding other than a standard video RGB representation (e.g., sRGB) would be significantly disadvantaged in the marketplace. In this article, we describe a solution that has been developed to maintain compatibility with existing file formats and software applications, while simultaneously retaining the extended dynamic range and color gamut information associated with the original scenes. With this approach, the input raw digital camera image or film scan is first transformed to the scene‐referred ERIMM RGB color encoding. Next, a rendered sRGB image is formed in the usual way and stored in a conventional image file (e.g., a standard JPEG file). A residual image representing the difference between the original extended dynamic range image and the final rendered image is formed and stored in the image file using proprietary metadata tags. This provides a mechanism for archiving the extended dynamic range/color gamut information, which is normally discarded during the rendering process, without sacrificing interoperability. Appropriately enabled applications can decode the residual image metadata and use it to reconstruct the ERIMM RGB image, whereas applications that are not aware of the metadata will ignore it and only have access to the sRGB image. The residual image is formed such that it will have negligible pixel values for those portions of the image that lie within the sRGB gamut, and will therefore be highly compressible. Tests on a population of 950 real customer images have demonstrated that the extended dynamic range scene information can be stored with an average file size overhead of about 8% compared to the sRGB images alone. © 2003 Wiley Periodicals, Inc. Col Res Appl, 28, 251–266, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.10160     

Miniaturised two-stage balanced Ku-band CPW MMIC amplifier using impedance transforming couplers

A two-stage balanced Ku-band coplanar waveguide amplifier design is presented which has been miniaturised by using impedance transforming couplers which considerably reduce the required matching networks to the MESFETs. The amplifier, measuring only 2*1.7 mm/sup 2/, exhibits a gain of 13.7 dB with less than +or-0.2 dB of ripple over the range 14-16 GHz.<>     

Scale periodicity and its sampling theorem

The scalar transform is a new representation for signals, offering a perspective that is different from the Fourier transform. We introduce the notion of a scalar periodic function. These functions are then represented through the discrete scale series. We also define the notion of a strictly scale-limited signal. Analogous to the Shannon interpolation formula, we show that such signals can be exactly reconstructed from exponentially spaced samples of the signal in the time domain. As an interesting, practical application, we show how properties unique to the scale transform make it very useful in computing depth maps of a scene     

A green route for the acylation of resorcinol with acetic acid

2',4'-Dihydroxyacetophenone, also known as resoacetophenone, is a commercially important intermediate which is generally prepared by the acylation of resorcinol with acetic acid in the presence of a molar excess of zinc chloride, which leads to waste disposal problems. The most frequently used acylating agents such as acetic anhydride and acetyl chloride have several disadvantages and need to be replaced by cheap and benign agents. In this connection, acetic acid is a better choice but with a non-polluting and reusable catalyst. The synthesis of 2',4'-dihydroxyacetophenone from resorcinol and acetic acid was carried out in the presence of a variety of solid acid catalysts such as montmorillonite clay (K-10), dodecatungstophosphoric acid (DTP) supported on K-10, sulfated zirconia and ion exchange resins. Amongst these catalysts, Amberlyst-36, an ion exchange resin, was found to be the most effective. The effects of various parameters on the rate of reaction and selectivity were investigated to establish the intrinsic kinetics of the reaction. It was possible to deduce the adsorption equilibrium constant and rate constant simultaneously for the reaction including the corresponding energies of activation. The catalyst is reusable. The process is in consonance with the principles of green chemistry. Electronic Publication     

Hot carrier effects on analog performance of N- and P-MOSFET's withoxynitride gate dielectrics

In this paper we report the impact of hot-carrier stress on analog performance of n- and p-MOSFET's with conventional oxide, NH₃-nitrided oxide (RTN) and reoxidized nitrided oxide (RTN/RTO) as gate dielectrics. Changes due to hot-carrier stress in crucial analog parameters viz., drain output resistance, voltage gain, and input offset voltage of a source coupled differential MOSFET pair are investigated. Results show that RTN/RTO gate dielectrics suppress degradation of analog parameters in n-MOSFET's but increase it slightly in p-MOSFET's, as compared to conventional oxide MOSFET's     

Exact solutions for characterization of electro-elastically graded materials

The present paper deals with a class of functionally graded materials (FGM), called active FGM that has electro-elastically graded material phases. An active FGM system leads to minimization of stress concentration that arises due to mismatch in the electrical and elastic properties of the constituent phases. This work focuses on the characterization of the through thickness stresses of an active FGM subjected to electrical excitation. The structure is comprised of a substrate, an electro-elastically graded layer and an active layer. A formulation for exact solutions of the system based on Euler–Bernoulli theory is presented. Power-law variation of the composition of the two phases in the graded layer is considered. Performance of linearly gradient FGM for a range of stiffness and electrical property ratios of the active and substrate materials have been studied. It is observed that the electrical strain component and the compositional gradation significantly influence the stress characteristics of the active FGM.