Highly Stable Colloidal “Giant” Quantum Dots Sensitized Solar Cells

Colloidal quantum dots (QDs) are widely studied due to their promising optoelectronic properties. This study explores the application of specially designed and synthesized “giant” core/shell CdSe/(CdS)_x QDs with variable CdS shell thickness, while keeping the core size at 1.65 nm, as a highly efficient and stable light harvester for QD sensitized solar cells (QDSCs). The comparative study demonstrates that the photovoltaic performance of QDSCs can be significantly enhanced by optimizing the CdS shell thickness. The highest photoconversion efficiency (PCE) of 3.01% is obtained at optimum CdS shell thickness ≈1.96 nm. To further improve the PCE and fully highlight the effect of core/shell QDs interface engineering, a CdSe_x S_1?x interfacial alloyed layer is introduced between CdSe core and CdS shell. The resulting alloyed CdSe/(CdSe_x S_1?x )₅/(CdS)₁ core/shell QD‐based QDSCs yield a maximum PCE of 6.86%, thanks to favorable stepwise electronic band alignment and improved electron transfer rate with the incorporation of CdSe_x S_1?x interfacial layer with respect to CdSe/(CdS)₆ core/shell. In addition, QDSCs based on “giant” core/CdS‐shell or alloyed core/shell QDs exhibit excellent long‐term stability with respect to bare CdSe‐based QDSCs. The giant core/shell QDs interface engineering methodology offers a new path to improve PCE and the long‐term stability of liquid junction QDSCs.     

An improved observation model for super-resolution under affine motion.

Super-resolution (SR) techniques make use of subpixel shifts between frames in an image sequence to yield higher resolution images. We propose an original observation model devoted to the case of nonisometric inter-frame motion as required, for instance, in the context of airborne imaging sensors. First, we describe how the main observation models used in the SR literature deal with motion, and we explain why they are not suited for nonisometric motion. Then, we propose an extension of the observation model by Elad and Feuer adapted to affine motion. This model is based on a decomposition of affine transforms into successive shear transforms, each one efficiently implemented by row-by-row or column-by-column one-dimensional affine transforms. We demonstrate on synthetic and real sequences that our observation model incorporated in a SR reconstruction technique leads to better results in the case of variable scale motions and it provides equivalent results in the case of isometric motions.     

System integration of high voltage electrostatic MEMS actuators

A system integration for High Voltage (HV) electrostatic MicroElectroMechanical Systems (MEMS) actuators is introduced on a micro-Printed Circuit Board. The system includes a programmable microcontroller, a programmable DC/DC converter, a multi output HV interface and electrostatic MEMS actuators. The system produces high output voltages (10–300 V) and can control a large variety of MEMS capacitive loads (1 to 50 pF) by combining diverse semiconductor technologies. This system proves that technologies, such as low voltage CMOS of different processes, high voltage DMOS and MEMS, can interact, communicate and even be integrated as a System In Package (SIP), providing significant size and cost reductions. The system was programmed to control electrostatic MEMS actuator. The DC/DC converter was made from components of different technologies and two addressable high voltage CMOS interfaces were fabricated with DALSA's 0.8 μm High Voltage process. A prototype of the global system has been built and tested.     

The rise and fall of French Ecological Tax Reform: social acceptability versus political feasibility in the energy tax implementation process

The French government has a 10-year history of negotiations with industry, resulting in voluntary agreements on energy consumption. When implemented, these voluntary agreements produced very few results in terms of global reduction of greenhouse emissions (Politiques et Management Public 11(4) (1993) 47), hence the idea of an energy tax became increasingly attractive for many French decision-makers. Ecological/Environmental Tax Reform (ETR) should have been one of the major political decisions and successes of the past leftwing coalition government. Instead it became one of its major failures as the Constitutional Court decided to terminate the energy tax project in December 2000. Through insights gleaned from focus groups and interviews with business-people and decision-makers, an attempt is made to understand the failure of the energy tax project. Firstly, decision-makers lacked crucial information about public and business opinions and secondly, there were conflicts between the relevant administrations. The fuel revolts of 2000 ended any hope of resolving the conflicts and implementing ETR, which was ultimately found unconstitutional. This paper examines the political controversies raised by the ETR project and the reasons for its eventual collapse, in the hope of contributing new understanding to the body of knowledge on the political difficulties of introducing environmental policy instruments.     

Characterisation and modelling of a 5 kW PEMFC for transportation applications

In the framework of the French inter lab SPACT project (fuel cell systems for transportation applications), a 10 kW PEM fuel cell testing bench has been installed in 2002 in the national fuel cell test platform located in Belfort, France. The behaviour of a 5 kW fuel cell, fed with humidified pure hydrogen gas and compressed air, has been investigated by the Laboratory of Electrical Engineering and Systems (L2ES) in association with the French National Institute for Transport and Safety Research (INRETS).     

Effect of additives on the degradation of acrylamide–acrylic acid copolymer in aqueous solution

This paper presents the results of a systematic study of the effect of different additives on the degradation of acrylamide–acrylic acid copolymers at high temperature. Under conditions of current applications in enhanced oil recovery (without oxygen and in the presence of ferrous ions), the effects of sodium azide, sequestrant DTPA, and isobutanol have been separately tested. It is shown that DTPA enhances degradation when ferrous ions are present. A new process of stabilization which may be efficient in most of the conditions is proposed.     

Tar sand extractions with microemulsions: I-the dissolution of light hydrocarbons by microemulsions using 2-butoxyethanol and diethylmethylamine as cosurfactants

For oil sand extractions with microemulsions it is important to disperse large quantities of light hydrocarbons in an aqueous medium. Fundamental studies on the properties of 2-butoxyethanol (BE) and diethylmethylamine (Et₂McN) in water suggest that these two liquids could be more effective cosurfactants than the usual alcohols used for this purpose. The phase diagrams of microemulsions using BE and Et₂MeN as cosurfactants, combined with typical ionic and non-ionic surfactants and typical aliphatic and aromatic hydrocarbons, were therefore investigated and compared with microemulsions based on n-butanol. Although the phase diagrams depend significantly on the nature of the surfactant and of the oil, the monophasic region generally increases with the cosurfactant in the order n-butanol < Et₂McN < BE. With the active mixture BE-cetyltrimethylammonium bromide, temperature has little effect on the phase diagram and NaCl generally destabilizes the microemulsion.     

Potentiometric titration for determination of amylose content of starch – A comparison with colorimetric method

Amylose, the amount of which varies significantly depending on the source, is one of the key components of starch. The proportion of the essentially linear amylose and the highly branched amylopectin greatly influences the physico-chemical properties of starch. In this study, potentiometric titration using an auto-titrator and colorimetric methods were compared for determining amylose contents of a variety of starch samples. Potentiometric titration results for starches from a variety of botanical sources were within the reported literature ranges while the colorimetric method seemed to overestimate amylose content.     

Multinational firms in the world wine industry: an investigation into the determinants of most-favoured locations

The objective of the paper is to identify some of the determinants of foreign investment of the largest multinational enterprises (MNEs) operating in the wine industry. The factors that drive firms to invest abroad and those that determine the location of those investments are examined in the case of the world wine industry. The list of the largest MNEs has been compiled using financial databases and company websites. Spearman rank correlation values are calculated between the ranking of the location popularity of host countries and the ranking of the independent variables or indices for the same period. The results of this study have some important implications. They indicate that location-specific advantages of host countries do provide an explication of the internationalization of firms in some preferred countries rather than others.     

Effect of a supplementation of Euphorbia heterophylla on nutritional meat quality of Guinea pig (Cavia porcellus L.)

The aim of the present work was to study the effect of dietary supplementation of Euphorbia heterophylla on the quality of the Guinea pig meat. Forty guinea pigs were divided into two groups fed ad libitum during 46 days a Panicum maximum diet (Panicum diet) or a mixed diet (75% Panicum maximum + 25% Euphorbia heterophylla) (Paneuphorbia diet) to compare their effects on performances and on the composition of guinea pig tissues and carcass. Daily weight gain, liver weight, carcass yield, and the lipid content of both the carcass and the perirenal fat were significantly increased by the Paneuphorbia diet. Feeding Paneuphorbia diet increased (P < 0.05) the n-3 PUFA content in perirenal fat, muscle, liver and in the carcass and decreased (P < 0.05) the n-6/n-3 ratios in all these tissues and the carcass. In conclusion, this study shows that Euphorbia heterophylla is a source of n-3 fatty acids which can improve significantly the n-3 PUFA content of Guinea pig meat and carcass.