THERMODYNAMIC PROPERTIES OF FRACTIONAL DIFFERINTEGRO TYPE CONSTITUTIVE RELATIONS

Abstract

Using the asymptotic properties of Riemann-Liouville form, the intrinsic rate-based first and second laws of thermodynamics properties of fractional differintegro operator type constitutive representations are investigated by illustrating how the conservative and nonconservalive features of the response behavior interact under spectrally rich inputs. Due to the generality of the development, fractional operator representations of any order are considered. This includes the determination of the underlying features giving rise to frequency dependencies in the phasing and amplitude behavior and in this context the irreversible energy release rate process associated with fractional viscoelastic simulations.     

Mercury in fruiting bodies of dark honey fungus (Armillaria solidipes) and beneath substratum soils collected from spatially distant areas

BACKGROUND: This paper reports data on bioconcentration potential and baseline mercury concentrations of fruiting bodies of dark honey fungus (Armillaria solidipes) Peck and soil substrate layer (0–10 cm) from 12 spatially distant sites across Poland. Mercury content of caps, stipes and soil samples were determined using validated analytical procedure including cold‐vapor atomic absorption spectroscopy after thermal decomposition of the sample matrix and further amalgamation and desorption of mercury from gold wool. RESULTS: Mean mercury concentrations ranged from 20 ± 8 to 300 ± 70 ng g^?1 dry weight (dw) in caps, from 20 ± 6 to 160 ± 40 ng g^?1 dw in stipes, and in underlying soil were from 20 ± 2 to 100 ± 130 ng g^?1 dw. The results showed that stipes mercury concentrations were 1.1‐ to 1.7‐fold lower than those of caps. All caps and the majority of stipes were characterized by bioconcentration factor values > 1, indicating that dark honey fungus can be characterized as a moderate mercury accumulator. CONCLUSION: Occasional or relatively frequent eating of meals including caps of dark honey fungus is considered safe in view of the low total mercury content, and the mercury intake rates are below the current reference dose and provisionally tolerable weekly intake limits for this hazardous metal. © 2012 Society of Chemical Industry     

Characterization of the surface layers formed on titanium by plasma electrolytic oxidation

This paper is concerned with the surface modification of titanium by the PEO method (plasma electrolytic oxidation) in the solutions which contain Ca, P, Si and Na. The chemical composition of the thus formed surface layers was examined by XPS and EDS. The morphology of the surface was observed by SEM. The phase composition was determined by X-ray diffraction (XRD). The adhesive strength of the oxide layers was evaluated by the scratch-test. The corrosion resistance was determined in a simulated body fluid (SBF) at a temperature of 37 °C by electrochemical methods for various exposure times.The oxide layers obtained were porous and enriched with Ca, P, Si and Na and their properties depended on the electrolyte solution and the parameters of the oxidation process. The results of the electrochemical examinations show that the surface modification by PEO does not worsen the corrosion resistance of titanium after a 13 h exposure in SBF. The electrochemical impedance spectroscopy (EIS) results indicate that the surface layers have a complex structure and that their electric properties undergo changes during long-term exposures in SBF.     

An analysis of the causes of a BWE counterweight boom support fracture

A bucket wheel excavator (BWE) collapsed in a brown coal mine. As a result of a tie rod fracture the counterweight boom, the discharge boom and several other components of the other assemblies underwent plastic deformation. This paper presents the results of computer simulations of the collapse. A finite element method analysis of the counterweight boom tie rod showed stress concentrations exceeding the allowable level. Also material tests of the fracture surface were carried out to identify the causes of the collapse. Macroscopic and microscopic images of areas within the fracture were obtained. Measurements of hardness and microhardness in the vicinity of the weld were performed. The FEM analyses and material tests showed that the causes of the collapse were design and welding faults.     

镍、铜低合金奥贝球铁特性研究

阐明了含Ni、Cu质量分数分别为1.5%和0.8%的奥贝球铁的凝固/相变和性能特点。测定了凝固过程的微分热分析曲线、膨胀仪曲线、绘制了奥氏体连续冷却较变曲线和等温转变动力学曲线，对比分析了该成分铸铁的淬透性。测定了Ni、Cu合金化奥贝球铁的常温力学性能。     

Phase inversion in liquid–liquid pipe flow

This paper covers the phase inversion phenomenon which occurs when an unstable, two-phase liquid–liquid system flows through a horizontal pipe. A short review has been provided for the methods applicable when establishing inversion conditions for stable emulsion systems. As regards phase inversion which takes place in unstable, liquid dispersion systems, the course and findings from our experiments have been described. The experiments involved the mixtures formed by water and four types of oil, and various methods were used for determination of the type of the liquid–liquid system, as well as conditions at which inversion occurred. The experimental findings made it possible to develop a method for determination of the type of an unstable liquid–liquid system which is just flowing, and hence for unequivocal indication of the types of continuous and disperse phases. The suggested method can be easily employed in practice since only the physical properties of both liquids and their mass flux densities need to be taken into consideration.     

NOx emission from a two-stroke ship engine. Part 1: Modeling aspect

International Maritime Organization regulations forces ship owners to measure NO_x emission from ship engines, but standard equipped engine rooms has not installed any usable apparatus to analyze of exhaust gases. In this paper, we propose a method of NO_x emission estimation based on the measurements of working parameters of two-stroke ship engine. This estimation consists of both the model enabling to determine a temperature and model of composition of a gas mixture in the combustion chamber of the engine. Application of such model does not require carrying out direct measurements of engine exhaust gases by exhaust gas analyzers. For the developed method, results of engine working parameters should be sufficient to estimate the NO_x emission according to IMO regulations.     

Resonant measurements of surface resistance of high-Tc superconducting films: How good or bad are they?

Errors in measurements of surface resistanceR _s of HTS materials are due to discrepancy between a mathematical model describing physical phenomena and a real measurement environment, finite accuracy of measurements of theQ-factor, and finite accuracy of constants used for calculation ofR _s . In this paper we analyze errors inR _s due to uncertainties in theQ-factor, geometrical coefficients, loss tangent,R _scu, and other factors when a cylindrical copper cavity with an HTS end plate, a stripline resonator, and sapphire rod resonators are used for HTS characterization.