Preparation,characterization, and adsorption properties for metal ions of a novel chelating resin containing sulfoxide and diethylene glycol

A novel chelating resin containing sulfoxide and diethylene glycol, poly{4‐vinylbenzyl‐[2‐2‐(hydroxyethyl)ethoxyl]sulfoxide} (PVESO) was synthesized using chloromethylated polystyrene (PS‐Cl) as material. Its structure was characterized by elemental analysis, infrared spectra, and scanning electron microscopy (SEM). The adsorption capacities of the resin for Hg²⁺, Ag⁺, Cu²⁺, Zn²⁺, and Pb²⁺ at various pH values were determined. The maximum adsorption capacities for Hg²⁺ and Ag⁺ were 1.56 and 0.75 mmol g^?1 respectively. The resin had high selectivity for Hg²⁺ and Ag⁺ over the pH range 1.0–7.0. The adsorption capacities for Hg²⁺ and Ag⁺ under competitive condition were also determined by batch experiment method. In addition, the adsorption kinetics of the resin towards Hg²⁺ at different temperatures was also investigated. The results showed that the adsorption rate was governed by film diffusion at 20°C and 25°C, by particle diffusion at 30°C and 35°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 6054–6059, 2006     

Studies on membrane formation mechanism by the light transmission technique. I

New parameters, light transmission rate and minimum light transmissions, are proposed. These two parameters reflect the characteristics of the membrane‐forming system and the formation process of the membranes by phase inversion. The relationship between the light transmission and the porous structure of the membrane can be explained by the geometrical optics principles. Variation of the two parameters combining Reuvers's phase separation theory provided a convenient analytical method to predict effectively membrane morphologies. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 174–181, 2003     

不饱和酸结构对不饱和聚酯树脂固化行为的影响

通过IR分析了用顺酐和反酸与聚酯合成不饱和聚酯树脂的反应机理,讨论了二种树脂体系固化放热曲线不同的原因。     

三（β－氯乙基）磷酸酯的合成

以三氯氧磷和环氧乙烷为原料，在三组份催化剂（ＪＣ－１）的催化下合成三（β－氯乙基）磷酸酯，产品的纯度和收率都高。探讨了影响产率的几个因素，工艺简便，易于工业化。     

带式输送机系统的设计与设备选型(一)

1通用带式输送机技术的发展情况 带式输送机与其他运输方式相比具有运距长，能力大，投资省，运费低，操作简单安全，管理维修容易，能耗低，污染小等优势而逐渐成为各行业物料搬运的主要手段。高强度的钢绳芯带式输送机因其为矿山开采和矿石输送工艺创造了十分有利的条件而在各种矿山外部输送中得到快速发展。近年来随着水泥厂规模迅速扩大，带式输送在水泥行业已成为矿石原料输送的首选方案。     

Theory of porous electrodes—XI. The positive plate of the lead-acid battery

Partial differential equations describing the transport of mass and electricity in the pores of the positive electrode of a lead acid battery were derived. The theory is based on exact transport equations and on the assumption that the solid porous matrix has a metallic conductivity. Volume changes in both phases are taken into account. Numerical solutions obtained on a computer are presented for the case where the influence of electrolyte between the electrodes can be neglected. The solutions depend on the product of electrode thickness times current density, and on the initial porosity.     

基于安全隔离的边界防护体系的设计与实现

本文针对电子政务信息系统的特点,设计了基于安全隔离的边界防护体系。将安全隔离技术应用到电子政务中,实现了数据的安全高效实时传输,形成了多方位的安全边界防护体系架构。     

The potentiometric behaviour of copolymers of methacrylic acid in water-ethanol solutions

Summary The synthesis is reported of copolymers of styrene with methacrylic acid and of methyl methacrylate with methacrylic acid by radical copolymerization, of copolymers of methyl methacrylate with methacrylic acid by partial alkaline hydrolysis of poly(methyl methacrylate), and of block copolymers of styrene with methacrylic acid. Modified titration curves of all these copolymers were recorded in water and water-ethanol solutions. In a solution containing 50 mass.% ethanol, only small differences could be observed between the potentiometric behaviour of the individual copolymers and polymethacrylic acid. Also, there were no essential differences in any of the solvents used between the potentiometric behaviour of block copolymers of styrene with methacrylic acid, on the one hand, and polymethacrylic acid, on the other. On the contrary, maxima and minima were always observed on the modified titration curves of statistical copolymers with a higher content of the hydrophobic comonomer in solutions with a high water content. Thus, using the modified titration curves, it is possible to decide whether a given copolymer is of the block or statistical type.     

模糊综合评价方法在桥型多方案选择中的应用

为了解决现阶段桥型多方案选择中过多依赖设计者经验,而不可避免的带来主观性与片面性的问题.针对桥型方案选择的多因素与模糊性特征,提出了模糊综合评价方法在桥型多方案选择中的应用,确定了影响桥梁选型的指标体系,介绍了该方法的应用模型与步骤,并结合实例详细介绍了这种方法的应用过程.结果验证了这一方法的简明性和实用性.有利于减少桥梁型式选择的失误,提高其客观性与合理性,以得出最佳方案.