Synthesis and electrochemical application of carbon nanotubes obtained from hexachloroethane

Carbon nanotubes (CNTs) with the average inner (outer) diameter of 10–20 nm (20–40 nm) and length up to 100s of nanometers were synthesized via Wurtz reaction at 400 °C for 12 h, using C₂Cl₆ and Na as reactants. These CNTs, having more defects because of the sp³ bonding raw material of C₂Cl₆, were used as electrode material to detect dopamine (DA) via cyclic voltammetry. The results show that there exists linear relation between peak currents and DA concentration in the range of 2 × 10⁻⁷∼2.8 × 10⁻⁴ mol L⁻¹.The linear regression equation is expressed as Ip (μA) = 0.089 + 0.134c (μmol L⁻¹). This CNTs-modified electrode showed high sensitivity with detection limit of 1 × 10⁻⁷ mol L⁻¹.     

Aerodynamic Characteristics of Popcorn Ash Particles

Popcorn ash particles are fragments of sintered coal fly ash masses that resemble popcorn in low apparent density. They can travel with the flow in the furnace and settle on key places such as catalyst surfaces. Computational fluid dynamics (CFD) models are often used in the design process to prevent the carryover and settling of these particles on catalysts. Particle size, density, and drag coefficient are the most important aerodynamic parameters needed in CFD modeling of particle flow. The objective of this study was to experimentally determine particle size, shape, apparent density, and drag characteristics for popcorn ash particles from a coal-fired power plant. Particle size and shape were characterized by digital photography in three orthogonal directions and by computer image analysis. Particle apparent density was determined by volume and mass measurements. Particle terminal velocities in three directions were measured in water and each particle was also weighed in air and in water. The experimental data were analyzed and models were developed for equivalent sphere and equivalent ellipsoid with apparent density and drag coefficient distributions. The method developed in this study can be used to characterize the aerodynamic properties of popcorn-like particles.     

Decay of two-qubit correlation in correlated stochastic dephasing

Time evolutions of quantum correlation, classical correlation and total correlation of two qubits are investigated when the two qubits are placed under the influence of classical phase fluctuations with correlation. Stochastic variables that describe the phase fluctuations are correlated and subject to the stationary Gauss–Markov process. The model includes the local and global dephasing models. It is shown that the quantum correlation measured by the quantum discord is increased by the correlation between the stochastic variables in the initial time region while the classical correlation and the total correlation are not. Furthermore the entanglement, the optimal fidelity of the quantum teleportation and the violation of the Bell inequality are investigated.     

声强测量法在汽车空调噪声测量中的应用

分析声强测量法的原理与优点，介绍声强测量法在汽车空调噪声声功率级测试中的应用。通过比较声强法与普通方法的测量结果，证明声强测量法在空调噪声测试中具有足够高的精度，有很高的实用价值。     

Development of a web-based CT dose calculator: WAZA-ARI

A web-based computed tomography (CT) dose calculation system (WAZA-ARI) is being developed based on the modern techniques for the radiation transport simulation and for software implementation. Dose coefficients were calculated in a voxel-type Japanese adult male phantom (JM phantom), using the Particle and Heavy Ion Transport code System. In the Monte Carlo simulation, the phantom was irradiated with a 5-mm-thick, fan-shaped photon beam rotating in a plane normal to the body axis. The dose coefficients were integrated into the system, which runs as Java servlets within Apache Tomcat. Output of WAZA-ARI for GE LightSpeed 16 was compared with the dose values calculated similarly using MIRD and ICRP Adult Male phantoms. There are some differences due to the phantom configuration, demonstrating the significance of the dose calculation with appropriate phantoms. While the dose coefficients are currently available only for limited CT scanner models and scanning options, WAZA-ARI will be a useful tool in clinical practice when development is finalised.     

Residual impurities in GaN/Al2O3 grown by metalorganic vapor phase epitaxy

Residual impurities in GaN films on sapphire (A1₂O₃) substrates grown by two-step metalorganic vapor phase epitaxy (MOVPE) have been investigated. We have mainly investigated the incorporation of carbon into the GaN films with GaN buffer layers on A1₂O₃ during MOVPE growth, comparing trimethygallium (TMGa) and triethygallium (TEGa) as the typical gallium precursors. The films were characterized by secondary ion mass spectroscopy analysis, photolu-minescence, and Hall measurements. The carbon, hydrogen, and oxygen concentrations increase with decreasing growth temperature in using TMGa. Especially the carbon concentration increases with decreasing a V/III ratio, for both TMGa and TEGa. There is about two times more carbon in the GaN films grown using TEGa than those using TMGa. The carbon from TMGa mainly enhances the D-A pair emission (∼378 nm), which shows the carbon makes an acceptor level at nitrogen sites in GaN. On the other hand, the carbon from TEGa enhances a deep emission (∼550 nm), which shows the carbon makes not only an acceptor level but deep levels at interstitial sites in GaN. The carbon impurities originate from methyl radicals for TMGa, or ethyl radicals for TEGa. It is supposed that, in the case of TEGa, the carbon impurities are not always located at nitrogen sites, but are also located at interstitial sites because of the C-C bonding in ethyl radicals.     

背腔式微带贴片天线的近场分布和交叉极化方向图的数值计算

采用矢量有限元——边界积分混合方法针对带有背腔结构的微带贴片天线进行了数值计算：首先计算了E面、H面方向图，用于验证该混合方法的正确性；接着计算了在第一谐振频点f1=1．96724G、第二谐振频点f2=2．85G处天线表面缝隙处的电场分布，同时讨论了天线的交叉极化方向图在两个谐振点的变化；最后分别针对在失谐状态下、电介质的不同损耗正切角、加有探针负载等情况，计算了相应的交叉极化方向图，讨论了其变化。     

In0.53Ga0.47As/InP floating guard ringavalanche photodiodes fabricated by double diffusion

In_0.53Ga_0.47As/InP separate absorption and multiplication region avalanche photodiodes (SAM-APDs) with doubly diffused floating guard rings have been demonstrated. The planar, front-side illuminated devices are easily fabricated and incorporate strong guarding against edge and surface breakdown. Edge gain is suppressed both by the action of the floating guard rings and by the grading of the p-n junction at the outer edges of the active region that results from the second diffusion. Uniform gains as high as 85 have been measured at multiplied dark currents <100 nA. Multiplied dark currents below 5 nA have been measured at 90% of breakdown, with capacitances below 400 fF for front-side illuminated devices. The low values of dark current and capacitance, as well as the ease of fabrication, make the devices well suited for fiber-optic applications     

Binding energies of shallow impurities in asymmetric strained wurtzite Al_x Ga_(1-x)N/GaN/AIy Ga1-y N quantum wells

The ground state binding energies of hydrogenic impurities in strained wurtzite Al_xGa_1-xN/GaN/Al_yGa_1-yN quantum wells are calculated numerically by a variational method.The dependence of the binding energy on well width,impurity location and Al concentrations of the left and right barriers is discussed,including the effect of the built-in electric field induced by spontaneous and piezoelectric polarizations.The results show that the change in binding energy with well width is more sensitive to the impurity position and barrier heights than the barrier widths,especially in asymmetric well structures where the barrier widths and/or barrier heights differ.The binding energy as a function of the impurity position in symmetric and asymmetric structures behaves like a map of the spatial distribution of the ground state wave function of the electron.It is also found that the influence on the binding energy from the Al concentration of the left barrier is more obvious than that of the right barrier.