全文获取类型
收费全文 | 142210篇 |
免费 | 24942篇 |
国内免费 | 6334篇 |
专业分类
电工技术 | 8595篇 |
技术理论 | 8篇 |
综合类 | 8310篇 |
化学工业 | 32224篇 |
金属工艺 | 6685篇 |
机械仪表 | 8136篇 |
建筑科学 | 10092篇 |
矿业工程 | 3409篇 |
能源动力 | 3909篇 |
轻工业 | 14715篇 |
水利工程 | 2974篇 |
石油天然气 | 5777篇 |
武器工业 | 1167篇 |
无线电 | 19233篇 |
一般工业技术 | 22009篇 |
冶金工业 | 4761篇 |
原子能技术 | 1431篇 |
自动化技术 | 20051篇 |
出版年
2024年 | 506篇 |
2023年 | 1735篇 |
2022年 | 3433篇 |
2021年 | 4981篇 |
2020年 | 4957篇 |
2019年 | 5871篇 |
2018年 | 6172篇 |
2017年 | 6852篇 |
2016年 | 7004篇 |
2015年 | 8635篇 |
2014年 | 9756篇 |
2013年 | 11765篇 |
2012年 | 10599篇 |
2011年 | 10926篇 |
2010年 | 10271篇 |
2009年 | 9706篇 |
2008年 | 9309篇 |
2007年 | 8740篇 |
2006年 | 7819篇 |
2005年 | 6277篇 |
2004年 | 4800篇 |
2003年 | 4122篇 |
2002年 | 4074篇 |
2001年 | 3495篇 |
2000年 | 3043篇 |
1999年 | 2180篇 |
1998年 | 1237篇 |
1997年 | 1037篇 |
1996年 | 922篇 |
1995年 | 820篇 |
1994年 | 608篇 |
1993年 | 455篇 |
1992年 | 324篇 |
1991年 | 211篇 |
1990年 | 202篇 |
1989年 | 184篇 |
1988年 | 129篇 |
1987年 | 75篇 |
1986年 | 58篇 |
1985年 | 40篇 |
1984年 | 22篇 |
1983年 | 17篇 |
1982年 | 24篇 |
1981年 | 19篇 |
1980年 | 29篇 |
1979年 | 18篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1959年 | 10篇 |
1951年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
121.
122.
Seyedeh Nooshin Banitaba Dariush Semnani Elahe Heydari‐Soureshjani Behzad Rezaei Ali A Ensafi Ahmadreza Taghipour‐Jahromi 《Polymer International》2020,69(8):675-687
In this study, solvent‐free nanofibrous electrolytes were fabricated through an electrospinning method. Polyethylene oxide (PEO), lithium perchlorate and ethylene carbonate were used as polymer matrix, salt and plasticizer respectively in the electrolyte structures. Keggin‐type hetero polyoxometalate (Cu‐POM@Ru‐rGO, Ni‐POM@Ru‐rGO and Co‐POM@Ru‐rGO (POM, polyoxometalate; rGO, reduced graphene oxide)) nanoparticles were synthesized and inserted into the PEO‐based nanofibrous electrolytes. TEM and SEM analyses were carried out for further evaluation of the synthesized filler structures and the electrospun nanofibre morphologies. The fractions of free ions and crystalline phases of the as‐spun electrolytes were estimated by obtaining Fourier transform infrared and XRD spectra, respectively. The results showed a significant improvement in the ionic conductivity of the nanofibrous electrolytes by increasing filler concentrations. The highest ionic conductivity of 0.28 mS cm?1 was obtained by the introduction of 0.49 wt% Co‐POM@Ru‐rGO into the electrospun electrolyte at ambient temperature. Compared with solution‐cast polymeric electrolytes, the electrospun electrolytes present superior ionic conductivity. Moreover, the cycle stability of the as‐spun electrolytes was clearly improved by the addition of fillers. Furthermore, the mechanical strength was enhanced with the insertion of 0.07 wt% fillers to the electrospun electrolytes. The results implied that the prepared nanofibres are good candidates as solvent‐free electrolytes for lithium ion batteries. © 2020 Society of Chemical Industry 相似文献
123.
124.
This study assessed the collection efficiency (CE) of two popularly used sampling devices (BioSampler and Coriolis sampler) for fungal aerosols. Phosphate‐buffered saline (PBS) supplemented with or without surfactant (Tween‐20, Tween‐80, or Triton X‐100) and antifoam agent was prepared and used as collection liquids. The agar impactor (BioStage) was simultaneously operated with liquid‐based samplers to collect fungi from seven sites located at a university building, public library, and animal farming. Fungal concentrations determined by liquid samplers were divided by those by BioStage, and the ratio values represented CE. Results indicate that the CE of BioSampler was superior to that of Coriolis (P = 0.0001) and the PBS containing surfactant collected fungi better than that without surfactant (P < 0.0001), whereas antifoam agent showed no influence (P = 0.8). Moreover, fungal concentrations determined by BioSampler with surfactant‐added PBS were statistically indifferent from those by BioStage (P > 0.05) with a Spearman correlation coefficient of 0.81‐0.83 (P < 0.01). In addition to sampler and collection liquid, sampling location was also identified as a significant CE factor (P = 0.006), implying potential influences by fungal genera in the studied fields. Overall, BioSampler with surfactant‐supplemented PBS (eg, Triton X‐100) is recommended considering the great CE and compatibility with a variety of analytical assays. 相似文献
125.
126.
Although Mg alloy attracts great attention for engineering applications because of high specific strength and low density, low corrosion resistance limits its extensive use. In this study, Mg–Al–Zn–Mn alloy was treated via a laser cladding process to generate a dense and compact laser cladding layer with solid metallurgical bonding on the substrate for improving corrosion resistance, effectively hindering the corrosion pervasion into Mg alloy. The corrosion current density declined from 103 μA/cm2 for Mg alloy to 13 μA/cm2 for the laser cladding layer in NaCl aqueous solution. Moreover, the laser cladding layer was slightly corroded in comparison with Mg alloy in NaCl aqueous solution. Besides, the microhardness of the cladding layer reached a mean value of 170.5 HV, 3.1 times of Mg alloy (56.8 HV) due to the in situ formation of hardening intermetallic phases. Wear resistance of laser cladding layer was also obviously improved. These results demonstrated that the laser cladding layer obviously enhanced anticorrosion property of Mg alloy for engineering applications. 相似文献
127.
以二茂铁甲醛和对甲苯磺酰基异氰(TOSMIC)为原料,经过Van Leusen反应,一步合成目标化合物5-二茂铁基噁唑,通过~1HNMR、~(13)CNMR和ESI-MS对其结构进行表征,并对影响收率的主要因素进行考察。结果表明,在物料比n(TOSMIC)∶n(二茂铁甲醛)为1.1∶1、反应溶剂为甲醇、K_2CO_3用量即n(K_2CO_3)∶n(二茂铁甲醛)为2.0∶1、反应温度为65℃、反应时间为8 h的最佳条件下,目标化合物收率达到74.7%。该方法具有原料廉价易得、反应操作简单、收率高等优点,具有一定的应用价值。 相似文献
128.
Alfredo M. Gravagnuolo Eden Morales‐Narváez Charlene Regina Santos Matos Sara Longobardi Paola Giardina Arben Merkoçi 《Advanced functional materials》2015,25(38):6084-6092
Class I hydrophobin Vmh2, a peculiar surface active and versatile fungal protein, is known to self‐assemble into chemically stable amphiphilic films, to be able to change wettability of surfaces, and to strongly adsorb other proteins. Herein, a fast, highly homogeneous and efficient glass functionalization by spontaneous self‐assembling of Vmh2 at liquid–solid interfaces is achieved (in 2 min). The Vmh2‐coated glass slides are proven to immobilize not only proteins but also nanomaterials such as graphene oxide (GO) and quantum dots (QDs). As models, bovine serum albumin labeled with Alexa 555 fluorophore, anti‐immunoglobulin G antibodies, and cadmium telluride QDs are patterned in a microarray fashion in order to demonstrate functionality, reproducibility, and versatility of the proposed substrate. Additionally, a GO layer is effectively and homogeneously self‐assembled onto the studied functionalized surface. This approach offers a quick and simple alternative to immobilize nanomaterials and proteins, which is appealing for new bioanalytical and nanobioenabled applications. 相似文献
129.
Mohammad Reza Gaeeni Morteza Sasani Ghamsari Abbas Majd Abadi Mohammad Hossein Majles Ara Wooje Han Hyung‐Ho Park 《Journal of the American Ceramic Society》2015,98(6):1818-1822
A facile sol–gel procedure has been developed for the synthesis of colloidal alumina nanocrystals. For the first time, optical characterization procedures were employed to study the quantum confinement effects in optical properties of the prepared Al2O3 sol. Accordingly, the hyperbolic band model was used to determine the optical band gap of colloidal alumina nanocrystals. X‐Ray diffraction pattern was used to study the crystallographic phase of the dried gel. Morphological characterization was performed using scanning electron microscopy (SEM). Inductively Coupled Plasma (ICP) emission spectroscopy was used to determination purity of the Al2O3 powder. High‐resolution TEM showed that the diameter of colloidal nanocrystals is about 10 nm. Photoluminescence spectroscopy demonstrated that quantum yields for colloidal nanocrystals are 68% with 300 nm excitation wavelength. The experimental observations confirm that highly stable alumina sol with strong UV emission was synthesized. The mentioned optical properties have not been reported before. 相似文献
130.