An equivalent circuit model of a pixellated-metal-mirror ferroelectric liquid crystal (FLC) optically addressed spatial light modulator (OASLM) is proposed. Using both structure and FLC material parameters of a real device and real material as the simulation parameters, the model is firstly confirmed by good agreement of simulation results and the reported experimental ones, and then utilized to optimize gray-scale performance of the OASLM. The model is developed from an improved FLC equivalent circuit, and has the ability to describe the voltage dropped across the modulating layer and to predict how optical outputs vary over time with the input drive voltage and control image. Simulation results indicate that gray-scale performance of the OASLM is highly dependent on write pulse width. More than 10 gray scales are observed when write pulse width is 100 μs and the number reduces to four when it reaches 500 μs. Other parameters of drive voltage can be set to adjust the region of write light intensity over which gray scales are best produced, and write pulses are found to be primary at high write light intensities, whereas erase pulses are dominant at low write light intensities. Furthermore, although gray-scale performance is weakly dependent on erase-light intensity, the erase light is necessary to ensure a proper erasure of the device and at least 1 mW/cm2 is required in this study. 相似文献
In this paper, a new method of electric field design of high voltage vacuum interrupters is proposed. According to the multi-gap insulation effect and the vulnerable breakdown spots theory, the symmetrical voltage shields are proved to be effective. So the initial model of a high voltage vacuum interrupter is designed. Next with finite element methods and optimization theory, a mathematical model of electric field intensity in interrupters is given. What's more, by optimizing this model with finite element software, a more symmetrical electric field in vacuum interrupters is obtained and its peak value appear as in the second auxiliary gaps (the two gaps between the center floating shield and the symmetrical voltage shields). The result shows that with this method, the vacuum interrupters can withstand higher static breakdown. 相似文献
Manipulating the alignment of liquid crystals (LCs) is a hot and fundamental issue for their applications in block copolymers, photonics, actuators, biosensors, and liquid-crystal displays. Here, the surface characteristic of Cu2O nanocrystals was well controlled to manipulate the orientation of the LCs. The mechanism of the orientation of the LCs induced by Cu2O nanocrystals was elucidated based on the interaction between the LCs and Cu2O nanocrystals. To comprehensively prove our assumption, different types of LCs (nematic, cholesteric, and smectic) as well as the same type of LCs with different polarities were selected in our system. Moreover, the photomechanical behaviors of the LC polymer composites demonstrated that the alignment of LCs can be effectively manipulated using Cu2O nanocrystals.
Nanomaterials with intense near-infrared (NIR) absorption exhibit effective photon-to-thermal energy transfer capabilities and can generate heat to ablate cancer cells, thus playing a pivotal role in photothermal cancer therapeutics. Herein, hydrophilic flower-like bismuth sulfur (Bi2S3) superstructures with uniform size and improved NIR absorption were controllably synthesized via a facile solvothermal procedure assisted by polyvinylpyrrolidone (PVP), which could adjust the product morphology. Induced by an 808-nm laser, the as-prepared Bi2S3 nanoflowers exhibited much higher photothermal conversion efficiency (64.3%) than that of Bi2S3 nanobelts (36.5%) prepared in the absence of PVP. This can be attributed not only to the Bi2S3 nanoflower superstructures assembled by 3-dimensional crumpled-paper-like nanosheets serving as many laser-cavity mirrors with improved reflectivity and absorption of NIR light but also to the amorphous structures with a lower band gap. Thus, to achieve the same temperature increase, the concentration or laser power density could be greatly reduced when using Bi2S3 nanoflowers compared to when using Bi2S3 nanobelts, which makes them more favorable for use in therapy due to decreased toxicity. Furthermore, these Bi2S3 nanoflowers effectively achieved photothermal ablation of cancer cells in vitro and in vivo. These results not only supported the Bi2S3 nanoflowers as a promising photothermal agent for cancer therapy but also paved an approach to exploit new agents with improved photothermal efficiency.
A series of copper catalysts with a core–shell or tubular structure containing various contents of Cu, Cu2O, and CuO were prepared via controlled oxidation of Cu nanowires (NWs) and used in the synthesis of dimethyldichlorosilane (M2) via the Rochow reaction. The Cu NWs were prepared from copper (II) nitrate using a solution-based reduction method. The samples were characterized by X-ray diffraction, thermogravimetric analysis, temperature-programmed reduction, X-ray photoelectron spectroscopy, transmission electron microscopy, and scanning electron microscopy. It was found that the morphology and composition of the catalysts could be tailored by varying the oxidation temperature and time. During the gradual oxidation of Cu NWs, the oxidation reaction initiated on the outer surface and gradually developed into the bulk of the NWs, leading to the formation of catalysts with various structures and layered compositions, e.g., Cu NWs with surface Cu2O, ternary Cu–Cu2O–CuO core–shell NWs, binary Cu2O–CuO nanotubes (NTs), and single CuO NTs. Among these catalysts, ternary Cu–Cu2O–CuO core–shell NWs exhibited superior M2 selectivity and Si conversion in the Rochow reaction. The enhanced catalytic performance was mainly attributed to improved mass and heat transfer resulting from the peculiar heterostructure and the synergistic effect among layered components. Our work indicated that the catalytic property of Cu-based nanoparticles can be improved by carefully controlling their structures and compositions.