Dendron-functionalized perylene diimides with carrier-transporting ability for red luminescent materials

This paper presents a series of dendrimers via a convergent synthetic approach with three generations, which contain perylene diimide cores, Fréchet-type poly(aryl ether) dendrons, and carbazole (CZ) or oxadiazole (OXZ) peripheral functional groups. The higher generation dendrimer has an obvious site-isolation or dilution effect of dendrons, which results in a relatively small red-shift of absorption and emission spectra when it forms a solid thin film for applications. The interactions between peripheral units and perylene diimide core in the dendrimers are also studied by steady-state and time-resolved fluorescence spectra under both direct and indirect excitation. The fluorescence data show that there exist two possible mechanisms, Förster energy transfer (FRET) and photo-induced electron transfer (PET), for dendrimers bearing carbazole units. No enhanced core fluorescence is observed because the energy transfer or light-harvesting potential of peripheral carbazole is counteracted by PET. While for dendrimers bearing oxadiazole units, no PET can take place between OXZ and perylene diimide since both of them are high electron affinity. The FRET and higher light-harvesting ability of oxadiazole without PET interfering result in the distinct enhancement of core emission in higher generation dendrimers. DSC results indicate that the incorporation of Fréchet-type poly(aryl ether) dendrons can improve the amorphous property and increase glass transition temperature (T_g). The preliminary EL results with single-layer architectures demonstrate that these dendrimers could be utilized as a promising kind of active red luminescent emitters with carrier-transporting ability. EL emission has the same recombination zone as PL, indicating that the recombination of excitons in fabricated EL devices is not close to cathode or anode vicinity. It is suggested that the site-isolation effect of dendron wedges is attributed to prevent the core luminorphores from approaching electrodes efficiently.     

南水北调中线总干渠水质变化趋势及污染源分析

为了解和掌握南水北调中线总干渠水质状况,依据总干渠26个常规水质断面监测数据,分析了总干渠沿程水质变化趋势。结果表明,主要污染指标(CODMn、氨氮、总氮和总磷)呈现出沿程增加趋势。根据影响总干渠水质的潜在影响因素,分析了7类污染源(直接水污染、大气粉尘沉降、桥面雨水污染、底泥污染、周边垃圾场淋溶液污染、雨洪污染、受污染地下水)及其可能对干渠水质产生的影响程度,并针对不同污染源提出了防控对策,供管理部门决策参考。     

无汞碱性锌锰电池贮存期漏液原因探讨

介绍了无汞锌粉中的杂质、析气量、锌粉形貌以及电池密封圈对无汞碱性电池高温贮存性能的影响，探讨了电池漏液的原因，提出了防止漏液的措施。     

On the complexity of role updating feasibility problem in RBAC

In Role Based Access Control (RBAC) systems, it is necessary and important to update the role–permission assignments in order to reflect the evolutions of the system transactions. However, role updating is generally complex and challenging, especially for large-scale RBAC systems. This is because the resulting state is usually expected to meet various requirements and constraints. In this paper, we focus on a fundamental problem of role updating in RBAC, which determines whether there exists a valid role–permission assignment, i.e., whether it can satisfy all the requirements of the role updating and without violating any role–capacity or permission–capacity constraint. We formally define such a problem as the Role Updating Feasibility Problem (RUFP), and study the computational complexity of RUFP in different subcases. Our results show that although several subcases are solvable in linear time, this problem is NP-complete in the general case.     

壳聚糖对化学镀镍废液中Ni^2＋吸附

研究了用壳聚糖吸附化学镀镍废液中Ni^2＋的最佳条件及其脱附和再生方法，以及镀液中络合剂等其他组分对吸附率的影响。结果表明，壳聚糖对化学镀镍废液中的Ni^2＋具有较好的吸附能力，pH是影响吸附的主要因素。在室温、pH=5．0时，Ni^2＋质量浓度为4．6952g／L的化学镀镍废液被0．9390g壳聚糖吸附2h后，Ni^2＋的去除率达72．25％。     

无油螺杆压缩机在燃料电池中的应用

由于环境污染、全球变暖、能源短缺等各方面原因,能量转换效率高且无污染的燃料电池汽车备受人们的青睐,作为燃料电池系统中重要部件之一的空气压缩机也成为研究的热点。西安交通大学压缩机研究所成功研制了可以应用于燃料电池的LG300型喷水螺杆空气压缩机以及具有体积小、质量轻、效率高的高速干式螺杆压缩机、膨胀机,并且经过与燃料电池系统配套使用,获得成功。     

Users’ interest grouping from online reviews based on topic frequency and order

Large volume of online review data can reveal consumers’ major interests on domain product, which attracts great research interests from the academic community. Most of the existing works focus on the problems of review summarization, aspect identification or opinion mining from an item’s point of view such as the quality or popularity of products. Considering the fact that users who generate those review texts draw different attentions to product aspects with respect to their own interests, in this article, we aim to learn K users’ interest groups indicated by their review writings. Such K interest groups’ identification can facilitate better understanding of major and potential consumers’ concerns which are crucial for applications like product improvement on customer-oriented design or diverse marketing strategies. Instead of using a traditional text clustering approach, we treat the groupId/clusterId as a hidden variable and use a permutation-based structural topic model called KMM. Through this model, we infer K interest groups’ distribution by discovering not only the frequency of product aspects (Topic Frequency), but also the occurrence priority of respective aspects (Topic Order). They jointly present an informative summarization on the raw review corpus. Our experiment on several real-world review datasets demonstrates a competitive solution.     

基于SOA的智能航运数据服务平台研究

为了实现全国范围的内河航运数据共享,提高我国内河航运的管理水平,需要一种稳定可靠、松耦合的数据共享方式。针对当前的内河航运数据共享需求,并根据当前我国各省的内河航运信息化建设的实际情况,参考国内外成熟的理论基础,提出了基于SOA的数据共享体系,从而实现多节点的关键数据实时共享的应用场景。通过这种方式可以实现内河航运数据共享服务,满足航运信息服务的要求,并适应今后不断增长的共享节点及共享压力。     

雷达软件测试文档追踪系统的关键技术研究

雷达软件规模日益庞大,其软件测试也变得非常复杂,测试需求追踪逐步变成非常困难的任务,目前急需解决雷达软件中测试需求追踪管理、文档自动生成等问题。通过对软件测试需求的识别与定位、软件测试任务的分派,实现了雷达软件测试需求的跟踪、追溯,以及按标准模板产生相应的文档,重点对实现该追踪系统的关键技术进行了分析和描述。     

纳米碳酸钙在非等温条件下热分解动力学及机理研究

Experiments on thermal decomposition of nano-sized calcium carbonate were carried out in a thermo-gravimetric analyzer under non-isothermal condition of different heating rates (5 to 20K·min-1). The Coats and Redfern's equation was used to determine the apparent activation energy and the pre-exponential factors. The mechanism of thermal decomposition was evaluated using the master plots, Coats and Redfern's equation and the kinetic compensation law. It was found that the thermal decomposition property of nano-sized calcium carbonate was different from that of bulk calcite. Nano-sized calcium carbonate began to decompose at 640℃, which was 180℃lower than the reported value for calcite. The experimental results of kinetics were compatible with the mechanism of one-dimensional phase boundary movement. The apparent activation energy of nano-sized calcium carbonate was estimated to be 151kJ·mol-1 while the literature value for normal calcite was approximately 200kJ·mol-1. The order of magnitude of pre-e