The effect of ionic interaction on the miscibility and crystallization behaviors of poly(ethylene glycol)/poly(L‐lactic acid) blends

The effect of end groups (2NH₂) of poly(ethylene glycol) (PEG) on the miscibility and crystallization behaviors of binary crystalline blends of PEG/poly(L ‐lactic acid) (PLLA) were investigated. The results of conductivity meter and dielectric analyzer (DEA) implied the existence of ions, which could be explained by the amine groups of PEG gaining the protons from the carboxylic acid groups of PLLA. The miscibility of PEG(2NH₂)/PLLA blends was the best because of the ionic interaction as compared with PEG(2OH, 1OH‐1CH₃, and 2CH₃)/PLLA blends. Since the ionic interaction formed only at the chain ends of PEG(2NH₂) and PLLA, unlike hydrogen bonds forming at various sites along the chains in the other PEG/PLLA blend systems, the folding of PLLA blended with PEG(2NH₂) was affected in a different manner. Thus the fold surface free energy played an important role on the crystallization rate of PLLA for the PEG(2NH₂)/PLLA blend system. PLLA had the least fold surface free energy and the fast crystallization rate in the PEG(2NH₂)/PLLA blend system, among all the PEG/PLLA systems studied. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Electronic properties of dehydrogenated nanodiamonds: A first-principles study

First-principles calculations using quantum-mechanical density functional theory (DFT) are carried out to study the geometric structure and electronic properties of dehydrogenated nanodiamonds with diameters varying from 0.8 nm to 1.6 nm. The results show that the electronic properties of dehydrogenated nanodiamond are quite different from those of bulk diamond or hydrogenated nanodiamond. Surface atoms play an important role in the electronic structure, especially the states near the Fermi level, for dehydrogenated nanodiamond. In addition, it has been revealed that the size-dependent feature in the electronic properties for dehydrogenated diamonds is also contributed by the surface effect, in addition to the quantum confinement effect.     

直接斜率波前复原算法的控制效果分析

建立自适应光学系统功率谱抑制函数的概念，分析了采用直接斜率波前复原算法的自适应当光学系统的控制效果，理论分析与６１单元自适应光学系统上的实验结果表明，直接斜率波前复原算法将导致控制效果下降。     

3^n阶矩阵乘法的分块算法

针对３＾ｎ阶矩阵的乘法运行，给出了一种分块算法，其乘法运行量比常规的矩阵乘法计算方法和补零的基－２算法都有所减少。     

浸胶工艺对Nomex蜂窝性能的影响

本文研究了浸胶工艺对Ｎｏｍｅｘ蜂窝性能的影响，分析探讨了提高Ｎｏｍｅｘ蜂窝性能及外观质量的途径。研究结果表明：采取新的浸胶工艺制作的Ｎｏｍｅｘ蜂窝，各项性能全面达到法国宇航材料标准。     

大力发展循环经济实现企业可持续发展

莱钢始建于1970年1月,现控股莱钢股份、鲁银投资两个上市公司及齐鲁证券等25个子公司。莱钢是中国冶金行业首批通过ISO9002质量管理体系、ISO14001环境管理体系和OHSAS18001职业安全健康管理体系国家认证的企业。2005年,莱钢被国家发改委确定为国家第一批循环经济试点单位。     

2007年1-10月主要钢铁产品进出口形势分析

2007年1-10月,我国的粗钢产量达到4.09亿吨,同比增长18.14%。10月单月产量4292.2万吨,再创单月产量新高;1-10月,钢材产量达4.67亿吨(含重复材),同比增长23.53%,10月钢材产量     

浅谈低温地面辐射采暖的利弊及隐患的避免

本文主要对低温地面辐射采暖的利弊及其隐患和隐患的避免加以分析、探讨。     

一幅画

从吃饱到吃好、吃精至吃的环境,人们对生活的要求逐渐趋向艺术化,餐馆老板会把环境设计与经营放在同等地位,所以好的餐饮空间层出不穷,也是社会发展的必然产物。位于宁波老外滩的瀚珍舫餐馆,建筑一层的面积较小,二、三层呈狭长形,做为餐馆这样的建筑条件并不理想,设计师把包厢和雅座设置在两边,这样走廊显得更幽深,柱子阵列得更有气势。拆除原先的楼梯,做了一部上下错位且不规则楼梯,曲折向上,增强了空间的层次。通顶的储酒柜,从三楼悬下的八米长吊灯,把一至三楼不落痕迹地融为一体。要设计一个好作品,设计师的构想需要不停地游走。碰撞的激情仿佛是一幅画,渐渐地,它的轮廓清晰了,色彩明朗了,它的主题神秘而遥不可及,每个人的心扉都有不同的暗香飘逸。掩映在现代手法中的精致、深沉从骨子里透出古典优雅     

Scattering center parameterization of wide-angle backscattered datausing adaptive Gaussian representation

We present a scattering center extraction algorithm to parameterize the backscattered data from complex targets collected over large angular apertures. This parameterization is based on a scattering center model of the target, but includes an aspect-dependent amplitude function for each scattering center. A two-dimensional (2-D) adaptive Gaussian representation (AGR) algorithm is used to extract the position and the amplitude function associated with each scattering center. The algorithm is tested with data generated by the Xpatch radar simulation code as well as chamber measurement data. The results show that a very good compression ratio can be achieved, resulting in a compact scattering center model of the target. Once such model is available, we can easily reconstruct range profiles and ISAR images at any aspect on the same plane with good accuracy