Preparation of an anion-exchange viscose fibre by graft polymerization to cellulose during the spinning process

Conclusions The fundamental possibility of modifying viscose fibres by graft polymerization of DVPS by a continuous method during the course of spinning has been demonstrated.The fibre obtained has anion-exchange properties and has satisfactory sorptive and physico-mechanical indices, comparable with those of TsM-A2 fibre.Translated from Khimicheskie Volokna, No. 2, pp. 28–30, March–April, 1987.     

Fabrication and optical characterization of poly(2,5‐di‐n‐butoxyphenylene) nanofibril arrays

Anodic aluminum oxide (AAO) membrane can be used as template for the synthesized nanostructures. In this article, we have prepared the AAO membrane by using electrooxidation of aluminum substrate in phosphoric acid, and fabricated poly(2,5‐di‐n‐butoxyphenylene) (BuO–PPP) nanofibril arrays by oxidative coupling polymerization of 1,4‐di‐n‐butoxybenzene (DBB) within the pores of the AAO template membrane. The detailed molecular structure of the polymer nanofibrils was characterized by using infrared and ¹H nuclear magnetic resonance spectra, and estimated to consist of almost equal fractions of 1,4‐ and 1,3‐ linkages. We have used transmission electron microscopy, scanning electron microscopy, and atom force microscopy to confirm the morphologies and images of the AAO template membrane and the fabricated nanometer scale of BuO–PPP nanofibril arrays. The experimental results demonstrated that the pores of the AAO membrane were regular and uniform, and parallel each other, and the BuO–PPP chains in the narrowest template‐synthesized nanofibrils were oriented parallel to the porous axes of the AAO membrane and perpendicular to the surface of the aluminum substrate. The polymer chain orientation was partially responsible for the enhanced conductivity. The ultraviolet absorption spectrum of the BuO–PPP nanofibril arrays shown that the polymer contains a better extended π‐conjugation system along poly‐(p‐phenylene) backbone, which resulted in longer wavelength shift of the absorption band, the absorption maxima were located at 258 nm (E₁ absorption band) and 332 nm (E₂ absorption band), respectively. Photoluminescence spectrum of the BuO–PPP nanofibril arrays exhibited a blue emission. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 425–430, 2004     

Anisotropy in the strength of cellulosic fibres

Conclusions It is proposed to use the equation of a lemniscate, or the Cassini curve, to determine the destructive stress at break for cellulose films in any direction. Thereupon, to determine , it is necessary to know the destructive stress along two basic directions (₀ and ₉₀).To obtain cellulosic films which are isotropic in plane, a necessary and sufficient condition is ₀=₉₀.Translated from Khimicheskie Volokna, No. 6, pp. 34–35, November–December, 1987.     

Supported Alumina Members by an in-Situ Sol–Gel Method

Alumina membranes were prepared using a sol–gel process. Thin gel layers were grown onto porous alumina support tubes by using the permeation of water through the tube to control the rate of hydrolysis. Optimum coating conditions were found to be an ASB to 2-propanol volume ratio of 1:25, coating times between 10 and 15 s, and partial drying times between 2.5 and 3 min, depending on whether the water was flowing in the tube or stored in the tube. The coatings remained crack-free and adherent when fired to 800°C.     

Refractories with a Boron nitride base

Conclusions A technique for the reaction sintering of a new refractory made of 82–83% boron nitride and 17–18% graphite has been developed.The refractory possesses high specific resistance up to 1500–1800°, a low coefficient of thermal expansion, a moderative evaporation rate in a vacuum, satisfactory strength and machinability, as well as high resistance to cryolite-aluminum melts, borate, chloride and also silicide and boron-silicon alloy melts (at between 900 and 2000°).     

采用JFM7201的北斗基带数字接收通道设计

北斗卫星导航定位系统是我国自行研制的,它采用直接序列扩频技术,只有当扩频码完全同步之后才能解调出信息码。因此,对于扩频码的捕获和跟踪就成为一个非常重要的环节,基带信号处理就可实现这样的功能。JFM7201芯片是一款基带信号处理芯片,与相关的处理器配合,可以实现信号的捕获、跟踪、解调以及输出位置、速度和时间的相关信息,是北斗接收机一种比较好的实现方式。     

软件定义网络分布式控制平台的研究与实现

在软件定义网络可以弥补传统分布式网络体系结构不足,有效应用的情况下,软件定义网络自身所存在的弊端,对其应用效果有一定影响。对此,加强软件定义网络分布式控制平台和研究和实现是非常必要的。利用此平台对软件定义网络有效控制和优化,提高软件定义网络应用水平。本文就软件定义网络分布式控制平台进行分析和研究,希望可以建成此平台。     

基于STM32的步行者航位推算装置设计

基于便携性与实用性考虑,提出一种新的步行者航位推算装置设计。使用三维加速度计与电子罗盘集成芯片LSM303DLHC和陀螺仪集成芯片MPU3050对步行者的实时运动信息进行采集,采用具有ARM Cortex-M3内核的STM32F103RBT6单片机收集传感器数据并对数据进行航位推算处理,将步行者航迹信息显示于TFTLCD上。实验证明,该装置具有较高的推算精度,能满足实际应用需求。     

计算机局域网网络的安全现状与对策分析

在现代企业中,随着办公自动化进程的不断深入,计算机局域网得到了普遍的发展,在很大程度上提高了工作效率。但是局域网技术在为工作带来便利的同时,安全问题也是比较严重的。本文主要探究的是计算机局域网网络的安全现状,并提出了相应的对策和解决措施。