Binding of several heavy metal ions by polyaspartyl polymers and their application to some Chinese herbal medicines

Water‐insoluble polyaspartyl polymers were synthesized by using water as medium instead of organic medium. Taking Ca²⁺ as a reference, the binding of several heavy‐metal ions, including Pb²⁺, Cd²⁺, Hg²⁺, Cr³⁺, Cu²⁺, and Mn²⁺, by polyaspartyl polymers was studied. The experimental results revealed that polyaspartate is an excellent binding agent for the investigated heavy‐metal ions. These cation ions were bound to polyaspartate polymer by the same mechanism as Pb²⁺, which can be explained by ion exchange model. Since polyaspartate has a protein‐resembling structure that is sensitive to trace heavy metal, it was used to remove some trace heavy‐metal elements in Chinese herbal medicines. It was found that polyaspartate material was an effective agent for the removal of Pb²⁺, Cd²⁺, and Hg²⁺ ions from glycyrrhizin, angelica, and gynostemma pentaphyllum. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

国际泥沙计划案例研究综述

在全球变化等多种因素的影响下,许多流域的泥沙问题严重,泥沙管理的重要性日益突出。通过对联合国教科文组织国际泥沙计划所开展的案例研究进行综述,认识到自然地理特征、社会经济条件、水利工程建设对流域产沙、输沙和水资源利用有重要影响。土壤侵蚀加速、水库淤积、下游输沙量减少和生态平衡破坏是目前全球各大流域面临的主要问题。综合各项案例,研究泥沙管理技术,提出流域综合泥沙管理的策略,包括水库淤积管理、推移质泥沙管理、土地管理和水土保持等技术手段,以及法律、行政和组织措施。     

多孔陶瓷的制备和应用研究进展

由于多孔陶瓷材料在化学工业、信息通讯、生物技术、环境能源等领域的广泛应用，近年来倍受关注。综述了多孔陶瓷的几种制备方法，并将多孔陶瓷在过滤材料、催化剂载体、生物材料、吸音隔热材料、敏感材料上的应用情况作了简要说明，充分肯定了多孔陶瓷对人类社会的作用。     

由双酚A结晶母液的裂解产物合成双酚A反应过程研究

对反应过程所需催化剂种类及其各影响因素进行了考察。研究表明，大孔强酸性离子交换树脂可替代无机酸作为催化剂用于该反应，其中以未经硫基化处理者为佳；原料中水分的存在不利于产物收率和质量，应控制水的质量分数在1％以下。本研究确定的较佳工艺条件为反应温度65℃，停留时间15min、苯酚／对－异丙烯基苯酚摩尔比20，对应的反应收率为98．5％。对双酚A副产物的处理提供了有效方法。     

苯乙烯/丙烯酸丁酯微乳液共聚物链段分布的研究

以苯乙烯/丙烯酸丁酯(St/BA)为共聚单体,进行了微乳液聚合反应,测定了共聚物组成和共聚单体的竞聚率。由竞聚率计算了共聚物分子的链段分布,分析了共聚物分子的微观结构。     

Scaled Jacobian transpose based control for robotic manipulators

This paper presents a scaled Jacobian transpose based control method for robotic manipulators as a modification of a conventional Jacobian transpose based method. The proposed method has several advantages such as it shows faster convergence and better tracking performance than the conventional method, furthermore, it does not have any singularity problem similar to the conventional method. The scaled Jacobian transpose is obtained by collecting each pseudoinverse of the column vector of the Jacobian matrix. The proposed method performs a given task well under singular configurations while minimizing the task error. Finally, a few comparative studies with the conventional method are provided to show the effectiveness of the proposed method through simulations.     

Multidisciplinary design modeling and optimizationfor satellite with maneuver capability

According to the mission of a satellite with maneuver capability, the collaborative optimization (CO) method was introduced for the satellite system design, and the related multidisciplinary design optimization (MDO) model was established. The possessing and needed velocity increments Δv and Δv _{n e e d} were taken as the measurement of maneuvering capability of the studied satellite, which were then combined with total mass of the satellite to form the optimization objective in the systematic level of the MDO problem. The design variables and constraints of the MDO problem dealt with disciplines or subsystems as guidance, navigation and control (GNC), power, and structure, and corresponding engineering analysis models were also built. A program system to solve the MDO problem wasdeveloped by integrating a non-nested CO method, the commercial and user-supplied codes on framework software iSIGHT. The result showed that the satellite performance could be obviously improved, which also indicates MDO technique is feasible and effective for the spacecraft design problem. The modeling and optimization procedure of the work can be referred for further research and engineering design.     

FO-CA:一种基于距离差异度组合权重的多属性数据分类方法

为了解决多属性数据分类问题,提出了一种基于模糊优选模型与聚类分析的分类方法(FO-CA)。首先由模糊优选模型得到有序综合指标数据集,其中在权重阶段提出了距离差异度并以此为依据构建了一种组合主客观权重的赋权方法;然后采用聚类分析将有序综合指标数据集聚类为几个簇进而分类;最后选取UCI中的Iris、Wine和Ruspini 3个数据集进行仿真实验。实验结果表明,该分类方法相比模糊优选方法及K-Means算法能获得更好的分类结果,对决策者有一定的参考价值。     

Thermal properties measurements of renatured gelatin using conventional and temperature modulated differential scanning calorimetry

The thermal properties of amorphous gelatin films and gelatin films with renatured structural order were measured by using conventional and temperature modulated differential scanning calorimetry (DSC). Different amounts of gelatin structural order associated with a melting enthalpic change in the DSC measurement were prepared based on different gelatin drying conditions. Two consecutive heating and cooling DSC measurements on the gelatin films showed that there was no change in the glass‐transition temperature (T_g) for the amorphous gelatin but there was a decrease in the T_g for the structural gelatin on the second DSC scan. This decrease was attributed to the plasticizing effect from the release of originally hydrogen‐bonded water associated with the structural gelatin. In addition, a reversing endotherm observed upon melting of the structural gelatin during a temperature modulated DSC measurement indicated that the transition of bound water to free water occurred as the partial triple‐helix gelatin melted. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1795–1801, 2006     

微分进化算法整数编码策略实现研究

微分进化算法（DE）是模仿生物进化“优胜劣汰、适者生存”的一种随机优化算法,具有简单、快速、鲁棒性好等特点,已经得到广泛应用.通过运用微分进化算法的整数编码方法,在整数空间中求解,并在实数空间中计算解的适应度.使用测试函数对程序进行测试,证明了整数编码解对空间个体中寻优的快速性、准确性.