全文获取类型
收费全文 | 12376篇 |
免费 | 1162篇 |
国内免费 | 574篇 |
专业分类
电工技术 | 979篇 |
技术理论 | 2篇 |
综合类 | 822篇 |
化学工业 | 2104篇 |
金属工艺 | 701篇 |
机械仪表 | 756篇 |
建筑科学 | 800篇 |
矿业工程 | 304篇 |
能源动力 | 324篇 |
轻工业 | 837篇 |
水利工程 | 228篇 |
石油天然气 | 690篇 |
武器工业 | 112篇 |
无线电 | 1423篇 |
一般工业技术 | 1572篇 |
冶金工业 | 648篇 |
原子能技术 | 179篇 |
自动化技术 | 1631篇 |
出版年
2024年 | 81篇 |
2023年 | 310篇 |
2022年 | 461篇 |
2021年 | 664篇 |
2020年 | 480篇 |
2019年 | 373篇 |
2018年 | 392篇 |
2017年 | 431篇 |
2016年 | 379篇 |
2015年 | 479篇 |
2014年 | 625篇 |
2013年 | 686篇 |
2012年 | 714篇 |
2011年 | 852篇 |
2010年 | 660篇 |
2009年 | 651篇 |
2008年 | 701篇 |
2007年 | 706篇 |
2006年 | 659篇 |
2005年 | 570篇 |
2004年 | 399篇 |
2003年 | 390篇 |
2002年 | 441篇 |
2001年 | 366篇 |
2000年 | 257篇 |
1999年 | 220篇 |
1998年 | 189篇 |
1997年 | 169篇 |
1996年 | 170篇 |
1995年 | 146篇 |
1994年 | 131篇 |
1993年 | 71篇 |
1992年 | 73篇 |
1991年 | 41篇 |
1990年 | 25篇 |
1989年 | 36篇 |
1988年 | 27篇 |
1987年 | 19篇 |
1986年 | 12篇 |
1985年 | 11篇 |
1984年 | 7篇 |
1983年 | 6篇 |
1982年 | 8篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1976年 | 6篇 |
1975年 | 2篇 |
1967年 | 2篇 |
1959年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 1 毫秒
71.
Polyaspartate is an excellent Pb2+‐binding agent in comparison with some polyaspartamide derivatives with different side chains, in that it possesses a higher Pb2+ uptake and a lower Pb2+ equilibrium concentration. Equilibrium sorption data for Pb2+ on polyaspartate can be well fitted with the Freundlich and Langmuir models. Experimental results show that a crosslinked polyaspartate hydrogel is superior to poly(acrylic acid)‐based resins and polystyrene‐based chelating resins. IR spectra and X‐ray photoelectron spectra reveal that the polyaspartate hydrogel binds Pb2+ by both an ion‐exchange mechanism and a chelating mechanism. The polyaspartate hydrogel is also an effective agent for the removal of Pb2+ from glycyrrhizin. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 2215–2220, 2005 相似文献
72.
73.
3‐Chlorothiophene (CT) was electrochemically polymerized in mixed electrolytes of a boron trifluoride diethyl etherate solution containing 0–20% (by volume) sulfuric acid. The oxidation potentials of the monomer in these media were measured to be only 1.06–1.31 V (vs Ag/AgCl). These values were much lower than that of CT in acetonitrile and 0.1 mol/L (Bu)4NBF4 (1.92 V vs Ag/AgCl). Poly(3‐chlorothiophene) (PCT) films with conductivities of 0.1–2 S cm?1 were obtained. The structure, morphology, and electrochemical behavior of the PCT films also were investigated. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 502–509, 2003 相似文献
74.
75.
The effects of the molecular weights (molecular weight of polystyrene, Mw,PS, varying from 2.9 to 129 k) on the surface morphologies of spin-coated and annealed polystyrene/poly (methyl methacrylate) (PS/PMMA=50/50, w/w) blend films were investigated by atomic force microscopy and X-ray photoelectron spectroscopy. For the spin-coated films, when the Mw,PS varied from 2.9 to 129 k, three different kinds of surface morphologies (a nanophase-separated morphology, a PMMA cellular or network-like morphology whose meshes filled with PS, a sea-island like morphology) were observed and their formation mechanisms are discussed, respectively. Upon annealing, two different morphology-evolution processes were observed. It is found that a upper PS-rich phase layer is formed when Mw,PS<4 k, and this behavior is mainly attributed to the low interfacial tension between PS and PMMA component. When Mw,PS>4 k, the PS-rich phase forms droplets on top of the PMMA-rich phase layer which wets the SiOx substrate. These results indicate that the surface morphology of the polymer blend films can be controlled by the polymer molecular weight and annealing conditions. 相似文献
76.
Through the addition of N‐hydroxymethyl acrylamide as a potential crosslinker, water‐absorptive blend fibers of copoly(acrylic acid–acrylamide) and poly(vinyl alcohol) with three‐dimensional network structures were prepared with heat‐crosslinking technology after fiber formation. Fourier transform infrared, scanning electron microscopy, dynamic mechanical analysis, and thermogravimetry were used to analyze the structures and properties of the fibers. The tensile behavior and absorbent capacities of the fibers were also studied. The results showed that there were lots of chemical crosslinking points in the fibers, the compatibility of copoly(acrylic acid–acrylamide) and poly(vinyl alcohol) was perfect, and the tensile properties of the fibers could be improved effectively through stretching in a vapor bath. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3353–3357, 2006 相似文献
77.
The effects of the glass‐bead content and size on the nonisothermal crystallization behavior of polypropylene (PP)/glass‐bead blends were studied with differential scanning calorimetry. The degree of crystallinity decreased with the addition of glass bead, and the crystallization temperature of the blends was marginally higher than that of pure PP at various cooling rates. Furthermore, the half‐time for crystallization decreased with an increase in the glass‐bead content or particle size, implying the nucleating role of the glass beads. The nonisothermal crystallization data were analyzed with the methods of Avrami, Ozawa, and Mo. The validity of various kinetic models for the nonisothermal crystallization process of PP/glass‐bead blends was examined. The approach developed by Mo successfully described the nonisothermal crystallization behavior of PP and PP/glass‐bead blends. Finally, the activation energy for the nonisothermal crystallization of pure PP and PP/glass‐bead blends based on the Kissinger method was evaluated. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 2026–2033, 2006 相似文献
78.
79.
Ji‐Sun Im Ju‐Hyung Lee Seung‐Kook An Ki‐Won Song Nam‐Ju Jo Jang‐Oo Lee Kohji Yoshinaga 《应用聚合物科学杂志》2006,100(3):2053-2061
A new type of polyimide/silica (PI/SiO2) hybrid composite films was prepared by blending polymer‐modified colloidal silica with the semiflexible polyimide. Polyimide was solution‐imidized at higher temperature than the glass transition temperature (Tg) using 3,3′,4,4′‐biphenyltetracarboxylic dianhydride (BPDA) and 4,4′‐diaminodiphenyl ether (ODA). The morphological observation on the prepared hybrid films by scanning electron microscopy (SEM) pointed to the existence of miscible organic–inorganic phase, which resulted in improved mechanical properties compared with pure PI. The incorporation of the silica structures in the PI matrix also increased both Tg and thermal stability of the resulting films. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2053–2061, 2006 相似文献
80.
针对Sine波纹腹板梁结构,通过设计其初始振幅缺陷,控制不同波形阶数下波纹梁的失稳模态,引导上下翼板按预期渐进、稳定、可重复的压溃变形模式发展.采用Abaqus/Explicit中的显式动力学方法数值模拟初始振幅缺陷与比吸能(Specific Energy Absorption,SEA)的关系.通过对比低阶、中阶和高阶波形的载荷-位移曲线说明波形阶数对吸能特性和失稳控制的影响.结果表明:对于给定的波形阶数,存在初始振幅缺陷的临界值使Sine波纹腹板梁结构达到预期的临界失稳状态,同时SEA最大;初始振幅缺陷越大,失稳控制越容易,但吸能效果随之降低. 相似文献