Copolymeric photoinitiators containing in‐chain thioxanthone and coinitiator amine for photopolymerization

Two kinds of copolymeric macromolecular photoinitiator, PTXPM and PTXPC, were prepared by introducing methylacryloyl or cinnamoyl groups to the side chain of PTXP. The photopolymerizations of poly(propylene glycol)diacrylate (PPGDA) and trimethylolpropane triacrylate (TMPTA), using PTXPM and PTXPC as photoinitiators, were studied by photo‐DSC. PTXPM and PTXPC have UV–vis spectra similar to that of PTXP with blue‐shift absorption maxima. The photopolymerization behavior of TMPTA, initiated by three photoinitiators, appears similar to that of PPGDA. Compared with PTXP and PTXPC, PTXPM gives higher polymerization rate and final conversion, in photopolymerization of PPGDA and TMPTA, which shows that the introduction of methyl acrylate to the PTXP chain has a greater effect on photopolymerization of PPGDA and TMPTA than that of cinnamoyl acrylate. The polymerization rate and final conversion, for photopolymerization of PPDGA initiated by PTXP, can be more effectively increased by the introduction of methyl acrylate group to the PTXP chain, than are those for TMPTA. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2395–2400, 2004     

甲基丙烯酸缩水甘油酯对大豆蛋白塑料改性作用研究

用模压的方法制备了甲基丙烯酸缩水甘油酯(GMA)改性大豆分离蛋白质(SPI)塑料。表征了GMA改性SPI塑料的力学性能、耐水性,并分析了GMA与SPI之间的相互作用。结果表明GMA在模压过程中,环氧基与蛋白质分子间发生接枝和交联反应,同时自聚,在GMA含量较低时可以同时对SPI塑料起到增强和增塑作用,但是随着GMA含量增加,交联作用增强,塑料的断裂伸长率下降。     

Polymer electrolytes from PEO and novel quaternary ammonium iodides for dye-sensitized solar cells

Polymer electrolytes were prepared by blending high molecular weight poly(ethylene oxide) (PEO) and a series of novel quaternary ammonium iodides, the polysiloxanes with oligo(oxyethylene) side chains and quaternary ammonium groups. X-ray diffraction (XRD) measurements ensured relatively low crystallinity when the quaternary ammonium iodides were incorporated into the PEO host. The ionic conductivity of these complexes was improved with the addition of plasticizers. The improvement in the ionic conductivity was determined by the polarity, viscosity and amounts of plasticizers. A plasticized electrolyte containing the novel quaternary ammonium iodide was successfully used in fabricating a quasi-solid-state dye-sensitized solar cell for the first time. The fill factor and energy conversion efficiency of the cell were calculated to be 0.68 and 1.39%, respectively.     

非齐次边界条件定解问题的一种齐次化函数形式

通过对非齐次边界条件的定解问题的讨论,引出了本文的论题,对非齐次边界条件定解问题的边界条件齐次化函数提出了一种比较一般和标准的形式,并提出了一个定理.对该定理进行了证明,证明了它的正确性.利用该定理可以非常方便地求解关于非齐次边界条件定解问题的齐次化函数.     

企业创新供应链收益共享契约模型研究

建立基于收益共享契约供应链模型,研究企业创新对供应链的影响,指出企业创新时供应链失调,分析供应链失调原因,提出供应链契约扩展模型,在企业创新时能实现供应链协调.     

二元地质条件下内支撑与土钉墙支护设计问题

结合某基坑工程的设计实践,对在基坑开挖深度内有土层和岩层、且岩层内存在软弱夹层的二元地质条件下采用内支撑和复合土钉墙组合形式支护时存在的问题进行了详细分析,主要包括土压力的计算模式、钢管桩下局部地基承载力的验算、刚-揉性组合支护型式的交接处刚度协调、内撑立柱的约束状态对内支撑稳定性的影响等问题,通过对这些问题的分析,得到在设计类似基坑支护形式时需要注意的问题,并提出解决问题的措施,为同类工程提供参考。     

基于正交设计的黄池沟退水道弯道体型优化的数值模拟分析

为探求黄池沟退水道弯道的合理体型,采用正交设计与数值模拟相结合的方法研究了体型参数对弯道水流的影响。选取弯道宽度、弯道曲率半径、纵向坡度3个主要影响参数按正交试验设计,确定了9组正交试验方案,利用经水工模型试验结果验证的数学模型对正交试验方案进行模拟,分析了体型参数对弯道及下游陡坡段横向水位差的影响。结果表明,3个体型参数影响作用由大到小依次为纵向坡度、弯道宽度和弯道曲率半径;坡度为显著影响因素,且平坡最佳,弯道曲率半径和弯道宽度影响不显著,据此推荐合理体型参数为坡度取0,弯道宽度和弯道曲率半径采用原设计值。     

微服务在智慧校园建设中的应用

智慧校园建设利用信息化手段和工具,以服务为向导,将校园的各项资源、管理及服务流程数字化,以提高服务质量和数据质量为目标,采用基于业务流程重构的微服务与微应用,将普遍存在于部门间的业务流程断层进行再造,解决智慧校园建设中数据更新不及时、不完整和不唯一等问题.文章以学校的人事职称评审服务为例,介绍了微服务在智慧校园建设中的应用.     

风电机组功率曲线建模方法对比研究

风电机组功率曲线表征了风机的实际运行状态,可以为风电机组故障诊断、功率预测等工作提供依据.而风电机组的标准功率曲线一般是由制造商在特定的测试环境下给出的,与实际运行曲线之间往往存在较大差异.为此研究了四种功率曲线拟合方法,并以多项式拟合法为基础展开,介绍了局部加权多项式拟合法,并说明了其相较于多项式拟合的优点.此外还介绍了三次样条和三次B样条曲线拟合法,为曲线拟合提供了更高的精度并引入了灵活性.利用河北某风电场SCADA系统记录的16号风机的实测数据对各种方法的拟合效果进行了分析,结果表明三次B样条拟合法拟合精度最高,可以将其应用于功率曲线的建模工作中.     

基于显著性的遥感图像舰船目标检测

舰船作为海洋信息感知中的重要目标,其检测在军舰探测、精确制导等军用领域以及海面搜救、渔船监测等民用领域具有极其重要的战略意义.海洋遥感图像受云雾、风浪、海杂波和光照等干扰使得舰船检测具有挑战性.根据可见光遥感图像舰船目标检测特点提出粗检测和细鉴别相结合的技术路线.先基于视觉显著性的谱残差法对图像进行增强以提取目标候选区域,后根据舰船与干扰因素差异采用舰船方向梯度直方图特征对目标候选区域进行鉴别,提取真正的舰船目标.实验结果表明,上述算法舰船检测率高,对光照、海杂波干扰具有一定程度的鲁棒性,且能有效剔除碎云岛屿等干扰物,显著降低虚警率.