Studies on the critical temperature of thermal explosion for 3-Nitro-1,2,4-triazol-5-one (NTO) and its salts

The critical temperature of thermal explosion for 3-nitro-1,2,4-triazol-5-one (NTO) and its ethylenediammonium salt (ENTO), potassium salt (KNTO), copper salt (CuNTO) and lead salt (PbNTO) were obtained using the stationary theory of thermal explosion, the calculation formula of estimating the critical temperature of thermal explosion under non-isothermal DSC condition, and the determination method for the critical temperature of thermal explosion of small-scale solid explosive and its data treatment method. The results of the four methods are agreeable to each other, whose differences are within 5%. The results indicate that the heat-resistance ability of NTO and its salts and of the common explosives, cyclotetramethylenetetranitramine (HMX), cyclotrimethylenetrinitramine (RDX), pentaerythritoltetranitrate (PETN) and tetryl decreases in the order HMX > NTO > ENTO > KNTO > RDX > PETN > tetryl > PbNTO > CuNTO.     

大、小飞扬草中锌铁锰微量元素的测定

目的:测定大、小飞扬草中Zn、Fe、Mn三种微量元素的含量。方法:硝酸和高氯酸(4+1)分解样品,火焰原子吸收光谱法(FAAS)测定。结果:大、小飞扬草中三种微量元素存在差异,其中大飞扬草中元素含量大小为:Fe>Mn>Zn,小飞扬草中上述元素含量为:Fe>Zn>Mn。回收率在97.0%~106.0%之间,RSD<2.1%。结论:大、小飞扬草中三种微量元素含量的差异测定可为进一步研究其药效与有关微量元素关系提供一定参考。     

Growth of silicon nitride films by bombarding amorphous silicon with N ions: MD simulation

In this study, the molecular dynamics simulation method was employed to investigate the growth of silicon nitride films by using N⁺ ions, with energies of 50, 100, 150 and 200 eV, to bombard an amorphous silicon surface at 300 K. After an initial period of N⁺ bombardment, saturation of the number of N atoms deposited on the surface is observed, which is in agreement with experiments. During subsequent steady state deposition, a balance between uptake of N by the surface and sputtering of previously deposited N is established. The Si(N_x) (x = 1-4) and N(Si_y) (y = 1-3) bond configurations in the grown films are analyzed.     

以环保约束性指标优化钢铁工业布局

针对中国钢铁工业布局中存在的＂北重南轻＂、＂东多西少＂和城市型钢铁布局较多等问题,指出现有的钢铁工业布局调整尚不能满足中国区域大气污染防治的要求。系统梳理中国近年来颁布的环境空气质量标准、钢铁工业污染物排放标准和环境保护规划方面针对钢铁工业提出的新要求,指出这些新标准、新要求为钢铁工业优化工业布局形成了重要环境保护约束性指标。同时结合这些约束性指标提出了执行特别排放限值、实行污染物减量置换、提高排污费标准、开展排污权交易和鼓励先进技术应用等推进钢铁工业布局优化的政策措施。     

维生素D对60Co辐射损伤小鼠的保护作用

为研究维生素D对基因组稳定性作用,观察维生素 D 对60Co 辐射损伤小鼠外周血象、骨髓嗜多染红细胞(Polychromatic erythrocytes,PCE)微核率和骨髓有核细胞(Bone marrow cells,BMC)细胞周期和凋亡的影响.使用60Co辐射制备损伤模型,维生素D制剂(阿法骨化醇胶丸)灌胃,观察外周血象、PCE 微核率(Giemsa法)的变化,并用流式细胞仪分析BMC细胞周期和凋亡情况.结果显示,小鼠辐射后外周血白细胞、血小板数显著下降,骨髓造血损伤,染色体损伤,而维生素D能在一定程度上促进外周血象的恢复,抑制微核率的发生.流式细胞仪分析表明,辐射后 24h,维生素D干预组,BMC的G0/G1期细胞比例较辐射损伤组明显减少,G2期和S期细胞较辐照组增多.这说明维生素D可能成为-个新的辐射防护剂.     

浅谈水质稳定剂与高频水处理仪

目前中小型化肥厂普遍采用水质稳定剂处理补充水和循环水，尽管提高了水的利用率，却仍有少量污水排放；使用高频水处理仪技术，不但水质达标，且经济合理。     

Effect of rubber particle modification on properties of rubberized concrete

To improve the combination of cement matrix and waste tire rubber particles in concrete, the rubber particles were treated with acrylic acid（ACA） and polyethylene glycol（PEG） for grafting hydrophilic groups on their surfaces. The X-Ray photoelectron spectroscopy（XPS） and surface contact angle were used to characterize the hydrophilicity and surface functional group of rubber particles. The effect of rubber particle modifi cation on fresh/hardened properties of rubberized concrete was studied. The experimental results show that the contact angle between rubber particle surface and water decreases when rubber particle is modifi ed. Compared with the unmodifi ed rubberized concrete（RC）, the unit weight of modifi ed rubberized concrete（MRC） changes slightly. However, the slump, air-entrainment, compressive strength, flexural strength, and impact performance of MRC are obviously improved. Under good condition of slump, the water-cement ratio of the MRC can be reduced from 0.4 to 0.38. And the compressive strength and fl exural strength of the MRC（10% rubber particle content） can be increased by 25.9% and 26.4%, respectively.     

大型空调系统生命周期评价与能源利用评价模型

基于西安咸阳国际机场货运中心空调系统,利用生命周期理论和层次分析法针对能源高效利用途径进行了研究。针对生命周期方法和层次分析法应用于建筑能源进行了深入分析,结合实际案例数据进行了生命周期清单分析,数据来源与所提模型紧密结合,基于层次分析法框架性模型,以空调工程各种资源的消耗值和各种环境影响潜值分析为例,量化剖析了如何利用全生命周期影响评价对耗能项目进行评价。结合案例数据的生命周期评价提出了能源利用评价层次模型,并针对模型给出了从全生命周期角度调整建立能源利用过程监控与评价等建议。     

Two Modes and Criterion of Brittle Fracture

The plastic zone at the tip of the flaw (including acute cark and common notch) was investigated. Forthe notch specimen, a formula of toughness K was proposed, and its physical meaning was emphasized.Twomodes of brittle fracture was identified and the evaluating criterion was established.     

以氯代烃为第三组分的稀土定向聚合催化剂——Ⅱ.顺丁橡胶的结构与性能

研究了Nd(naph)_3-Al(i-Bu)_2H-t-BuCl(或allyl-Cl)催化体系制得的顺丁橡胶(BR)的结构与性能。结果表明,[η]=2.7～3.7dL/g,分子量分散指数小于4,[η]<1低分子级分含量小于50％,顺式-1,4含量大于或等于95％时,其生胶、混炼胶和硫化胶的性能均良好,硫化胶的综合性能与一般稀土体系BR和镍系BR相当甚至超过。