93.
Gold nanoparticles (AuNPs) of different sizes were synthesized into a crosslinked network of polyacrylamide (PAAm) microgels. PAAm was prepared by means of semicontinuous inverse heterophase polymerization under monomer‐starving conditions with a
z‐average particle size of 384 ± 18 nm. AuNPs with controlled size were obtained by a reduction reaction of Au
+3 to Au
0 from a gold(III) chloride trihydrate (HAuCl
4) solution inside microgel the crosslinked network (AuNP‐PAAm). The reduction reaction was verified for 2 h by ultraviolet–visible spectroscopy (UV–vis). AuNP–PAAm exhibited a particle size between 288 ± 12 and 230 ± 15 nm at HAuCl
4 concentrations of 0.4 and 1.3 m
M, respectively. The AuNP–PAAms were observed by transmission electron microscopy, and their sizes were determined to be 19 ± 2 nm (1.3 m
M) and 17 ± 2 nm (1.1 m
M). With UV–vis spectroscopy, we detected the formation of AuNPs at a wavelength of 552 nm, and with X‐ray diffraction analysis, we proved that the crystal arrangement was face‐centered cubic. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 ,
133, 43560.
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