Effects of Dissimilar Alumina Particulates on Microstructure and Properties of Cold-Sprayed Alumina/A380 Composite Coatings

In this study,alumina/A380 composite coatings were fabricated by cold spray.The influence of alumina particulates' morphology(spherical and irregular) and content on the deposition behavior of the coatings(including surface roughness,surface residual stress,cross-sectional microstructure and microhardness) was investigated.Results revealed that the spherical alumina mainly shows micro-tamping effect during deposition,which result in remarkable low surface roughness and porosity of the coatings.In addition,very low deposition efficiency and good interfacial bonding between the coating and the substrate were achieved.For irregular alumina particles,the embedding of ceramic particulates in the coating was dominant during deposition process,resulting in high retention in the final deposit.However,it showed limited influence on porosity,surface roughness and interfacial bonding of the deposit.The coatings containing irregular alumina particulates exhibited much higher microhardness than those containing spherical alumina due to the higher load-bearing capacity of deposited alumina.     

金属零件表面改性的喷丸强化技术

传统的机械喷丸工艺在工业界已经得到广泛的应用。随着激光技术的发展,出现了一种新的加工工艺——激光喷丸。它们都能改善金属零件表面的机械性能,尤其是在表面产生压缩应力,使零件的抗应力腐蚀等能力大为提高,从而延长零件的疲劳寿命。由于激光喷丸具有形成的残余压应力比机械喷丸深等优势,因而强化效果更佳。     

柠檬酸法制备热障涂层用La2Ce2O7粉体

以ZrO(NO3)2·2H2O、Ce(NO3)·6H2O和La2O3为原料,采用柠檬酸法制备了La2Ce2O7粉体,研究了pH值、乙二醇及柠檬酸用量、煅烧温度等工艺参数对La2Ce2O7粉体的影响。结果表明,采用该方法能够制备纯净的La2Ce2O7粉体,最佳实验条件是pH值为5,乙二醇、柠檬酸与金属离子的摩尔比分别是1.8和2,煅烧温度为400℃。     

Effects of distance between arc and heat sink on stress and distortion in DC-LSND welding technology

The characteristics of temperatures, stresses and strains fields have been studied numerically for a titanium alloy sheet welded with an improved gas tungsten arc welding method, in which a trailing spot heat sink is introduced to control the welding stress and distortion. The impinging jet model is employed to describe the internee heat transfer between the cooling media and the top suufuce of the workpiece. The influcnee of the distance between arc and heat sink is investigated. Results show that there is an ideal range of distance. Using the ideal distance, a low stress and no distortion welding structure can be derived.     

Si对MCrAlY涂层微观结构及性能的影响

本文制备了Si含量分别为0,2%及5%的CoCrAlSiY合金涂层,研究了Si元素的添加对合金粉末及涂层的组织、结构及性能的影响,初步探讨了Si元素对涂层高温性能的作用机理。研究结果表明：Si元素主要分布在涂层的β相中,通过影响β相的含量和分布对涂层的高温性能产生影响,Si推进了合金由内氧化向外氧化发生的过程,促进了保护性氧化膜的形成,但Si含量过高,会引起氧化膜的PBR值增加,氧化膜的应力变大,不利于涂层高温抗热震性能的提高。     

Cu/Ti复合添加对Nd2Fe14B/α-Fe纳米双相磁体磁性能和相分解的影响

用熔体快淬法制备了高性能纳米双相耦合Nd2Fe14B/α-Fe磁体，研究了Cu/Ti复合添加对Nd2Fe14B/α-Fe纳米双相磁体磁性能和相分解的影响，实验结果表明，Cu和Ti复合添加可提高快淬带的晶化温度，并且改变α－Fe相析出方式，α－Fe直接从TbCu7结构的亚稳相分解中析出，而不是从非晶相中析出，这有利于形成α－Fe相晶粒细小且均匀分布的微结构，其最优磁性能为Hc=384kA/m(4.8kOe),σ＝110Am^2/kg(110emu/g),(BH)max=120kJ/m^3(15MGOe)。     

Mo的替代对FeNbBCu软磁纳米晶合金磁谱的影响

本文研究了Fe82Nb7-xMoxB10Cu1(x=0,1,3,5）系列纲伙晶软磁合金中Mo的含量对磁导率谱（频率范围1kHz-1MHz)的影响，并用畴壁钉扎理论进行了解释，在磁谱中观测到随着Mo含量的增加，弛豫频率线性地上升，μ′随外加磁场幅度变化曲线表明其原因在于Mo的替代导致了钉扎场的增强。     

40Cu-W合金伪半固态触变模锻成形研究

采用基于粉末成形及半固态成形工艺而提出的伪半固态触变模锻成形工艺,成功制备出力学性能良好的40Cu-W合金筒形件,其中在成形温度为1 350 ℃、模锻压力为500 MPa工艺条件下制件的抗弯强度可达1 151 MPa,致密度达到98.38%.制件微观组织致密,分布比较均匀,低熔点的铜相包围在钨颗粒的周围,为制件性能的提高起到了重要作用.     

Mg-2.54Nd-0.26Zn-0.32Zr合金组织分析

采用XRD、DTA、OM和TEM研究Mg-2.54Nd-0.26Zn-0.32Zr合金铸态和热处理后的相组成、相变温度、微观组织.研究表明:Mg-2.54Nd-0.26Zn-0.32Zr合金铸态组织析出相主要是分布在晶界的块状Mg_(12)Nd稀土化合物,只有少量的片状和粒状Mg_(12)Nd相分布在晶界和晶内;T6处理后Mg_(12)Nd以相互交叉的片状形式团簇状分布在基体中,形成方式为点状析出相聚集而成.     

熔盐电解脱氧制备TiV合金

在CaCl_2熔盐中电解混合氧化物合成TiV合金.电解电压为3.0～3.2 V,电解温度为900 ℃,钛、钒混合氧化物作为阴极,石墨棒作为阳极.初步研究了电解原理.结果显示,反应过程是混合氧化物逐步还原生成组分可控的TiV合金.还原经历了从优先生成钛到逐步形成TiV合金的合金化历程.中间产物包括CaTiO_3、钒和钛的低价氧化物.