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991.
通过理论推导证明:在外扩散与化学抑制共存的非均相固定化酶促反应中,总有效系数η为外扩散有效系数ηdif和化学抑制有效系数ηch的乘积,并且分别小于相应的ηdif和ηch;从数学上解释了外扩散抑制和一般性化学抑制间所存在的“抗激发互交作用”。利用所得公式计算表明:底物浓度对外扩散与竞争性、非竞争性和反竞争性等不同化学抑制共存的非均相固定化酶促反应有明显不同的影响;扩散抑制均显著地影响非均相固定化酶促反应,使得反应体系的总有效系数随抑制作用的增加而明显减小,从而对这类反应有了更进一步的认识 相似文献
992.
Preparation of fluoroacrylate nanocopolymer by miniemulsion polymerization used in textile finishing
Latex based on fluoroacrylate (TAN) and other comonomers was prepared via miniemulsion polymerization in the presence of stearyl trimethyl ammonium chloride (STAC) and 2, 2′‐azobis (2‐amidinopropane) dihydrochloride (ABAP) as a water soluble initiator. Light transmittance studies demonstrated that the light transmittance of prepared emulsions increases with the amount of TAN, STAC, cosolvent DPM, and hydrophobe DM. Given suitable reaction temperature and quantities of TAN, STAC, DPM, and DM, a copolymer emulsion of fluoroacylate with a particle size of 50 nm was produced. The water repellency tested on polyester fabrics displayed greater effectiveness than that of commercial products with higher fluorine content. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 1466–1472, 2004 相似文献
993.
994.
Synthesis of Dimethyl Carbonate from Methanol and Carbon dioxide using Potassium Methoxide as Catalyst under Mild Conditions 总被引:2,自引:0,他引:2
Pd-supported on WO3–ZrO2 (W/Zr atomic ratio=0.2) calcined at 1073 K was found to be highly active and selective for gas-phase oxidation of ethylene to acetic acid in the presence of water at 423 K and 0.6 MPa. Contact time dependence demonstrated that acetic acid is formed via acetaldehyde formed by a Wacker-type reaction, not through ethanol by hydration of ethylene. 相似文献
995.
996.
介孔材料化学改性研究进展 总被引:1,自引:0,他引:1
综述了介孔材料化学改性目的,改性原理以及改性方法。介孔材料的化学改性包括对材料骨架的修饰以及对孔道表面的功能化,介孔材料表面自由硅醇键、双羟基硅醇踺是化学改性的基础,利用疏水性物质改性可以提高材料的水热稳定性,引入催化活性组分可以提高催化性能,利用具有特定官能团的硅烷偶连剂改性,则能够实现特殊的目的。详述了化学改性方法,包括元素取代法、共价键移植法和有机硅烷偶连法。元素取代法是对分子筛骨架结构的修饰,共价键移植法是一种不引起孔道结构破坏且非常有效的骨架修饰方法,对介孔材料表面进行有机硅烷偶连剂法修饰改性主要有两种途径:即共沉淀法和后移植法。 相似文献
997.
The esterification of the hydroxyl group of starch with DuPont Surlyn was considered as pretreatment method of starch before blending with polyolefins. In treating starch with Surlyn, two different raction conditions were taken to optimize reaction conditions. First, the esterification reaction was carried out in 110°C xylene with oleic acid as a catalyst. Second, the reaction out in a 90°C mixture of deionized water and xylene with ceric ammonium nitrate(CAN) as an initiator. Starch granules would be swollen above the gelatinization temperature in water. In both cases starch was midified by Surlyn to have good compatibility with low-density polyethylene (LDPE). The mechanical and theological properties were examined for blends of the treated starch and LDPE. This system may be one of the biodegradable polymer blends that sufficiently retain properties as a packaging film. 相似文献
998.
Joo Batista A. Silva Regina C. M. de Paula Judith P. A. Feitosa Eduardo Diogo Gurgel‐Filho Claudio Maniglia‐Ferreira Francisco Jose de Souza Filho 《应用聚合物科学杂志》2006,100(5):4082-4088
Gutta‐percha cone is the most widely used material for root canal filling. The in vivo aging of this cone focus on the degradation of its main organic component, trans‐1,4‐polyisoprene, was studied. Aged cones (25 samples) from 2 to 30 years of root canal filling were extracted from different patients in the occasion of retreatment by mechanical way. The information about the aging time was given by the patients. Gel‐permeation chromatography (GPC) and infrared spectroscopy (FTIR) were the analytical techniques used. Polyisoprene degrades with time of aging, but in a slow process. Decrease in polymer molar mass from 5.7 × 105 to 1.7 × 105 g/mol was observed in polyisoprene from cone after 30 years of root canal filling and inside a noninfected tooth. In tooth with caries and periodontal infection, the decrease in molar mass is higher (4.6 × 104 g/mol in cone with 10 years of aging). The production of carbonyl and hydroxyl groups in the aged material indicates that the process is oxidative, even in closed teeth. In these cases, the oxygen could be provided from tissue fluid. The degradation mechanism is complex and depends on many factors, besides time of root canal filling. The dental problem caused by the aging could be the production and migration of cytotoxic substances to periodontal ligament and the reduction on the canal sealing property due to the polymer weight loss. Both of them could contribute to the root canal treatment failure. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100:4082–4088, 2006 相似文献
999.
The amounts of isoflavones extracted from Korean soybean by various ultrasonic waves were compared using 60% aqueous ethanol
solution. The effect on extraction yield of variations in solvent composition, temperature, and extraction time was investigated.
The experimental results confirmed that ultrasonic waves are a desirable method to extract isoflavones from Korean soybean.
The highest yield of aglycone isoflavones was obtained by ultrasonic waves with a frequency of 20 KHz and an extraction time
of 10 min, which produced yields of glycoside and aglycone isoflavones three-fold greater than those by dipping method. 相似文献
1000.
Nucleation effects of 2,2′‐methylene‐bis (4,6‐di‐tert‐butylphenyl) phosphate metal salts as a nucleating agent for isotactic polypropylene (iPP) were investigated with differential scanning calorimeter and polarized optical microscope, and their effects on mechanical, optical, and heat resistance properties of iPP were also studied. The results showed that monovalent metal salts of substituted aromatic heterocyclic phosphate such as sodium salt, lithium salt, and potassium salt had a good performance. With 0.2 wt % of sodium salt, lithium salt, or potassium salt incorporated into iPP, the crystallization peak temperature of iPP could be increased by 13.5, 13.6, and 15.0°C, respectively; the mass fraction of crystallinity of iPP could be increased by about 5%; and crystallization rate was enhanced increasingly. Meanwhile the tensile strength and flexural modulus of iPP could be increased by about 10 and 30%, respectively, and the clarity and heat distortion temperature of iPP could also be improved significantly. But bivalent and trivalent metal salts of substituted aromatic heterocyclic phosphate had little effect on properties of iPP. Meanwhile the morphology study showed that the addition of monovalent sodium salt could decrease the spherulite size of iPP significantly. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 4868–4874, 2006 相似文献