位错芯重构缺陷对于Si中位错运动的影响

为了研究晶格常数不匹配的异质结SiGe/Si生长过程中低温缓冲层内缺陷对位错运动的影响,使用位错偶极子模型在Si晶体内建立了一对30°部分位错,和导致30°部分位错运动的弯结结构,以及位错芯重构缺陷(RD)与弯结组合而生成的弯结-RD结构.通过分子动力学模拟,使用Parrnello-Rahmman方法施加剪应力促使位错运动,得到了左右弯结-RD结构在迁移过程中的8种稳定构型,并且使用NEB方法和紧束缚势计算了纯弯结和弯结-RD迁移过程中势垒高度,发现弯结-RD的迁移能力要高于纯弯结结构.从模拟结果推断出,低温层生长技术中的Si低温缓冲层由于低温限制了重构缺陷的运动,减少其相遇发生湮灭的概率,从而使得更多的弯结能够与重构缺陷结合生成弯结-RD结构来提高30°部分位错的运动能力,由此释放异质结结构失配应力所需的位错密度会随之减小.     

Preparation and characterization of polyurethane microcapsules containing n‐octadecane with styrene‐maleic anhydride as a surfactant by interfacial polycondensation

A series of polyurethane microcapsules containing a phase change material (PCM) of n‐octadecane was successfully synthesized by an interfacial polymerization in aqueous styrene‐maleic anhydride (SMA) dispersion with diethylene triamine (DETA) as a chain extender reacting with toluene‐2,4‐diisocyanate (TDI). The average diameter of microPCMs is in the range of 5–10 μm under the stirring speed of 3000–4000 rpm. Optical and SEM morphologies of microPCMs had ensured that the shell was regularly fabricated with the influence of SMA. FTIR results confirmed that the shell material was polyurethane and the SMA chains associated on core material reacted with TDI forming a part of shell material. The shell thickness was decreasing in the range of 0.31–0.55 μm with the molar ratio of DETA/TDI from 0.84 to 1.35 and the weight of core material increasing from 40 to 80% (wt %). By controlling the weight ratio of PCM as 40, 50, 60, 70, and 80% in microPCMs, it was found using DSC that the T_m and T_c of microPCMs were in the range of 29.8–31.0^oC and 21.1–22.0°C and an obvious phase change had been achieved nearly the same temperature range of that of PCM. The results from release curves of microPCM samples prepared by 1.4, 1.7, and 2.0 g of SMA indicated the release properties were affected by the amount of the dispersant, which attributed to the emulsion effect and shell polymerization structure. The above results suggest that the shell structure of microPCMs can be controlled and the properties of microPCMs determined by shell will perform proper practical usage. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4996–5006, 2006     

A force modulation study on crystallization process in ferroelectric vinylidene fluoride and trifluoroethylene copolymer films

This paper introduces the Force Modulation technique to the study of crystallization process in ferroelectric vinylidene fluoride and trifluoroethylene copolymer films. Using this technique we have successfully visualized ferroelectric crystalline domains and observed that these ferroelectric domains grow out from amorphous phase, unite into strip-like structures, and finally congregate into a union. Force Modulation can weaken the influence of topography on imaging of ferroelectric domains, and reveal more details, which are difficult to be observed in topographical image.     

机载隐蔽式短波天线研究

给出了一种用于Y7—200A运输机的隐蔽式短波天线，该天线为位于飞机垂尾前缘的回线天线，与飞机的外形共形，不影响飞机的飞行性能。在利用传输线理论与缝隙天线理论对该天线进行分析的基础上，对输入阻抗、天线与天线调谐器结合后的天线效率进行了研究，给出了该天线与KHF950电台相配合的测试试验结果，该天线能够在2．5MHz到30MHZ范围内与KHF950电台良好调谐，表明这种天线完全可以用于Y7—200A型飞机，代替原有的钢索天线。这是在国产飞机上首次使用这种天线。     

箕状凹陷坡折带成因及对同生断层和沉积的控制,以南襄盆地南阳凹陷为例

坡折带是沉积地貌突变的古构造枢纽带。南襄盆地南阳凹陷南部控凹铲状正断层在非平面上滑动造成凹陷北部盖层缓坡弯折,构成盆内沉积区域的分界线,是同生断层集中发育和沉积相发生突变的地带。特定的坡折带类型揭示了同沉积断裂的活动和分布特征,制约着沉积物的分散过程和砂体堆积。在不同的盆地演化阶段,同生断层与沉积相带控制着不同圈闭类型的形成。      

丙烯酸高碳醇酯的合成

介绍了降凝剂中间体丙烯酸高碳醇酯的合成和产品分离提纯方法。考察了合成条件对酯化反应的影响，结果表明，在原料丙烯酸与十八醇摩尔比1．2：1，阻聚剂对苯二酚用量占原料总量1．5％，催化剂对甲苯磺酸用量占原料总量1．5％，反应温度80-86℃，回流反应时间6h条件下，酯化率最高达89％。产品分离提纯方法与传统分离方法比较，所需分离时间短，洗涤用水量少，而产品收率远高于传统分离方法，达95％以上。     

硬粒子对聚合物材料表面的冲击摩擦研究

冲击摩擦为接触面切向与法向冲量之比。用聚合物材料试件与弹簧钢片组成振动测试系统 ,硬粒子以一定入射角冲击试件水平面引起系统振动 ,接触冲量通过振幅反映出来 ,记录初始振幅值而计算出一个冲击过程的冲击摩擦因数。结果表明 ,当入射角α在 2 5°-60°变化时 ,冲击摩擦因数f从 0 .5降至 0 .2左右。文章同时分析讨论了摩擦对聚合物表面接触强度的影响。     

Control of structure and tack properties of acrylic pressure‐sensitive adhesives designed by a polymerization process

Free radical emulsion polymerization of methyl methacrylate (MMA) and 2‐ethylhexyl acrylate (EHA) results in the synthesis of pressure‐sensitive adhesives (PSAs) with good tack properties. Management of both the copolymer composition and the polymerization process allows one to control the behavior of the PSA. Semicontinuous (SC) processes create polymer particles whose instantaneous composition is close to that of the feed particle The SC Mixture process (continuous feeding with comonomer blends) affords nearly homogeneous latex particles and PSA films. The SC Gradient process (separate feedings at inversely varying rates) affords heterogeneous particles and films. The Batch process leads to somewhat heterogeneous films, but the hard (MMA‐rich) microdomains are made compatible with their soft (EHA‐rich) matrix because of the assumed formation of tapered‐type copolymers. Tack measurements indicate the importance of the particle and film structures. Too much hardness or softness leads to unacceptable lacks of adhesion and cohesion, respectively. Homogeneous structures prove adequate, but their tack properties collapse with rising temperature. Heterogeneous structures, with extensive phase segregation, prove unsatisfactory because they lack adhesion and cohesion. Finally, the association of well‐balanced composition and compatible heterogeneity is the criterion for suitable PSA behavior. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2749–2756, 2003